**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-63-0 |Isopropanol | 98% | 200-661-7 |
|----------------|--------------------------------------|----------|-----------|
| 74-98-6 |Propane | | 200-827-9 |
|----------------|--------------------------------------|----------|-----------|
| 81-88-9 |Rhodamine B | 2% | 201-383-9 |
|----------------|--------------------------------------|----------|-----------|
| 106-97-8 |Butane | | 203-448-7 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN F+
Risk Phrases: 12 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Extremely flammable. Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Extremely flammable liquid and vapor. Containers may explode in
the heat of a fire.
Extinguishing Media:
Water may be ineffective. Use water spray, dry chemical, carbon
dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 67-63-0:
United Kingdom, WEL - TWA: 400 ppm TWA; 999 mg/m3 TWA
United Kingdom, WEL - STEL: 500 ppm STEL; 1250 mg/m3 STEL
United States OSHA: 400 ppm TWA; 980 mg/m3 TWA
Belgium - TWA: 400 ppm VLE; 997 mg/m3 VLE
Belgium - STEL: 500 ppm VLE; 1248 mg/m3 VLE
France - VLE: 400 ppm VLE; 980 mg/m3 VLE
Germany: 200 ppm TWA; 500 mg/m3 TWA
Japan: 400 ppm Ceiling; 980 mg/m3 Ceiling
Malaysia: 400 ppm TWA; 983 mg/m3 TWA
Netherlands: 250 ppm MAC; 650 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 400 ppm VLA-ED; 998 mg/m3 VLA-ED
Spain: 500 ppm VLA-EC; 1250 mg/m3 VLA-EC
CAS# 74-98-6:
United States OSHA: 1000 ppm TWA; 1800 mg/m3 TWA
Germany: 1000 ppm TWA; 1800 mg/m3 TWA
Malaysia: 2500 ppm TWA
Spain: 1000 ppm VLA-ED (listed under Aliphatic hydrocarbon gases
mixtures alkanes C
CAS# 81-88-9:
CAS# 106-97-8:
United Kingdom, WEL - TWA: 600 ppm TWA; 1450 mg/m3 TWA
United Kingdom, WEL - STEL: 750 ppm STEL; 1810 mg/m3 STEL
Belgium - TWA: 800 ppm VLE; 1928 mg/m3 VLE
France - VME: 800 ppm VME; 1900 mg/m3 VME
Germany: 1000 ppm TWA; 2400 mg/m3 TWA
Japan: 500 ppm OEL; 1200 mg/m3 OEL
Malaysia: 800 ppm TWA; 1900 mg/m3 TWA
Netherlands: 600 ppm MAC; 1430 mg/m3 MAC
Russia: 300 mg/m3 TWA
Spain: 1000 ppm VLA-ED (listed under Aliphatic hydrocarbon gases
mixtures alkanes C
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Aerosol
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-63-0: NT8050000
CAS# 74-98-6: TX2275000
CAS# 81-88-9: BP3675000
CAS# 106-97-8: EJ4200000
LD50/LC50:
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H
Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, mouse:
LC50 = 53000 mg/m3; Inhalation, rat: LC50 = 16000 ppm/8H; Inhalation,
rat: LC50 = 72600 mg/m3; Oral, mouse: LD50 = 3600 mg/kg; Oral, mouse:
LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 =
5045 mg/kg; Oral, rat: LD50 = 5000 mg/kg; Skin, rabbit: LD50 = 12800
mg/kg.
CAS# 74-98-6.
CAS# 81-88-9: Oral, mouse: LD50 = 887 mg/kg.
CAS# 106-97-8: Inhalation, mouse: LC50 = 680000 mg/m3/2H;
Inhalation, rat: LC50 = 658000 mg/m3/4H.
Carcinogenicity:
Isopropanol -
Not listed by ACGIH, IARC, or NTP.
Propane -
Not listed by ACGIH, IARC, or NTP.
Rhodamine B -
California: carcinogen, initial date 7/1/90
Butane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AEROSOLS, 30
Hazard Class: 2.1
UN Number: 1950
Packing Group:
IMO
Shipping Name: AEROSOLS, FLAMMABLE, N.O.S.
Hazard Class: 2.1
UN Number: 1950
Packing Group:
RID/ADR
Shipping Name: AEROSOLS
Hazard Class: 2
UN Number: 1950
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F+
Risk Phrases:
R 12 Extremely flammable.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 74-98-6: 0
CAS# 81-88-9: 2
CAS# 106-97-8: 0
Canada
CAS# 67-63-0 is listed on Canada's DSL List.
CAS# 74-98-6 is listed on Canada's DSL List.
CAS# 81-88-9 is listed on Canada's DSL List.
CAS# 106-97-8 is listed on Canada's DSL List.
CAS# 67-63-0 is listed on Canada's Ingredient Disclosure List.
CAS# 74-98-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 81-88-9 is listed on Canada's Ingredient Disclosure List.
CAS# 106-97-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 74-98-6 is listed on the TSCA inventory.
CAS# 81-88-9 is listed on the TSCA inventory.
CAS# 106-97-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 36 Irritating to eyes.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 5/27/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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