**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 77-86-1 |Tris (hydroxymethyl) aminomethane | | 201-064-4 |
|----------------|--------------------------------------|----------|-----------|
| 108-95-2 |Phenol | | 203-632-7 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 34 24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Toxic in contact with skin and if swallowed.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Toxic in contact with skin.
Ingestion:
Poison by ingestion. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 77-86-1:
CAS# 108-95-2:
United Kingdom, WEL - TWA: 2 ppm TWA
United Kingdom, WEL - STEL: 6 ppm STEL
United States OSHA: 5 ppm TWA; 19 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 7.8 mg/m3 VLE
France - VME: 5 ppm VME; 19 mg/m3 VME
Germany: 5 ppm TWA; 19 mg/m3 TWA
Germany: Skin absorber
Japan: 5 ppm OEL; 19 mg/m3 OEL
Malaysia: 5 ppm TWA; 15 mg/m3 TWA
Netherlands: 2 ppm MAC; 8 mg/m3 MAC
Russia: 0.3 mg/m3 TWA
Spain: 2 ppm VLA-ED; 8 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Yellow solution
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Not available.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 77-86-1: TY2900000
CAS# 108-95-2: SJ3325000
LD50/LC50:
CAS# 77-86-1: Oral, rat: LD50 = 5900 mg/kg.
CAS# 108-95-2: Draize test, rabbit, eye: 5 mg Severe; Draize test,
rabbit, skin: 500 mg/24H Severe; Draize test, rabbit, skin: 100 mg
Mild; Inhalation, mouse: LC50 = 177 mg/m3; Inhalation, mouse: LC50 =
177 mg/m3/4H; Inhalation, rat: LC50 = 316 mg/m3; Inhalation, rat:
LC50 = 316 mg/m3/4H; Oral, mouse: LD50 = 270 mg/kg; Oral, rat: LD50 =
317 mg/kg; Oral, rat: LD50 = 512 mg/kg; Skin, rabbit: LD50 = 630
mg/kg; Skin, rat: LD50 = 669 mg/kg; Skin, rat: LD50 = 1500 mg/kg.
Carcinogenicity:
Tris (hydroxymethyl) aminomethane -
Not listed by ACGIH, IARC, or NTP.
Phenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
USA RQ: CAS# 108-95-2: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 24/25 Toxic in contact with skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 77-86-1: 1
CAS# 108-95-2: 2
Canada
CAS# 77-86-1 is listed on Canada's DSL List.
CAS# 108-95-2 is listed on Canada's DSL List.
CAS# 77-86-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 108-95-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 77-86-1 is listed on the TSCA inventory.
CAS# 108-95-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 34 Causes burns.
R 24/25 Toxic in contact with skin and if swallowed.
MSDS Creation Date: 5/27/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl O-Mesitylsulfonylacetohydroxamate, 98%
| 38202-27-6 |
|
1,1-Methylene-di-2-naphthol, 98%
| 1096-84-0 |
|
2-Naphthyl benzoate, 98%
| 93-44-7 |
|
4-Fluorobenzyl triphenyl phosphoniumchloride, 98%
| 0-01-1 |
|
3,4-Methylenedioxyacetophenone, 98%
| 3162-29-6 |
|
Chloromethyl chlorosulfate, 98%
| 49715-04-0 |
|
2,4,5-Trihydroxypyrimidine, 97%
| 496-76-4 |
|
3-Nitro-1,2-phenylenediamine, 98%
| 3694-52-8 |
|
1-Fluoro-4-hydroxy-1,4-diazabicyclo[2.2.2]octane
| 162241-33-0 |
|
5-Bromo-4-chloro-3-indolyl-??-d-glucuronide monocyclohexylamine salt,
| 114162-64-0 |
|
Diethyl sebacate, 98%
| 110-40-7 |
|
Propyl Disulfide, 99% (GC)
| 629-19-6 |
|
Tetraethyl ethylenediphosphonate, 95%
| 995-32-4 |
|
9-Aminoacridine hydrochloride monohydrate, 98%
| 134-50-9 |
|
N-Benzoyl-D,L-methionine, 98%
| 4703-38-2 |
|
N-(p-Toluenesulfonyl)-DL-methionine, 98%
| 4703-33-7 |
|
5-Bromo-2-hydroxybenzyl alcohol, 98%
| 2316-64-5 |
|
2-Acetoxyacetophenone, 98%
| 7250-94-4 |
|
Diethyldithiocarbamic acid, 97%
| 147-84-2 |
|
4-Chloro-2-isopropyl-5-methylphenol, 98%
| 89-68-9 |
|
DL-6-Methoxy-alpha-methyl-2-napthalenemethanol, 98%
| 77301-42-9 |
|
4-Sulfonic calix[6]arene hydrate
| |
|
Decanenitrile
| 1975-78-6 |
|
2-Cyanoethyl 2-naphthyl ketone
| 0-01-1 |
|
Betha, Betha-Dimethyl-Gamma-Methylene-Gamma-Butyrolactone, 99%
| 0-00-1 |
|
Bromocresol green, ozone friendly ready to use spray for TLC, solvent
| 67-63-0 |
|
Dimethylaminobenzaldehyde, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Ninhydrine, ozone friendly ready to use spray for TLC chromatography
| 67-63-0 |
|
Phosphomolybdic acid, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Rhodamine B, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Phenol/Chloroform/Isoamylalcohol, stabilized, water sat. sol.,
| 67-66-3 |
|
Phenol/TRIS saturated sol., stabilized, DNase, RNase and Protease
| 77-86-1 |
|
Chloroform/Isoamyl alcohol, DNase, RNase and Protease free (24 parts
| 67-66-3 |
|
Citric acid trisodium salt hydrate, DNase RNase and Protease free
| 68-04-2 |
|
Ethylenediaminetetraacetic acid disodium salt, DNase, RNase and
| 139-33-3 |
|
Ethylenediaminetetraacetic acid tetrasodium salt, DNase, RNase and
| 64-02-8 |
|
Tris Borate EDTA buffer, 10x, DNase, RNase and Protease free, pH 8.3
| 77-86-1 |
|
Tris EDTA buffer, DNase, RNase and Protease free, ready to use, pH
| 77-86-1 |
|
Tris EDTA acetate buffer, 10x, DNase, RNase and Protease free, pH 8.3
| 77-86-1 |
|
HEPES free acid, DNase, Rnase and Protease free
| 7365-45-9 |
|
Citric acid, anhydrous, Rnase and Protease free
| 77-92-9 |
|
Acrylamide ultra sequencing gel, 4%, ready-to-use solution
| 57-13-6 |
|
Acrylamide ultra sequencing gel, 6%, ready-to-use solution
| 57-13-6 |
|
Acrylamide ultra sequencing gel, 8%, ready-to-use solution
| 57-13-6 |
|
Acrylamide / N,N'-Methylenebisacrylamide 19:1, 40% mix solution in
| 79-06-1 |
|
Acrylamide / N,N'-Methylenebisacrylamide 29:1, 40% mix solution in
| 79-06-1 |
|
Acrylamide / N,N'-Methylenebisacrylamide 37.5:1, 40% mix solution in
| 0-01-1 |
|
4-Butoxyacetanilide, 97%
| 23563-26-0 |
|
1-(??5-Bromopropoxy)-4-nitrobenzene, 97%
| 13094-50-3 |
|
4-Iodo-3-nitrotoluene, 97%
| 5326-39-6 |
|
|