**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 821-10-3 |1,4-Dichloro-2-butyne, 99% | 99% | 212-474-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause irritation of the
respiratory tract with burning pain in the nose and throat, coughing,
wheezing, shortness of breath and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Do
not get on skin or in eyes. Do not ingest or inhale.
Storage:
Do not store in direct sunlight. Store in a tightly closed
container. Store in a dry area. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 821-10-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 165 - 168 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 160 deg C ( 320.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2580g/cm3
Molecular Formula: C4H4Cl2
Molecular Weight: 122.98
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, temperatures above 150C.
Incompatibilities with Other Materials:
Strong oxidizing agents and strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 821-10-3: ER9600000
LD50/LC50:
Not available.
Carcinogenicity:
1,4-Dichloro-2-butyne, 99% -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HALOGENATED IRRITATING LIQUID, N.O.S.*
Hazard Class: 6.1
UN Number: 1610
Packing Group: II
IMO
Shipping Name:
Hazard Class:
UN Number: 1610
Packing Group:
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 821-10-3: No information available.
Canada
CAS# 821-10-3 is listed on Canada's NDSL List.
CAS# 821-10-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 821-10-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cyclen, 97%
| 294-90-6 |
|
4-Hydroxy Benzylidene Malonic Acid Dimethyl Ester, 97+%
| 51947-45-6 |
|
2-Bromo-5-Nitrothiazole, 98%
| 3034-48-8 |
|
Nickel (II) Chloride Hexahydrate
| 7791-20-0 |
|
9-Aminoacridine hemihydrate, 98%
| 90-45-9 |
|
3-Bromothiophene, 97+%
| 872-31-1 |
|
3-Aminobenzoic acid, 99+%
| 99-05-8 |
|
1,2,5,6,9,10-Hexabromocyclododecane, Tech.
| 3194-55-6 |
|
DL-Menthol, 99%
| 1490-04-6 |
|
2,4-Dimethyl-2,6-Heptadien-1-ol, 99%
| 80192-56-9 |
|
Nickel(II) nitrate hexahydrate
| 13138-45-9 |
|
Nickel (II) Oxide, Green or Black
| 1313-99-1 |
|
L-Tyrosine Hydrazide, 98%
| 7662-51-3 |
|
Germanium Dioxide, 99.999%, electronic grade
| 1310-53-8 |
|
DL-Propranolol Hydrochloride, 99%
| 318-98-9 |
|
Pentachlorocyclopropane, 98%
| 6262-51-7 |
|
Nickel (II) sulfate hexahydrate
| 10101-97-0 |
|
Phenylarsonic acid, 97%
| 98-05-5 |
|
3-[5-(Dimethylamino)-1-naphthalenesulfonamido]-PROXYL, free radical,
| 76841-99-1 |
|
Nickel (II) Carbonate
| 3333-67-3 |
|
Nickel (II) Ammomium Sulfate Hexahydrate
| 7785-20-8 |
|
Nicotine (pract), 95% (gc)
| 54-11-5 |
|
5(6)-Carboxyfluorescein disodium salt, monohydrate
| |
|
1,4-Dichloro-2-butyne, 99%
| 821-10-3 |
|
Poly(4-methoxystyrene)
| 24936-44-5 |
|
Benzothiazole, 97%
| 95-16-9 |
|
Fast garnet GBC, zinc chloride salt
| |
|
Diphenylamine Hydrochloride, 99% (Titr.)
| 537-67-7 |
|
Pentafluorobenzonitrile, 97+%
| 773-82-0 |
|
4-Hydrazinobenzoic Acid, 98% (Titr.)
| 619-67-0 |
|
Poly(chloroprene)
| 9010-98-4 |
|
4-Pyridinealdoxime, 98%
| 696-54-8 |
|
Duroquinone, 97%
| 527-17-3 |
|
Methyl isonicotinate, 98%
| 2459-09-8 |
|
Ninhydrin Monohydrate
| 485-47-2 |
|
Thallium (I) Bromide, 99%
| 7789-40-4 |
|
3-Phenoxybenzyl alcohol, 98%
| 13826-35-2 |
|
Trans-2-Heptenal, 97%
| 18829-55-5 |
|
syn-2-Pyridinealdoxime, 99+%
| 873-69-8 |
|
N-Acetylthiourea, 99.5%
| 591-08-2 |
|
1-(2,2-Diethoxyethyl)guanidine sulfate , 99%
| 52225-73-7 |
|
Nitric acid, red fuming
| 7697-37-2 |
|
Nitric acid, 20-70%
| 7697-37-2 |
|
Boc-Glycine, 99+%
| 4530-20-5 |
|
3,4-Dichlorophenylacetic Acid, 98%
| 5807-30-7 |
|
Trilaurin
| 538-24-9 |
|
2-Cyanoacetanilide, 98%
| 621-03-4 |
|
3-Methyl-2-quinoxalinol
| 14003-34-0 |
|
Nitrobenzene, reagent ACS
| 98-95-3 |
|
5-Chloro-2-pentanone, 97%
| 5891-21-4 |
|
|