**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 76-86-8 |Triphenylsilyl chloride | 95 | 200-989-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Aspiration may
lead to pulmonary edema. May cause burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT get water inside containers. In case of fire, use carbon
dioxide, dry chemical powder or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Keep container tightly closed. Do
not get on skin or in eyes. Do not ingest or inhale. Use with
adequate ventilation. Do not allow contact with water. Discard
contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Corrosives area. Store
protected from moisture. Store in a cool, dry area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 76-86-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 378 deg C @ 760.00mmHg
Freezing/Melting Point: 88.00 - 91.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: decomposes
Specific Gravity/Density: Not available.
Molecular Formula: C18H15ClSi
Molecular Weight: 294.85
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, moisture, water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide,
chloride fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 76-86-8: VV2720000
LD50/LC50:
Not available.
Carcinogenicity:
Triphenylsilyl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 76-86-8: No information available.
Canada
CAS# 76-86-8 is listed on Canada's NDSL List.
CAS# 76-86-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 76-86-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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2-(2-Chlorophenoxy)propionic acid, 98%
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2-Methoxyacetophenone
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3-Methyl-4-nitroanisole, 98%
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(S)-alpha-Methyl-4-carboxyphenylglycine
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(R,S)-alfa-Methyl-4-carboxyphenylglycine
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(2R,4R)-4-Methylglutamic acid hydrochloride
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(2s,4s)-4-methylglutamic acid . hydrochloride
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Nbd fgin-1-27 analog
| 336111-14-9 |
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Diethyl (3,3-Diethoxypropyl)Phosphonate
| 15110-17-5 |
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Nifedipine, USP grade
| 21829-25-4 |
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| 60646-30-2 |
|
Arsenic Trioxide
| 1327-53-3 |
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2-Hydroxyethyl stearate
| 111-60-4 |
|
Thulium(III) Trifluoromethanesulfonate, 99%
| 141478-68-4 |
|
1-Fluoro-2-nitrobenzene, 97% (GC)
| 1493-27-2 |
|
Neodymium(III) Trifluoromethanesulfonate, 99%
| 34622-08-7 |
|
Methyltrioxorhenium (VII)
| 70197-13-6 |
|
Lanthanum(III) Trifluoromethanesulfonate, 99%
| 52093-26-2 |
|
Yttrium(III) Trifluoromethanesulfonate, 99%
| 52093-30-8 |
|
Gallium(III) Trifluoromethanesulfonate, 99%
| 74974-60-0 |
|
Cerium(III) Trifluoromethanesulfonate, 99%
| 76089-77-5 |
|
1-Chloromethyl-2,4-diisocyanatobenzene, 97%
| 51979-57-8 |
|
4,6-Dichloropyrimidine, 97%
| 1193-21-1 |
|
Methyl 5-propylthio-2-benzimidazolecarbamate, 98%
| 54965-21-8 |
|
(2R,3R)-1-Carboxy-2,3-Dihydroxy-4-Methylcyclohexa-4,6-Diene, 95%
| 0-01-1 |
|
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane, 96%
| 2401-73-2 |
|
1,3-Dihydro-1-(1-methylethenyl)-2H-benzimidazole-2-one, 99%
| 52099-72-6 |
|
N-Benzylpyrrolidine, 97%
| 0-01-1 |
|
1-Phenyl-6,7-Dimethoxy-3,4-Dihydroisoquinoline, 98%
| 10172-39-1 |
|
Arsenic(V) oxide
| 1303-28-2 |
|
Nimodipine
| 66085-59-4 |
|
Formylmethyl Triphenylphopshonium Chloride, 98%
| 62942-43-2 |
|
1,2-Dichloropropane, 98%
| 78-87-5 |
|
(Ethylthio)trimethylsilane, tech., 90%
| 5573-62-6 |
|
PCCG-4
| 0-01-1 |
|
1,3-Dioxane, 97%
| 505-22-6 |
|
Tamoxifen.Citrate
| 54965-24-1 |
|
Victoria Blue B
| 2580-56-5 |
|
Triphenylsilyl chloride, 95%
| 76-86-8 |
|
DL-2-Methylserine hydrate, 98%
| 3398-40-1 |
|
DL-2-Isopropylserine, 99%
| 7522-43-2 |
|
DL-2-Isobutylserine
| 7522-44-3 |
|
DL-N-Benzoyl-2-Methylserine, 98%
| 7508-82-9 |
|
Victoria Blue R
| 2185-86-6 |
|
DL-N-Benzoyl-2-Isopropylserine
| 52421-46-2 |
|
DL-N-Benzoyl-2-Isobutylserine
| 52421-47-3 |
|
DL-N-Benzoyl-2-benzylserine
| 52421-48-4 |
|
Dl-2-benzylserine, 97%
| 4740-47-0 |
|
4,4'(5')-Dihydroxydibenzo-15-crown-5, 96%, contains approx. 1 mole of
| 0-00-1 |
|
|