**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 150-76-5 |4-Methoxyphenol | < 0.1 | 205-769-8 |
|----------------|--------------------------------------|----------|-----------|
| 376-14-7 |2-(N-Ethylperfluorooctanesulfonamido)e| 100 | 206-805-5 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin. The toxicological properties of this material have not been
fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated. May be
harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May be harmful if
inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Polymerizes
readily if not inhibited; heat can initiate reaction.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation. Do not let this chemical
enter the environment.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 92-84-2:
Belgium - TWA: 5 mg/m3 VLE
France - VME: 5 mg/m3 VME
Malaysia: 5 mg/m3 TWA
Netherlands: 5 mg/m3 MAC
Spain: 5 mg/m3 VLA-ED
CAS# 150-76-5:
Belgium - TWA: 5 mg/m3 VLE
France - VME: 5 mg/m3 VME
Germany: 5 mg/m3 TWA
Malaysia: 5 mg/m3 TWA
Netherlands: 5 mg/m3 MAC
Spain: 5 mg/m3 VLA-ED
CAS# 376-14-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 48-55 C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C16H14F17NO4S
Molecular Weight: 639.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable only if stored and handled under recommended conditions. The
stability of the product depends upon the availability of both
dissolved oxygen and MEHQ inhibitor(CAS=150-76-5). The presence of
oxygen is necessary for the MEHQ to function effectively. The
product should never be stored under an inert gas atmosphere, but
should always be stored under an atmosphere containing 5-21% oxygen
by volume.
Conditions to Avoid:
Dust generation, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents, polymerizing initiators.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide, hydrogen fluoride gas.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 92-84-2: SN5075000
CAS# 150-76-5: SL7700000
CAS# 376-14-7 unlisted.
LD50/LC50:
CAS# 92-84-2: Oral, mouse: LD50 = 5 gm/kg; Oral, rabbit: LD50 = 4
gm/kg.
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent)
Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
CAS# 376-14-7.
Carcinogenicity:
Phenothiazine -
Not listed by ACGIH, IARC, or NTP.
4-Methoxyphenol -
Not listed by ACGIH, IARC, or NTP.
2-(N-Ethylperfluorooctanesulfonamido)ethyl methacrylate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 92-84-2: 2
CAS# 150-76-5: 1
CAS# 376-14-7: 2
Canada
CAS# 92-84-2 is listed on Canada's DSL List.
CAS# 150-76-5 is listed on Canada's DSL List.
CAS# 376-14-7 is listed on Canada's NDSL List.
CAS# 92-84-2 is listed on Canada's Ingredient Disclosure List.
CAS# 150-76-5 is listed on Canada's Ingredient Disclosure List.
CAS# 376-14-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 92-84-2 is listed on the TSCA inventory.
CAS# 150-76-5 is listed on the TSCA inventory.
CAS# 376-14-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 12/28/1998 Revision #4 Date: 11/26/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2',4'-Dimethylacetoacetanilide
| 97-36-9 |
|
2,5-Dihydroxybenzoic Acid, 99%
| 490-79-9 |
|
Mandelonitrile, tech.
| 532-28-5 |
|
N-Acetylsulfanilyl Chloride, 99%(Titr.)
| 121-60-8 |
|
DL-Amethopterin hydrate
| 60388-53-6 |
|
D-Ethionine, 98%
| 535-32-0 |
|
Boron trichloride, 1M solution in methylene chloride
| 75-09-2 |
|
2,4,4-Trimethyl-2-Oxazoline, 99%
| 1772-43-6 |
|
4-Nitrophenyl Isothiocyanate
| 2131-61-5 |
|
Norephedrine Hydrochloride, 98% (Titr.)
| 3195-78-6 |
|
Diethyl phenylphosphonite, 99%
| 1638-86-4 |
|
2,3-Dichlorobutane, 98%
| 7581-97-7 |
|
1,1-Diphenylethylene, 99% (GC)
| 530-48-3 |
|
2-(N-Ethylperfluorooctanesulfonamido)ethyl methacrylate, stab. w/
| 92-84-2 |
|
1-Hydroxybenzotriazole, 98%
| 2592-95-2 |
|
3',4'-Dimethylacetophenone, 97%
| 3637-01-2 |
|
4-Chloro-alpha-methylbenzylamine, 97%
| 6299-02-1 |
|
4-Phenylazophenol, 97% (UV-Vis)
| 1689-82-3 |
|
Diethyl oxalate, 99%
| 95-92-1 |
|
l-Lysine dihydrochloride, 99%
| 657-26-1 |
|
2-Iodobenzoyl Chloride, 98+%
| 609-67-6 |
|
2-Chloronicotinamide, 98%
| 10366-35-5 |
|
2-Thenylmercaptan, 98%
| 6258-63-5 |
|
2-??4-(4-dimethylaminophenyl)-1,3- butadienyl??-3-ethylbenzothiazolium
| 114720-33-1 |
|
3-Chloro-2-methylpropionitrile, tech., 85+%
| 7659-45-2 |
|
Sodium Deuteroxide (30 wt. % Solution in D2O), 99+ Atom % D
| 7732-18-5 |
|
Succinyl chloride, ca 95 %
| 543-20-4 |
|
2-Chloro-4-fluorobenzyl chloride, 98%
| 93286-22-7 |
|
1-(2,4-Dichlorophenyl)-1-Propanone 95%
| 37885-41-9 |
|
3-Ethoxyphenol, 98% (gc)
| 621-34-1 |
|
Rhodium on alumina powder (5% rh)
| |
|
Dibutyltin bis(2-ethylhexanoate)
| 2781-10-4 |
|
2,4-Diamino-6-phenyl-s-triazine, 99+% (titr.)
| 91-76-9 |
|
Ethyl Methylcarbamate, 99% (GC)
| 105-40-8 |
|
(4-Aminophenyl)trimethylammonium iodide hydrochloride, 94%
| 62654-12-0 |
|
2,2,5,5-Tetramethyl-3-Pyrrolidine- Carboxamide
| 702-96-5 |
|
Celestine blue
| 1562-90-9 |
|
1-(2-Furyl)-1,3-butanedione
| 25790-35-6 |
|
N-alpha-Benzoyl-dl-arginine-p-nitroanilide hydrochloride, 99+%
| 911-77-3 |
|
Hydroxy Naphthol Blue, Disodium Salt, P.A.
| 29114-66-7 |
|
Linoleic acid (techn), 60% (gc)
| 60-33-3 |
|
Octafluorotoluene, 98%
| 434-64-0 |
|
Cacodylic acid sodium salt, trihydrate
| 124-65-2 |
|
2-Methoxyethyl Acetoacetate, 97%
| 22502-03-0 |
|
2-(2-Thienyl)pyridine, 97+%
| 3319-99-1 |
|
Naphthol green b
| 19381-50-1 |
|
2,4,5-Trimethyloxazole, 95%
| 20662-84-4 |
|
P-Arsanilic Acid, 99% (UV-Vis)
| 98-50-0 |
|
(S)-(+)-10-Methyl-1(9)-Octal-2-One,98.5%
| 4087-39-2 |
|
Indole-3-pyruvic acid , 97%
| 392-12-1 |
|
|