**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 591-87-7 |Allyl Acetate | 99 | 209-734-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 20/21 25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation and in contact with skin.
Toxic if swallowed.Lachrymator (substance which increases the flow
of tears).
Potential Health Effects
Eye:
May cause transient corneal injury. Lachrymator (substance which
increases the flow of tears). Causes eye irritation and possible
burns.
Skin:
May be harmful if absorbed through the skin. May cause blistering of
the skin. Causes skin irritation and possible burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
May be harmful if inhaled. Vapors may cause dizziness or
suffocation. Causes respiratory tract irritation with possible burns.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Extensive irrigation with water is
required (at least 30 minutes).
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Destroy contaminated shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water. May
cause irritation of the digestive tract and possible burns.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Wash clothing before reuse. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 591-87-7:
Russia: 2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: acrid odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 103.0 - 104.0 deg C @ 760.00m
Freezing/Melting Point: -22 deg C
Autoignition Temperature: 374 deg C ( 705.20 deg F)
Flash Point: 21 deg C ( 69.80 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: .9280g/cm3
Molecular Formula: C5H8O2
Molecular Weight: 100.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 591-87-7: AF1750000
LD50/LC50:
CAS# 591-87-7: Draize test, rabbit, eye: 100 mg Moderate; Draize
test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = 1000
ppm/1H; Oral, mouse: LD50 = 170 mg/kg; Oral, rat: LD50 = 130 mg/kg;
Skin, rabbit: LD50 = 1021 mg/kg.
Carcinogenicity:
Allyl Acetate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALLYL ACETATE
Hazard Class: 3 (6.1)
UN Number: 2333
Packing Group: II
IMO
Shipping Name: ALLYL ACETATE
Hazard Class: 3.2 (6.1)
UN Number: 2333
Packing Group: II
RID/ADR
Shipping Name: ALLYL ACETATE
Hazard Class: 3
UN Number: 2333
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 25 Toxic if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 27 Take off immediately all contaminated clothing.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 591-87-7: No information available.
Canada
CAS# 591-87-7 is listed on Canada's DSL List.
CAS# 591-87-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 591-87-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/26/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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9-Octyl-9-heptadecanol, tech.
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|
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| 542-90-5 |
|
3,5-Dichlorobenzoic Acid, 99%
| 51-36-5 |
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Ethyl 2-aminocyclopenta[b]thiophene-3-carboxylate, 99+%
| 4815-29-6 |
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| 619-66-9 |
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N-Methylacetamide, 99+%
| 79-16-3 |
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| 1874-22-2 |
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| 13444-93-4 |
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Cytochrome c, horse heart muscle 90% warburg activity
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Octylamine, 99+% (GC)
| 111-86-4 |
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2,3-Diaminonaphthalene, 97%
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| 56-12-2 |
|
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| 93-68-5 |
|
4-Cyclohexyl-1-Butanol, 99%
| 4441-57-0 |
|
Pipes (1,4-Piperazinebis(Ethanesulfonic Acid)) 98.5+%
| 5625-37-6 |
|
5-Norbornene-2-acrylic acid, 99%
| 15222-64-7 |
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| 461-98-3 |
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| 2439-54-5 |
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| 110-72-5 |
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