**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 95-16-9 |Benzothiazole | 97 | 202-396-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
May cause mild eye irritation.
Skin:
May cause mild skin irritation. May be absorbed through the skin in
harmful amounts.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May cause
dizziness, incoordination, and unconsciousness.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use carbon dioxide, dry chemical powder or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Wash area with soap and water. Clean
up spills immediately, observing precautions in the Protective
Equipment section. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 95-16-9:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: yellow to brown
Odor: aromatic odor
pH: Not available.
Vapor Pressure: 34 mm Hg @131 deg C
Viscosity: Not available.
Boiling Point: 231 deg C @ 760.00mm Hg
Freezing/Melting Point: 2 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.2380g/cm3
Molecular Formula: C7H5NS
Molecular Weight: 135.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 95-16-9: DL0875000
LD50/LC50:
CAS# 95-16-9: Draize test, rabbit, eye: 100 uL/24H Mild; Draize
test, rabbit, skin: 500 uL/24H Mild; Oral, mouse: LD50 = 900 mg/kg;
Oral, rat: LD50 = 380 mg/kg.
Not available.
Carcinogenicity:
Benzothiazole -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 1.81-2.09 mg/L; 5,15,30
min; Microtox test at 15 C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 95-16-9: 2
Canada
CAS# 95-16-9 is listed on Canada's DSL List.
CAS# 95-16-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 95-16-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/15/1999 Revision #4 Date: 1/28/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cyclen, 97%
| 294-90-6 |
|
4-Hydroxy Benzylidene Malonic Acid Dimethyl Ester, 97+%
| 51947-45-6 |
|
2-Bromo-5-Nitrothiazole, 98%
| 3034-48-8 |
|
Nickel (II) Chloride Hexahydrate
| 7791-20-0 |
|
9-Aminoacridine hemihydrate, 98%
| 90-45-9 |
|
3-Bromothiophene, 97+%
| 872-31-1 |
|
3-Aminobenzoic acid, 99+%
| 99-05-8 |
|
1,2,5,6,9,10-Hexabromocyclododecane, Tech.
| 3194-55-6 |
|
DL-Menthol, 99%
| 1490-04-6 |
|
2,4-Dimethyl-2,6-Heptadien-1-ol, 99%
| 80192-56-9 |
|
Nickel(II) nitrate hexahydrate
| 13138-45-9 |
|
Nickel (II) Oxide, Green or Black
| 1313-99-1 |
|
L-Tyrosine Hydrazide, 98%
| 7662-51-3 |
|
Germanium Dioxide, 99.999%, electronic grade
| 1310-53-8 |
|
DL-Propranolol Hydrochloride, 99%
| 318-98-9 |
|
Pentachlorocyclopropane, 98%
| 6262-51-7 |
|
Nickel (II) sulfate hexahydrate
| 10101-97-0 |
|
Phenylarsonic acid, 97%
| 98-05-5 |
|
3-[5-(Dimethylamino)-1-naphthalenesulfonamido]-PROXYL, free radical,
| 76841-99-1 |
|
Nickel (II) Carbonate
| 3333-67-3 |
|
Nickel (II) Ammomium Sulfate Hexahydrate
| 7785-20-8 |
|
Nicotine (pract), 95% (gc)
| 54-11-5 |
|
5(6)-Carboxyfluorescein disodium salt, monohydrate
| |
|
1,4-Dichloro-2-butyne, 99%
| 821-10-3 |
|
Poly(4-methoxystyrene)
| 24936-44-5 |
|
Benzothiazole, 97%
| 95-16-9 |
|
Fast garnet GBC, zinc chloride salt
| |
|
Diphenylamine Hydrochloride, 99% (Titr.)
| 537-67-7 |
|
Pentafluorobenzonitrile, 97+%
| 773-82-0 |
|
4-Hydrazinobenzoic Acid, 98% (Titr.)
| 619-67-0 |
|
Poly(chloroprene)
| 9010-98-4 |
|
4-Pyridinealdoxime, 98%
| 696-54-8 |
|
Duroquinone, 97%
| 527-17-3 |
|
Methyl isonicotinate, 98%
| 2459-09-8 |
|
Ninhydrin Monohydrate
| 485-47-2 |
|
Thallium (I) Bromide, 99%
| 7789-40-4 |
|
3-Phenoxybenzyl alcohol, 98%
| 13826-35-2 |
|
Trans-2-Heptenal, 97%
| 18829-55-5 |
|
syn-2-Pyridinealdoxime, 99+%
| 873-69-8 |
|
N-Acetylthiourea, 99.5%
| 591-08-2 |
|
1-(2,2-Diethoxyethyl)guanidine sulfate , 99%
| 52225-73-7 |
|
Nitric acid, red fuming
| 7697-37-2 |
|
Nitric acid, 20-70%
| 7697-37-2 |
|
Boc-Glycine, 99+%
| 4530-20-5 |
|
3,4-Dichlorophenylacetic Acid, 98%
| 5807-30-7 |
|
Trilaurin
| 538-24-9 |
|
2-Cyanoacetanilide, 98%
| 621-03-4 |
|
3-Methyl-2-quinoxalinol
| 14003-34-0 |
|
Nitrobenzene, reagent ACS
| 98-95-3 |
|
5-Chloro-2-pentanone, 97%
| 5891-21-4 |
|
|