**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 98-05-5 |Benzenearsonic acid | 97 | 202-631-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects
was found.
Skin:
No information regarding skin irritation and other potential effects
was found.
Ingestion:
Low hazard for usual industrial handling.
Inhalation:
Low hazard for usual industrial handling.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid if irritation develops or persists. Flush skin with
plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
CAS# 98-05-5:
United Kingdom, WEL - TWA: (listed as arsenic compounds, n.o.s.):
mg/m3 TWA (except arsine, as As)
United Kingdom, WEL - STEL: (listed as arsenic compounds, n.o.s.)
0.3 mg/m3 STEL (except arsine, as As)
United States OSHA: 0.5 mg/m3 TWA (listed under Arsenic).
Belgium - TWA: (listed as arsenic): 0.01 mg/m3 VLE
Japan: (listed as arsenic compounds, n.o.s.): 3 ??g/m3 OEL (refere
value, as As)
Malaysia: (listed as arsenic): 0.01 mg/m3 TWA
Netherlands: (listed as arsenic): 0.050 mg/m3 MAC
Spain: (listed as arsenic compounds, n.o.s.): 0.1 mg/m3 VLA-ED (a
As)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 160 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: SPARINGLY SOLUBLE IN WATER (20C)
Specific Gravity/Density:
Molecular Formula: C6H7AsO3
Molecular Weight: 202.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
None.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-05-5: CY3150000
LD50/LC50:
CAS# 98-05-5: Oral, mouse: LD50 = 270 ug/kg.
Carcinogenicity:
Benzenearsonic acid -
IARC: Group 1 carcinogen (listed as Arsenic).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.*
Hazard Class: 6.1
UN Number: 3280
Packing Group: II
IMO
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3280
Packing Group: II
RID/ADR
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3280
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 98-05-5: 3
Canada
CAS# 98-05-5 is listed on Canada's DSL List.
CAS# 98-05-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 98-05-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cyclen, 97%
| 294-90-6 |
|
4-Hydroxy Benzylidene Malonic Acid Dimethyl Ester, 97+%
| 51947-45-6 |
|
2-Bromo-5-Nitrothiazole, 98%
| 3034-48-8 |
|
Nickel (II) Chloride Hexahydrate
| 7791-20-0 |
|
9-Aminoacridine hemihydrate, 98%
| 90-45-9 |
|
3-Bromothiophene, 97+%
| 872-31-1 |
|
3-Aminobenzoic acid, 99+%
| 99-05-8 |
|
1,2,5,6,9,10-Hexabromocyclododecane, Tech.
| 3194-55-6 |
|
DL-Menthol, 99%
| 1490-04-6 |
|
2,4-Dimethyl-2,6-Heptadien-1-ol, 99%
| 80192-56-9 |
|
Nickel(II) nitrate hexahydrate
| 13138-45-9 |
|
Nickel (II) Oxide, Green or Black
| 1313-99-1 |
|
L-Tyrosine Hydrazide, 98%
| 7662-51-3 |
|
Germanium Dioxide, 99.999%, electronic grade
| 1310-53-8 |
|
DL-Propranolol Hydrochloride, 99%
| 318-98-9 |
|
Pentachlorocyclopropane, 98%
| 6262-51-7 |
|
Nickel (II) sulfate hexahydrate
| 10101-97-0 |
|
Phenylarsonic acid, 97%
| 98-05-5 |
|
3-[5-(Dimethylamino)-1-naphthalenesulfonamido]-PROXYL, free radical,
| 76841-99-1 |
|
Nickel (II) Carbonate
| 3333-67-3 |
|
Nickel (II) Ammomium Sulfate Hexahydrate
| 7785-20-8 |
|
Nicotine (pract), 95% (gc)
| 54-11-5 |
|
5(6)-Carboxyfluorescein disodium salt, monohydrate
| |
|
1,4-Dichloro-2-butyne, 99%
| 821-10-3 |
|
Poly(4-methoxystyrene)
| 24936-44-5 |
|
Benzothiazole, 97%
| 95-16-9 |
|
Fast garnet GBC, zinc chloride salt
| |
|
Diphenylamine Hydrochloride, 99% (Titr.)
| 537-67-7 |
|
Pentafluorobenzonitrile, 97+%
| 773-82-0 |
|
4-Hydrazinobenzoic Acid, 98% (Titr.)
| 619-67-0 |
|
Poly(chloroprene)
| 9010-98-4 |
|
4-Pyridinealdoxime, 98%
| 696-54-8 |
|
Duroquinone, 97%
| 527-17-3 |
|
Methyl isonicotinate, 98%
| 2459-09-8 |
|
Ninhydrin Monohydrate
| 485-47-2 |
|
Thallium (I) Bromide, 99%
| 7789-40-4 |
|
3-Phenoxybenzyl alcohol, 98%
| 13826-35-2 |
|
Trans-2-Heptenal, 97%
| 18829-55-5 |
|
syn-2-Pyridinealdoxime, 99+%
| 873-69-8 |
|
N-Acetylthiourea, 99.5%
| 591-08-2 |
|
1-(2,2-Diethoxyethyl)guanidine sulfate , 99%
| 52225-73-7 |
|
Nitric acid, red fuming
| 7697-37-2 |
|
Nitric acid, 20-70%
| 7697-37-2 |
|
Boc-Glycine, 99+%
| 4530-20-5 |
|
3,4-Dichlorophenylacetic Acid, 98%
| 5807-30-7 |
|
Trilaurin
| 538-24-9 |
|
2-Cyanoacetanilide, 98%
| 621-03-4 |
|
3-Methyl-2-quinoxalinol
| 14003-34-0 |
|
Nitrobenzene, reagent ACS
| 98-95-3 |
|
5-Chloro-2-pentanone, 97%
| 5891-21-4 |
|
|