**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 74974-60-0 |Gallium(III) Trifluoromethanesulfonate| 99% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Hygroscopic (absorbs moisture from the air).Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose
upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Avoid generating dusty conditions. Provide
ventilation. Vacuum or sweep up material and place into a suitable,
dry disposal container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use only in
a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 74974-60-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: stench
pH: Not available.
Vapor Pressure: 10 hPa @ 55 deg C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.7
Molecular Formula: C3F9GaO9S3
Molecular Weight: 516.91
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases, alkali metals, alkaline earth metals,
moisture.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, sulfur oxides
(SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 74974-60-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Gallium(III) Trifluoromethanesulfonate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 74974-60-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 74974-60-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 74974-60-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/24/2000 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3,4,5,6-Pentafluorostyrene, 97+%
| 653-34-9 |
|
2-(2-Chlorophenoxy)propionic acid, 98%
| 25140-86-7 |
|
2-Methoxyacetophenone
| 4079-52-1 |
|
3-Methyl-4-nitroanisole, 98%
| 5367-32-8 |
|
(S)-alpha-Methyl-4-carboxyphenylglycine
| 0-01-1 |
|
(R,S)-alfa-Methyl-4-carboxyphenylglycine
| 146669-29-6 |
|
(2R,4R)-4-Methylglutamic acid hydrochloride
| 166756-77-0 |
|
(2s,4s)-4-methylglutamic acid . hydrochloride
| 160806-12-2 |
|
Nbd fgin-1-27 analog
| 336111-14-9 |
|
Diethyl (3,3-Diethoxypropyl)Phosphonate
| 15110-17-5 |
|
Nifedipine, USP grade
| 21829-25-4 |
|
(S)-(+)-2,2,2-Trifluoro-1-(9-Anthryl)Ethanol, 97%
| 60646-30-2 |
|
Arsenic Trioxide
| 1327-53-3 |
|
2-Hydroxyethyl stearate
| 111-60-4 |
|
Thulium(III) Trifluoromethanesulfonate, 99%
| 141478-68-4 |
|
1-Fluoro-2-nitrobenzene, 97% (GC)
| 1493-27-2 |
|
Neodymium(III) Trifluoromethanesulfonate, 99%
| 34622-08-7 |
|
Methyltrioxorhenium (VII)
| 70197-13-6 |
|
Lanthanum(III) Trifluoromethanesulfonate, 99%
| 52093-26-2 |
|
Yttrium(III) Trifluoromethanesulfonate, 99%
| 52093-30-8 |
|
Gallium(III) Trifluoromethanesulfonate, 99%
| 74974-60-0 |
|
Cerium(III) Trifluoromethanesulfonate, 99%
| 76089-77-5 |
|
1-Chloromethyl-2,4-diisocyanatobenzene, 97%
| 51979-57-8 |
|
4,6-Dichloropyrimidine, 97%
| 1193-21-1 |
|
Methyl 5-propylthio-2-benzimidazolecarbamate, 98%
| 54965-21-8 |
|
(2R,3R)-1-Carboxy-2,3-Dihydroxy-4-Methylcyclohexa-4,6-Diene, 95%
| 0-01-1 |
|
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane, 96%
| 2401-73-2 |
|
1,3-Dihydro-1-(1-methylethenyl)-2H-benzimidazole-2-one, 99%
| 52099-72-6 |
|
N-Benzylpyrrolidine, 97%
| 0-01-1 |
|
1-Phenyl-6,7-Dimethoxy-3,4-Dihydroisoquinoline, 98%
| 10172-39-1 |
|
Arsenic(V) oxide
| 1303-28-2 |
|
Nimodipine
| 66085-59-4 |
|
Formylmethyl Triphenylphopshonium Chloride, 98%
| 62942-43-2 |
|
1,2-Dichloropropane, 98%
| 78-87-5 |
|
(Ethylthio)trimethylsilane, tech., 90%
| 5573-62-6 |
|
PCCG-4
| 0-01-1 |
|
1,3-Dioxane, 97%
| 505-22-6 |
|
Tamoxifen.Citrate
| 54965-24-1 |
|
Victoria Blue B
| 2580-56-5 |
|
Triphenylsilyl chloride, 95%
| 76-86-8 |
|
DL-2-Methylserine hydrate, 98%
| 3398-40-1 |
|
DL-2-Isopropylserine, 99%
| 7522-43-2 |
|
DL-2-Isobutylserine
| 7522-44-3 |
|
DL-N-Benzoyl-2-Methylserine, 98%
| 7508-82-9 |
|
Victoria Blue R
| 2185-86-6 |
|
DL-N-Benzoyl-2-Isopropylserine
| 52421-46-2 |
|
DL-N-Benzoyl-2-Isobutylserine
| 52421-47-3 |
|
DL-N-Benzoyl-2-benzylserine
| 52421-48-4 |
|
Dl-2-benzylserine, 97%
| 4740-47-0 |
|
4,4'(5')-Dihydroxydibenzo-15-crown-5, 96%, contains approx. 1 mole of
| 0-00-1 |
|
|