**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-66-3 |Chloroform | 97.8 | 200-663-8 |
|----------------|--------------------------------------|----------|-----------|
| 123-51-3 |Isoamyl alcohol | 2.2 | 204-633-5 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 10 22 38 40 48/20/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Irritating to skin. Limited
evidence of a carcinogenic effect. Harmful : danger of serious damage
to health by prolonged exposure through inhalation and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 67-66-3:
United Kingdom, WEL - TWA: 2 ppm TWA; 9.9 mg/m3 TWA
United Kingdom, WEL - STEL: 6 ppm STEL; 29.7 mg/m3 STEL
United States OSHA: ; 50 ppm Ceiling; 240 mg/m3 Ceiling
Belgium - TWA: 10 ppm VLE; 50 mg/m3 VLE
France - VME: 5 ppm VME; 25 mg/m3 VME
France - VLE: 50 ppm VLE; 250 mg/m3 VLE
Germany: 4 ppm TWA (large technical manufacture and use); 20 mg/m
TWA (large technical m
Germany: Skin absorber
Japan: 10 ppm OEL; 49 mg/m3 OEL
Malaysia: 10 ppm TWA; 49 mg/m3 TWA
Netherlands: 5 ppm STEL; 25 mg/m3 STEL
Netherlands: 1 ppm MAC; 5 mg/m3 MAC
Spain: 2 ppm VLA-ED; 10 mg/m3 VLA-ED
CAS# 123-51-3:
United Kingdom, WEL - TWA: 100 ppm TWA; 366 mg/m3 TWA
United Kingdom, WEL - STEL: 125 ppm STEL; 458 mg/m3 STEL
United States OSHA: 100 ppm TWA; 360 mg/m3 TWA
Belgium - TWA: 100 ppm VLE; 366 mg/m3 VLE
Belgium - STEL: 125 ppm VLE; 459 mg/m3 VLE
France - VME: 100 ppm VME; 360 mg/m3 VME
Germany: 100 ppm TWA; 370 mg/m3 TWA
Japan: 100 ppm OEL; 360 mg/m3 OEL
Malaysia: 100 ppm TWA; 361 mg/m3 TWA
Netherlands: 100 ppm MAC; 360 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 100 ppm VLA-ED; 366 mg/m3 VLA-ED
Spain: 125 ppm VLA-EC; 458 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear solution
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 43 deg C ( 109.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-66-3: FS9100000
CAS# 123-51-3: EL5425000
LD50/LC50:
CAS# 67-66-3: Draize test, rabbit, eye: 148 mg; Draize test, rabbit,
eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, mouse: LC50 = 17200 mg/m3/2H; Inhalation, mouse: LC50 =
6000 mg/m3/6H; Inhalation, rat: LC50 = 47702 mg/m3/4H; Inhalation,
rat: LC50 = 6000 mg/m3/6H; Oral, mouse: LD50 = 36 mg/kg; Oral, rat:
LD50 = 695 mg/kg; Oral, rat: LD50 = 1250 mg/kg; Skin, rabbit: LD50 =
>20 gm/kg.
CAS# 123-51-3: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize
test, rabbit, skin: 20 mg/24H Moderate; Oral, rabbit: LD50 = 3438
mg/kg; Oral, rat: LD50 = 1300 mg/kg; Oral, rat: LD50 = 4300 mg/kg;
Skin, rabbit: LD50 = 3970 uL/kg.
Carcinogenicity:
Chloroform -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 10/1/87
NTP: Suspect carcinogen
IARC: Group 2B carcinogen
Isoamyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.*
Hazard Class: 3 (6.1)
UN Number: 1992
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3.3
UN Number: 1992
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1992
Packing group: III
USA RQ: CAS# 67-66-3: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 40 Limited evidence of a carcinogenic effect.
R 48/20/22 Harmful : danger of serious damage to
health by prolonged exposure through inhalation and if
swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 67-66-3: 3
CAS# 123-51-3: 1
Canada
CAS# 67-66-3 is listed on Canada's DSL List.
CAS# 123-51-3 is listed on Canada's DSL List.
CAS# 67-66-3 is listed on Canada's Ingredient Disclosure List.
CAS# 123-51-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-66-3 is listed on the TSCA inventory.
CAS# 123-51-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 5/19/1998 Revision #3 Date: 9/24/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl O-Mesitylsulfonylacetohydroxamate, 98%
| 38202-27-6 |
|
1,1-Methylene-di-2-naphthol, 98%
| 1096-84-0 |
|
2-Naphthyl benzoate, 98%
| 93-44-7 |
|
4-Fluorobenzyl triphenyl phosphoniumchloride, 98%
| 0-01-1 |
|
3,4-Methylenedioxyacetophenone, 98%
| 3162-29-6 |
|
Chloromethyl chlorosulfate, 98%
| 49715-04-0 |
|
2,4,5-Trihydroxypyrimidine, 97%
| 496-76-4 |
|
3-Nitro-1,2-phenylenediamine, 98%
| 3694-52-8 |
|
1-Fluoro-4-hydroxy-1,4-diazabicyclo[2.2.2]octane
| 162241-33-0 |
|
5-Bromo-4-chloro-3-indolyl-??-d-glucuronide monocyclohexylamine salt,
| 114162-64-0 |
|
Diethyl sebacate, 98%
| 110-40-7 |
|
Propyl Disulfide, 99% (GC)
| 629-19-6 |
|
Tetraethyl ethylenediphosphonate, 95%
| 995-32-4 |
|
9-Aminoacridine hydrochloride monohydrate, 98%
| 134-50-9 |
|
N-Benzoyl-D,L-methionine, 98%
| 4703-38-2 |
|
N-(p-Toluenesulfonyl)-DL-methionine, 98%
| 4703-33-7 |
|
5-Bromo-2-hydroxybenzyl alcohol, 98%
| 2316-64-5 |
|
2-Acetoxyacetophenone, 98%
| 7250-94-4 |
|
Diethyldithiocarbamic acid, 97%
| 147-84-2 |
|
4-Chloro-2-isopropyl-5-methylphenol, 98%
| 89-68-9 |
|
DL-6-Methoxy-alpha-methyl-2-napthalenemethanol, 98%
| 77301-42-9 |
|
4-Sulfonic calix[6]arene hydrate
| |
|
Decanenitrile
| 1975-78-6 |
|
2-Cyanoethyl 2-naphthyl ketone
| 0-01-1 |
|
Betha, Betha-Dimethyl-Gamma-Methylene-Gamma-Butyrolactone, 99%
| 0-00-1 |
|
Bromocresol green, ozone friendly ready to use spray for TLC, solvent
| 67-63-0 |
|
Dimethylaminobenzaldehyde, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Ninhydrine, ozone friendly ready to use spray for TLC chromatography
| 67-63-0 |
|
Phosphomolybdic acid, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Rhodamine B, ozone friendly ready to use spray for TLC
| 67-63-0 |
|
Phenol/Chloroform/Isoamylalcohol, stabilized, water sat. sol.,
| 67-66-3 |
|
Phenol/TRIS saturated sol., stabilized, DNase, RNase and Protease
| 77-86-1 |
|
Chloroform/Isoamyl alcohol, DNase, RNase and Protease free (24 parts
| 67-66-3 |
|
Citric acid trisodium salt hydrate, DNase RNase and Protease free
| 68-04-2 |
|
Ethylenediaminetetraacetic acid disodium salt, DNase, RNase and
| 139-33-3 |
|
Ethylenediaminetetraacetic acid tetrasodium salt, DNase, RNase and
| 64-02-8 |
|
Tris Borate EDTA buffer, 10x, DNase, RNase and Protease free, pH 8.3
| 77-86-1 |
|
Tris EDTA buffer, DNase, RNase and Protease free, ready to use, pH
| 77-86-1 |
|
Tris EDTA acetate buffer, 10x, DNase, RNase and Protease free, pH 8.3
| 77-86-1 |
|
HEPES free acid, DNase, Rnase and Protease free
| 7365-45-9 |
|
Citric acid, anhydrous, Rnase and Protease free
| 77-92-9 |
|
Acrylamide ultra sequencing gel, 4%, ready-to-use solution
| 57-13-6 |
|
Acrylamide ultra sequencing gel, 6%, ready-to-use solution
| 57-13-6 |
|
Acrylamide ultra sequencing gel, 8%, ready-to-use solution
| 57-13-6 |
|
Acrylamide / N,N'-Methylenebisacrylamide 19:1, 40% mix solution in
| 79-06-1 |
|
Acrylamide / N,N'-Methylenebisacrylamide 29:1, 40% mix solution in
| 79-06-1 |
|
Acrylamide / N,N'-Methylenebisacrylamide 37.5:1, 40% mix solution in
| 0-01-1 |
|
4-Butoxyacetanilide, 97%
| 23563-26-0 |
|
1-(??5-Bromopropoxy)-4-nitrobenzene, 97%
| 13094-50-3 |
|
4-Iodo-3-nitrotoluene, 97%
| 5326-39-6 |
|
|