**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7757-82-6 |Sodium sulfate anhydrous | | 231-820-9 |
|----------------|--------------------------------------|----------|-----------|
| 7758-98-7 |Cupric sulfate | | 231-847-6 |
|----------------|--------------------------------------|----------|-----------|
| 13463-67-7 |Titanium dioxide | | 236-675-5 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Not available.
Skin:
Not available.
Ingestion:
Not available.
Inhalation:
Not available.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Not available.
Extinguishing Media:
Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Not available.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Not available.
Storage:
Not available.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Exposure Limits
CAS# 7757-82-6:
Russia: 10 mg/m3 TWA
CAS# 7758-98-7:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: 0.5 mg/m3 TWA
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
CAS# 13463-67-7:
United Kingdom, WEL - TWA: 10 mg/m3 TWA (total inhalable); 4 mg/m
TWA (respirable)
United Kingdom, WEL - STEL: 30 mg/m3 STEL (total inhalable); 12 m
STEL (respirable)
United States OSHA: 15 mg/m3 TWA (total dust)
Belgium - TWA: 10 mg/m3 VLE
France - VME: 10 mg/m3 VME (as Ti)
Malaysia: 10 mg/m3 TWA
Netherlands: 10 mg/m3 MAC
Russia: 10 mg/m3 TWA (inhalable dust)
Spain: 10 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Not available.
Skin:
Not available.
Clothing:
Not available.
Respirators:
Not available.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Not available.
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: Not available.
Molecular Weight: Not available.
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Not available.
Hazardous Polymerization: Not available.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7757-82-6: WE1650000
CAS# 7758-98-7: GL8800000
CAS# 13463-67-7: XR2275000
LD50/LC50:
CAS# 7757-82-6: Oral, mouse: LD50 = 5989 mg/kg.
CAS# 7758-98-7: Oral, mouse: LD50 = 369 mg/kg; Oral, mouse: LD50 =
87 mg/kg; Oral, rat: LD50 = 300 mg/kg; Oral, rat: LD50 = 960 mg/kg.
CAS# 13463-67-7.
Carcinogenicity:
Sodium sulfate anhydrous -
Not listed by ACGIH, IARC, or NTP.
Cupric sulfate -
Not listed by ACGIH, IARC, or NTP.
Titanium dioxide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7757-82-6: 0
CAS# 7758-98-7: 2
CAS# 13463-67-7: 0
Canada
CAS# 7757-82-6 is listed on Canada's DSL List.
CAS# 7758-98-7 is listed on Canada's DSL List.
CAS# 13463-67-7 is listed on Canada's DSL List.
CAS# 7757-82-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 7758-98-7 is listed on Canada's Ingredient Disclosure List.
CAS# 13463-67-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7757-82-6 is listed on the TSCA inventory.
CAS# 7758-98-7 is listed on the TSCA inventory.
CAS# 13463-67-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 5/08/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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