**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 57-13-6 |Urea | 45% | 200-315-5 |
|----------------|--------------------------------------|----------|-----------|
| 77-86-1 |Tris borate EDTA buffer | 10% | 201-064-4 |
|----------------|--------------------------------------|----------|-----------|
| 79-06-1 |Acrylamide | 8% | 201-173-7 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 45 46 24/25 48/23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause cancer. May cause heritable genetic damage. Toxic in
contact with skin and if swallowed. Toxic : danger of serious damage
to health by prolonged exposure through inhalation, contact with
skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation. Causes redness and pain.
Skin:
If absorbed, causes symptoms similar to those of ingestion. Causes
redness and pain. Toxic in contact with skin.
Ingestion:
Poison by ingestion. Causes gastrointestinal irritation with nausea,
vomiting and diarrhea. May cause cardiac disturbances.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated exposure may cause adverse reproductive
effects. May cause cancer according to animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 57-13-6:
Russia: 10 mg/m3 TWA
CAS# 77-86-1:
CAS# 79-06-1:
United Kingdom, WEL - TWA: 0.3 mg/m3 TWA
United Kingdom, WEL - STEL: 0.9 mg/m3 STEL
United States OSHA: 0.3 mg/m3 TWA
Belgium - TWA: 0.03 mg/m3 VLE
France - VME: 0.1 ppm VME; 0.3 mg/m3 VME
Germany: 0.06 mg/m3 TWA (solid); 0.03 mg/m3 TWA
Germany: Skin absorber
Japan: 0.1 mg/m3 OEL
Malaysia: 0.03 mg/m3 TWA
Russia: 0.2 mg/m3 TWA
Spain: 0.03 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear colorless solution
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide, ammonia.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 57-13-6: YR6250000
CAS# 77-86-1: TY2900000
CAS# 79-06-1: AS3325000
LD50/LC50:
CAS# 57-13-6: Oral, mouse: LD50 = 11 gm/kg; Oral, rat: LD50 = 8471
mg/kg.
CAS# 77-86-1: Oral, rat: LD50 = 5900 mg/kg.
CAS# 79-06-1: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, skin: 50 mg/3D Mild; Draize test, rabbit, skin: 500
mg/24H Mild; Oral, mouse: LD50 = 107 mg/kg; Oral, rabbit: LD50 = 150
mg/kg; Oral, rat: LD50 = 124 mg/kg; Skin, rabbit: LD50 = 1680 uL/kg;
Skin, rat: LD50 = 400 mg/kg.
Carcinogenicity:
Urea -
Not listed by ACGIH, IARC, or NTP.
Tris borate EDTA buffer -
Not listed by ACGIH, IARC, or NTP.
Acrylamide -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 1/1/90
NTP: Suspect carcinogen
IARC: Group 2A carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
96 Hour Static LC50 to Fathead Minnow = 90 mg/L
48 Hour Static LC50
to Daphnia Magna = 98-105 mg/L
96 Hour Static LC50 to Rainbow Trout =
162 mg/L
96 Hour Flow-Through LC50 to Mysid Shrimp = 78 mg/L
96 Hour
Flow-Through LC50 to Fathead Minnow = 120 mg/L
96 Hour Flow-Through
LC50 to Bluegill Sunfish = 100 mg/L
96 Hour Flow-Through LC50 to
Rainbow Trout = 110 mg/L
48 Hour Flow-Through LC50 to Daphnia Magna =
160 mg/L
48 Hour Flow-Through LC50 to Midge Larvae = 410 mg/L
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
USA RQ: CAS# 79-06-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 46 May cause heritable genetic damage.
R 24/25 Toxic in contact with skin and if swallowed.
R 48/23/24/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation,
contact with skin and if swallowed.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 57-13-6: 1
CAS# 77-86-1: 1
CAS# 79-06-1: 3
Canada
CAS# 57-13-6 is listed on Canada's DSL List.
CAS# 77-86-1 is listed on Canada's DSL List.
CAS# 79-06-1 is listed on Canada's DSL List.
CAS# 57-13-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 77-86-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 79-06-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 57-13-6 is listed on the TSCA inventory.
CAS# 77-86-1 is listed on the TSCA inventory.
CAS# 79-06-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 5/27/1998 Revision #3 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl O-Mesitylsulfonylacetohydroxamate, 98%
| 38202-27-6 |
|
1,1-Methylene-di-2-naphthol, 98%
| 1096-84-0 |
|
2-Naphthyl benzoate, 98%
| 93-44-7 |
|
4-Fluorobenzyl triphenyl phosphoniumchloride, 98%
| 0-01-1 |
|
3,4-Methylenedioxyacetophenone, 98%
| 3162-29-6 |
|
Chloromethyl chlorosulfate, 98%
| 49715-04-0 |
|
2,4,5-Trihydroxypyrimidine, 97%
| 496-76-4 |
|
3-Nitro-1,2-phenylenediamine, 98%
| 3694-52-8 |
|
1-Fluoro-4-hydroxy-1,4-diazabicyclo[2.2.2]octane
| 162241-33-0 |
|
5-Bromo-4-chloro-3-indolyl-??-d-glucuronide monocyclohexylamine salt,
| 114162-64-0 |
|
Diethyl sebacate, 98%
| 110-40-7 |
|
Propyl Disulfide, 99% (GC)
| 629-19-6 |
|
Tetraethyl ethylenediphosphonate, 95%
| 995-32-4 |
|
9-Aminoacridine hydrochloride monohydrate, 98%
| 134-50-9 |
|
N-Benzoyl-D,L-methionine, 98%
| 4703-38-2 |
|
N-(p-Toluenesulfonyl)-DL-methionine, 98%
| 4703-33-7 |
|
5-Bromo-2-hydroxybenzyl alcohol, 98%
| 2316-64-5 |
|
2-Acetoxyacetophenone, 98%
| 7250-94-4 |
|
Diethyldithiocarbamic acid, 97%
| 147-84-2 |
|
4-Chloro-2-isopropyl-5-methylphenol, 98%
| 89-68-9 |
|
DL-6-Methoxy-alpha-methyl-2-napthalenemethanol, 98%
| 77301-42-9 |
|
4-Sulfonic calix[6]arene hydrate
| |
|
Decanenitrile
| 1975-78-6 |
|
2-Cyanoethyl 2-naphthyl ketone
| 0-01-1 |
|
Betha, Betha-Dimethyl-Gamma-Methylene-Gamma-Butyrolactone, 99%
| 0-00-1 |
|
Bromocresol green, ozone friendly ready to use spray for TLC, solvent
| 67-63-0 |
|
Dimethylaminobenzaldehyde, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Ninhydrine, ozone friendly ready to use spray for TLC chromatography
| 67-63-0 |
|
Phosphomolybdic acid, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Rhodamine B, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Phenol/Chloroform/Isoamylalcohol, stabilized, water sat. sol.,
| 67-66-3 |
|
Phenol/TRIS saturated sol., stabilized, DNase, RNase and Protease
| 77-86-1 |
|
Chloroform/Isoamyl alcohol, DNase, RNase and Protease free (24 parts
| 67-66-3 |
|
Citric acid trisodium salt hydrate, DNase RNase and Protease free
| 68-04-2 |
|
Ethylenediaminetetraacetic acid disodium salt, DNase, RNase and
| 139-33-3 |
|
Ethylenediaminetetraacetic acid tetrasodium salt, DNase, RNase and
| 64-02-8 |
|
Tris Borate EDTA buffer, 10x, DNase, RNase and Protease free, pH 8.3
| 77-86-1 |
|
Tris EDTA buffer, DNase, RNase and Protease free, ready to use, pH
| 77-86-1 |
|
Tris EDTA acetate buffer, 10x, DNase, RNase and Protease free, pH 8.3
| 77-86-1 |
|
HEPES free acid, DNase, Rnase and Protease free
| 7365-45-9 |
|
Citric acid, anhydrous, Rnase and Protease free
| 77-92-9 |
|
Acrylamide ultra sequencing gel, 4%, ready-to-use solution
| 57-13-6 |
|
Acrylamide ultra sequencing gel, 6%, ready-to-use solution
| 57-13-6 |
|
Acrylamide ultra sequencing gel, 8%, ready-to-use solution
| 57-13-6 |
|
Acrylamide / N,N'-Methylenebisacrylamide 19:1, 40% mix solution in
| 79-06-1 |
|
Acrylamide / N,N'-Methylenebisacrylamide 29:1, 40% mix solution in
| 79-06-1 |
|
Acrylamide / N,N'-Methylenebisacrylamide 37.5:1, 40% mix solution in
| 0-01-1 |
|
4-Butoxyacetanilide, 97%
| 23563-26-0 |
|
1-(??5-Bromopropoxy)-4-nitrobenzene, 97%
| 13094-50-3 |
|
4-Iodo-3-nitrotoluene, 97%
| 5326-39-6 |
|
|