**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-62-7 |Bromotrichloromethane | 99% | 200-886-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI T
Risk Phrases: 23/24/25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver damage. May cause central nervous system
depression. May cause cardiac abnormalities.
Inhalation:
Causes respiratory tract irritation. May cause cardiac
abnormalities. Can produce delayed pulmonary edema. May cause liver
damage.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated. Runoff from fire
control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. For small fires,
use dry chemical, carbon dioxide, or water spray. For large fires,
use dry chemical, carbon dioxide, alcohol-resistant foam, or water
spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Use with adequate
ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 75-62-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 38.4 mmHg @ 25
Viscosity: Not available.
Boiling Point: 105 deg C @ 760.00mm Hg
Freezing/Melting Point: -6 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: immiscible
Specific Gravity/Density: 2.0120g/cm3
Molecular Formula: CBrCl3
Molecular Weight: 198.27
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-62-7: PA5400000
LD50/LC50:
Not available.
Carcinogenicity:
Bromotrichloromethane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 75-62-7: No information available.
Canada
CAS# 75-62-7 is listed on Canada's DSL List.
CAS# 75-62-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-62-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
l-Cysteic Acid Monohydrate, 99+%
| 23537-25-9 |
|
1-Hexanesulfonic acid sodium salt premixed concentrate
| |
|
N-Alpha-Carbobenzyloxy-L-Asparagine, 98%
| 2304-96-3 |
|
Ytterbium atomic absorption standard solution, 1 mg/ml yb in 2% hno3
| |
|
Bromotrichloromethane, 99%
| 75-62-7 |
|
Dicyclopentadiene, 95%, stabilized with 100-200 ppm
| 77-73-6 |
|
3-Amino-1-propanesulfonic acid, 95%
| 3687-18-1 |
|
Copper(ii) fluoride, anhydrous, 99+%
| 7789-19-7 |
|
2-Chloro-4-Fluorophenylacetic Acid
| 177985-32-9 |
|
Cyclopropyl Phenyl Sulfide
| 14633-54-6 |
|
BOC-L-Tyrosine, 99+%
| 3978-80-1 |
|
1,8-Octanediol, 99+%
| 629-41-4 |
|
3-Thiophenecarboxylic acid, 99%
| 88-13-1 |
|
1,2,3-Trimethylbenzene, Tech., 90%
| 526-73-8 |
|
Molybdenum(v) chloride, 98%
| 10241-05-1 |
|
2-Dimethylaminoethyl Acetate
| 1421-89-2 |
|
4-Benzyl-4-Hydroxypiperidine, 95+%(GC)
| 51135-96-7 |
|
8-Chloroquinoline, 99% (gc)
| 611-33-6 |
|
2-Ethyl-3,5(6)-dimethylpyrazine,99.5+%
| 27043-05-6 |
|
p-Ethoxybenzyl Alcohol, 98%
| 6214-44-4 |
|
2,3-Dichlorothiophene, 97%
| 17249-79-5 |
|
Tropolone, 98%
| 533-75-5 |
|
1,3-Difluorobenzene, 99+%
| 372-18-9 |
|
2-Methylundecanal, 95%
| 110-41-8 |
|
2-Ethyl-2-methyl-1,3-dioxolane, 99%
| 126-39-6 |
|
Bromoethane, 98%
| 74-96-4 |
|
1,3,5-Triphenylbenzene, 97%
| 612-71-5 |
|
1-Tetradecene, 92%
| 1120-36-1 |
|
9,10-Anthracenedicarboxaldehyde, 95% (UV-Vis)
| 7044-91-9 |
|
Lead cyclohexanebutyrate
| 62637-99-4 |
|
1-Butanethiol, 99+%
| 109-79-5 |
|
L-(+)-Homoarginine hydrochloride, 99+%
| 1483-01-8 |
|
3,4-(Methylenedioxy)-aniline, 97%
| 14268-66-7 |
|
(2-Chloroethyl)benzene, 99%
| 622-24-2 |
|
Poly(propylene), chlorinated
| 68442-33-1 |
|
Dodecyl aldehyde, 96%, stabilized with 0.1% BHA
| 112-54-9 |
|
N,N'-Diallyltartardiamide
| 58477-85-3 |
|
5,6,7,8-Tetrahydro-2-naphthol, 98%
| 1125-78-6 |
|
Cyclodecanone, 97%
| 1502-06-3 |
|
4-Amino-1-butanol, 98%
| 13325-10-5 |
|
4-Aminoveratrole, 98%
| 6315-89-5 |
|
2-Bromo-4-nitrotoluene, 98%
| 7745-93-9 |
|
Pulegone (Pract), 88% (GC)
| 89-82-7 |
|
Diethyl suberate, 98%
| 2050-23-9 |
|
beta-Bromostyrene, mixture of cis/trans isomers, 97%
| 103-64-0 |
|
Naphthenic acids (pract)
| 1338-24-5 |
|
S(+)-1,3-Butanediol, 98%
| 24621-61-2 |
|
5-Bromo-1,2,4-trimethylbenzene, 99%
| 5469-19-2 |
|
alpha-D(+)-Melibiose hydrate, 99+%
| 585-99-9 |
|
O-Tolualdehyde 98% (Stabilized with 0.1 % H.Q.)
| 529-20-4 |
|
|