2-propanoic acid, 2-cyano-, ethyl ester; (ethyl cyanoacrylate) polymethylmethacrylate silica, amorphous (fumed); (silica, amorphous treated) hydroquinone (sara 302/313) (cercla) volatile organic content: 76% (epa method 24) sup dat: skin adhesion: first immerse bonded surf in warm, soapy water. ing 6: of blunt edge, e.g. spatula/teaspoon handle; then remove adhesive ing 7:pull surf apart w/direct opposing action. eyelid to eyelid/eyeball ing 8: stuck together/bonded to eyeball, wash thoro w/warm water & ing 9: further action, typically in 1-4 days. there will be no residual ing 10: manipulation. adhesive on eyeball: cyanoacrylate introduced into ing 11: & will disassociate from it over intermittent periods, gen ing 12: periods of weeping until clearance achieved. during period of ing 13: together w/lachrymatory eft, & it is important to understand ing 14: will norm occur w/in matter of hrs, even w/gross contam. mouth: ing 15: apply lots of warm water to lips & encourage max wetting ing 16: lips apart. do not try to pull lips w/direct opposing action. it ing 17: cyanoacrylate. adhesive solidifies & adheres in mouth. saliva ing 18: case a lump forms in mouth, position patient to prevent ingest of ing 19: cyanoacrylates give off heat on solidification. in rare cases a ing 20: cause a burn. burbs should be treated norm after lump of ing 21: described above. surgery: it hould never be nec to use such a ing 22: bonded skin. inhalation: remove to fresh air. support breathing
LOCTITE CORPORATION -- SUPER BONDER 409 INDUST GRADE GEL INST ADH, 4
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BXQXT
MSDS NAME: SUPER BONDER 409 INDUST GRADE GEL INST ADH, 40945
Responsible Party
Name: LOCTITE CORPORATION
Address: 705 NORTH MOUNTAIN RD
City: NEWINGTON CT 06111
Info Phone: 203-278-1280
Emergency Phone Number: 203-278-1280
Preparer's Name: STEPHEN REPETTO
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
=======================================================
Ingredients
=======================================================
Cas: 7085-85-0
RTECS #: UD3330000
Name: 2-PROPANOIC ACID, 2-CYANO-, ETHYL ESTER; (ETHYL CYANOACRYLATE)
% Wt: 85-90
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 112945-52-5
RTECS #: VV7310000
Name: SILICA, AMORPHOUS (FUMED); (SILICA, AMORPHOUS TREATED)
% Wt: 5-10
OSHA PEL: 6 MG/M3
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE (SARA 302/313) (CERCLA)
% Wt: 0.1-0.5
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC CONTENT: 76% (EPA METHOD 24)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUP DAT: SKIN ADHESION: FIRST IMMERSE BONDED SURF IN WARM, SOAPY WATER.
PEEL/ROLL SURF APART W/AID
-----------------------------
Name: ING 6: OF BLUNT EDGE, E.G. SPATULA/TEASPOON HANDLE; THEN REMOVE ADHESIVE
FROM SKIN W/SOAP & WATER. DO NOT TRY TO
-----------------------------
Name: ING 7:PULL SURF APART W/DIRECT OPPOSING ACTION. EYELID TO EYELID/EYEBALL
ADHESION: IN THE EVENT THAT EYELIDS ARE
-----------------------------
Name: ING 8: STUCK TOGETHER/BONDED TO EYEBALL, WASH THORO W/WARM WATER &
APPLY GAUZE PATCH. THE EYE WILL OPEN W/OUT
-----------------------------
Name: ING 9: FURTHER ACTION, TYPICALLY IN 1-4 DAYS. THERE WILL BE NO RESIDUAL
DMG. DO NOT TRY TO OPEN EYES BY
-----------------------------
Name: ING 10: MANIPULATION. ADHESIVE ON EYEBALL: CYANOACRYLATE INTRODUCED INTO
EYES WILL ATTACH ITSELF TO EYE PROTEIN
-----------------------------
Name: ING 11: & WILL DISASSOCIATE FROM IT OVER INTERMITTENT PERIODS, GEN
COVERING SEVERAL HRS. THIS WILL CAUSE
-----------------------------
Name: ING 12: PERIODS OF WEEPING UNTIL CLEARANCE ACHIEVED. DURING PERIOD OF
CONTAM, DOUBLE VISION MAY BE EXPERIENCED
-----------------------------
Name: ING 13: TOGETHER W/LACHRYMATORY EFT, & IT IS IMPORTANT TO UNDERSTAND
THE CAUSE & REALIZE THAT DISASSOCIATION
-----------------------------
Name: ING 14: WILL NORM OCCUR W/IN MATTER OF HRS, EVEN W/GROSS CONTAM. MOUTH:
IF LIPS ARE ACCIDENTLY STUCK TOGETHER,
-----------------------------
Name: ING 15: APPLY LOTS OF WARM WATER TO LIPS & ENCOURAGE MAX WETTING
& PRESS FROM SALIVA INSIDE MOUTH. PEEL/ROLL
-----------------------------
Name: ING 16: LIPS APART. DO NOT TRY TO PULL LIPS W/DIRECT OPPOSING ACTION. IT
IS ALMOST IMPOSS TO SWALLOW
-----------------------------
Name: ING 17: CYANOACRYLATE. ADHESIVE SOLIDIFIES & ADHERES IN MOUTH. SALIVA
WILL LIFT ADHESIVE IN ONE HALF-2 DAYS. IN
-----------------------------
Name: ING 18: CASE A LUMP FORMS IN MOUTH, POSITION PATIENT TO PREVENT INGEST OF
LUMP WHEN IT DETACHES. BURNS:
-----------------------------
Name: ING 19: CYANOACRYLATES GIVE OFF HEAT ON SOLIDIFICATION. IN RARE CASES A
LGE DROP WILL INCR IN TEMP ENOUGH TO
-----------------------------
Name: ING 20: CAUSE A BURN. BURBS SHOULD BE TREATED NORM AFTER LUMP OF
CYANOACRYLATE IS RELEASED FROM TISS AS
-----------------------------
Name: ING 21: DESCRIBED ABOVE. SURGERY: IT HOULD NEVER BE NEC TO USE SUCH A
DRASTIC METH TO SEPARATE ACCIDENTALLY
-----------------------------
Name: ING 22: BONDED SKIN. INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING
(GIVE OXYGEN OR ARTIFICIAL RESPIRATION) (FP N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50 (ORAL RAT): > 5000 MG/KG.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: SKIN CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY
AND STRONGLY. SKIN AND EYE IRRITANT. VAPOR IS IRRITATING TO EYES AND MUCOUS
MEMBRANES ABOVE TLV. PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS M AY
PRODUCE ALLERGIC REACTIONS W/ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS.
CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: CYANOACRYLATE ADHESIVE IS A VERY FAST SETTING & STRONG ADHESIVE.
IT BONDS HUMAN TISS INCL SKIN IN SEC. EXPERIENCE HAS SHOWN THAT ACCIDENTS DUE
TO CYANOACRYLATES ARE HANDLED BEST BY PASSIVE, NONSURGICA L FIRST AID.
TREATMENT OF SPECIFIC TYPES OF ACCIDENTS ARE GIVEN BELOW. SKIN: REMOVE EXCESS
ADHESIVE. SOAK IN WARM, SOAPY WATER. ADHESIVE WILL COME LOOSE FROM SKIN IN
SEVERAL HRS. CURED (SUP DAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE COMPLETELY. SOAK UP
WITH AN INERT ABSORBENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: POLYMERIZE AS ABOVE. INCINERATE FOLLOWING EPA AND
LOCAL, STATE, AND FEDERAL REGULATIONS.
Handling And Storage Precautions: STORE BELOW 75F TO PRESERVE SHELF LIFE. AVOID
CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >150F,>66C
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: IRRITATING ORGANIC FRAGMENTS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: NITRILE OR POLYETHYLENE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: WEAR NITRILE OR POLYETHYLENE APRONS WHEN HANDLING
LARGE AMOUNTS. DO NOT USE COTTON.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: MATLS TO AVOID: MAY CAUSE POLYMERIZATION.
POLYMERIZATION OF LARGE AMOUNTS OF ADHESIVE WILL GENERATE HEAT CAUSING SMOKE,
SKIN BURNS, AND STRONG, IRRITATING VAPORS. FIRST AID PROC: ADHESIVE DOES NOT
PRE SENT A HEALTH HAZARD EVEN WHEN BONDED TO SKIN.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >300F,>149C
Vapor Pres: <0.2 @ 80F
Vapor Density: 3
Spec Gravity: 1.1 @ 80F
Solubility in Water: POLYMERIZED BY WATER
Appearance and Odor: CLEAR LIQUID WITH SHARP, IRRITATING ODOR
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: POLYMERIZED BY WATER, ALCOHOLS, AMINES/ALKALIES. AVOID CONT
W/CLTHG, FABRICS, RAGS/TISS. CONT W/THESE MATLS (SUP DAT)
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SUPER BONDER 409 INDUST GRADE GEL INST ADH, 40945
Company: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT
Zipcode: 06067-3910
Health Emergency Phone: 203-278-1280
Label Required IND: Y
Date Of Label Review: 05/18/1995
Status Code: C
Label Date: 05/18/1995
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: COMBUSTIBLE. POLYMERIZES WITH WATER. ACUTE: SKIN
CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE
IRRITANT. VAPOR IS IRRITATING TO EYES AND MUCOUS MEMBRANES ABOVE TLV.
PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAYPRODUCE ALLERGIC REACTIONS
W/ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS. CHRONIC: NONE SPECIFIED BY
MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.