LCI (LUCIER CHEMICAL INDUSTRIE -- FLUOROSILICIC ACID
=======================================================
Material Safety Data Sheet
=======================================================
NIIN: 00-594-6375
MSDS Num: CCSTG
MSDS NAME: FLUOROSILICIC ACID
Responsible Party
Name: LCI (LUCIER CHEMICAL INDUSTRIES) LTD
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Info Phone: 904-241-1200
Emergency Phone Number: 904-241-1200, CHEMTREC 800-424-9300
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Address: 415 PABLO AVE N
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Phone: 904-241-1200
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: HYDROFLUOSILICIC ACID
Unit of Issue: DR
Quantitative Expression: 00000000500LB
UI Container Qty: 1
Type of Container: DRUM
=======================================================
Ingredients
=======================================================
Cas: 16961-83-4
RTECS #: VV8225000
Name: HYDROFLUOROSILICIC ACID
% Wt: 24+1%
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: 74+1%
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: TLV: 2.5 MG/ME AS F
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: LIQUID VAPORS CAN CAUSE SEVERE IRRITATION &
BURNS WHICH MAY NOT BE APPARENT FOR HOURS. CAN CAUSE SEVRE IRRITATION TO THE
LUNGS, NOSE & THROAT. IF SWALLOWED, CAN CAUSE SEVERE DAMAGE TO THROAT AN
D STOMACH. CHRONIC: PROLONGED EXPOSURE COULD RESULT IN BONE CHANGES,
CORROSIVE EFFECTS OF MUCOUS MEMBRANES.
Explanation Of Carcinogenicity: NOT CARCINOGENIC.
Signs And Symptions Of Overexposure: ULCERATION OF NOSE, THROAT AND BRONCHIAL
TUBES, COUGH, SHOCK, PULMONARY EDEMA, FLUOROSIS, COMA AND DEATH.
Medical Cond Aggravated By Exposure: ANY SKIN CONDITION AND/OR PREEXISTING
RESPIRATORY DISEASE INCLUDING ASTHMA AND EMPHYSEMA.
First Aid: INHALATION-REMOVE EXPOSED PERSON TO AN UNCONTAMINATED AREA
IMMEDIATELY. IF BREATHING HAS STOPPED, PERFORM CPR. PROVIDE OXYGEN. CONTACT
PHYSICIAN. EYE-FLUSH EYES FOR 15 MIN WITH WATER. OBTAIN MEDICAL A TTENTION
IMMEDIATELY. SKIN-REMOVE TO UNCONTAMINATED AREA & SUBJECT TO DRENCH
SHOWER FOR 15-20 MIN. REMOVE CLOTHING. OBTAIN MEDICAL AID. INGESTION-GIVE
WATER TO DILUTE. DO NOT INDUCE VOMIT. GET AID.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: ANY PERSON IN AREA SHOULD WEAR A NIOSH APPROVED AIR
SUPPLIED ACID SUIT. DIKE AREA TO CONTAIN MATERIAL. DO NOT ALLOW AOLUTION TO
ENTER SEWERS/WATER. TAKE UP WITH SAND OR NON-COMBUSTIBLE ABSORBENT MATER IAL
& PLACE IN CONTAINER FOR LATER DISPOSAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSER MUST COMPLY WITH FEDERAL, STATE AND LOCAL
DISPOSAL OR DISCHARGE LAWS.
Handling And Storage Precautions: STORE IN CONTAINERS IN COOL DRY WELL
VENTILATED AREA AWAY FROM SOURCES OF HEAT OR IGNITION. DO NOT STORE IN GLASS
OR STONEWARE.
Other Precautions: USE NON-SPARKING TOOLS. KEEP SEPERATE FROM ALKALI METALS,
OXIDIZING AGENTS, COMBUSTIBLE SOLIDS ADN ORGANIC PEROXIDES. DO NOT INHALE
FUMES AND PREVENT SKIN CONTACT.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: USE AGENT WHICH IS APPROPIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures: WEAR NIOSH APPROVED SELF-CONTAINED ACID SUITS.
Unusual Fire/Explosion Hazard: REACTS WITH MANY METALS TO PRODUCE FLAMMABLE AND
EXPLOSIVE HYDROGEN GAS. KEEP CONTAINER COOL WITH WATER, USING NOZZLE, AS
DECOMPOSITION WILL OCCUR ABOVE 227F.
=======================================================
Control Measures
=======================================================
Respiratory Protection: A NIOSH APPROVED CARTRIDGE RESPIRATOR WITH FULL-FACE
SHIELD. CHEMICAL CARTRIDGE SHOULD PROVIDE PROTECTION AGAINST ACID FUMES. FOR
CONCENTRATIONS GREATER THAN 20PPM, A NIOSH APPROVED SELF-CONTAINED BRE ATHING
APPARATUS W/FULL FACE SHIELD.
Ventilation: GENERAL OR LOCAL EXHAUST SYSTEM SUFFICIENT TO MAINTAIN VAPORS
BELOW 2.5 MG/M3.
Protective Gloves: ACID-PROOF GLOVES.
Eye Protection: TIGHT FITTING CHEMICAL SPLASH GOGGLES
Other Protective Equipment: ACID PROOF CLOTHING, GLOVES AND SHOES. USE A NIOSH
APPROVED ACID PROOF SUIT & BOOTS WHERE LIQUID OR HIGH VAPOR POSSIBLE.
Work Hygienic Practices: EYE WASH AND EMERGENCY SHOWER FACILITY SHOULD BE
AVAILABLE IN HANDLING AREA. CONTACT LENSES SHOULD NOY BE WORN.
Supplemental Safety and Health: USE FULL, FACE SHIELD.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: C1
B.P. Text: 222F,106C
M.P/F.P Text: -4F,-20C
Vapor Pres: 218 MMHG
Vapor Density: 10.21 LB/G
Spec Gravity: 1.223
PH: 12
Solubility in Water: COMPLETE
Appearance and Odor: WATER WHITE TO STRAW YELLOW FUMING LIQUID WITH PUNGENT
ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: METAL, GLASS, STONEWARE, ALKALI AND STRONG CONCENTRATED
ACIDS.
Hazardous Decomposition Products: WHEN HEATED TO DECOMPOSITION, IT EMITS HIGHLY
TOXIC AND CORROSIVE FUMES OF HYDROGEN FLUORIDE, SILICA TETRAFLUORIDE & H.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 78365
MSDS NAME: FLUOROSILICIC ACID
MSDS Prepared Date: 05/01/1993
Review Date: 02/14/1997
Net Unit Weight: 500 LB
AF MMAC Code: NR
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 1
Type Of Container: DRUM
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: GMU
DOT Proper Shipping Name: FLUOROSILICIC ACID
Hazard Class: 8
UN ID Num: UN1778
DOT Packaging Group: II
Label: CORROSIVE
Special Provision: A6,A7,B2,B15,N3,N34,T12,T27
Packaging Exception: NONE
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 1 L
Max Qty Cargo: 30 L
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: HLP
IMO Proper Shipping Name: FLUOROSILICIC ACID
IMDG Page Number: 8176
UN Number: 1778
UN Hazard Class: 8
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 8-06
MED First Aid Guide NUM: 750
=======================================================
Detail IATA Information
=======================================================
IATA PSN CK
IATA UN ID Num: 1992
IATA Proper Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S. *
IATA UN Class: 3
Subsidiary Risk Class: 6.1
IATA Label: FLAMMABLE LIQUID & TOXIC
UN Packing Group: II
Packing Note Passenger: 305
Max Quant Pass: 1L
Max Quant Cargo: 60L
Packaging Note Cargo: 307
=======================================================
Detail AFI Information
=======================================================
AFI PSN CK
AFI Symbols: *
AFI Proper Shipping Name: FLAMMABLE LIQUIDS, POISONOUS, N.O.S.
AFI Hazard Class: 3
AFI UN ID NUM: UN1992
AFI Packing Group: II
AFI Label: 6.1
Special Provisions: P4
Back Pack Reference: A7.3
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: FLUOROSILICIC ACID
Company: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Street: 415 PABLO AVE N
PO Box: 49000
City: JACKSONVILLE BEACH FL
Zipcode: 32240-9000
Health Emergency Phone: 904-241-1200, CHEMTREC 800-424-9300
Label Required IND: Y
Date Of Label Review: 02/14/1997
Status Code: C
Label Date: 02/14/1997
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: SPILL: ANY PERSON IN AREA SHOULD WEAR A NIOSH APPROVED
AIR SUPPLIED ACID SUIT. DIKE AREA TO CONTAIN MATERIAL. DO NOT ALLOW AOLUTION
TO ENTER SEWERS/WATER. TAKE UP WITH SAND OR NON-COMBUSTIBLE ABSORBEN T
MATERIAL & PLACE IN CONTAINER FOR LATER DISPOSAL. FIRST AID:
INHALATION-REMOVE EXPOSED PERSON TO AN UNCONTAMINATED AREA IMMEDIATELY. IF
BREATHING HAS STOPPED, PERFORM CPR. PROVIDE OXYGEN. CONTACT PH YSICIAN.
EYE-FLUSH EYES FOR 15 MIN WITH WATER. OBTAIN MEDICAL ATTENTION IMMEDIATELY.
SKIN-REMOVE TO UNCONTAMINATED AREA & SUBJECT TO DRENCH SHOWER FOR 15-20
MIN. REMOVE CLOTHING. OBTAIN MEDICAL AID. I NGESTION-GIVE WATER TO DILUTE. DO
NOT INDUCE VOMIT
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|
| ALL PAGES On Chemical Property IN THIS GROUP
| | NAME | CAS |
|
HYDROXYLAMINE HYDROCHLORIDE, 3% TO 50%, LC15540
| 5470-11-1
7732-18-5 |
|
HYDROXYLAMINE HYDROCHLORIDE, 3% TO 50%, LC15550
| 5470-11-1
7732-18-5 |
|
SERIES IV TONER CARTRIDGE
| |
|
PERMATEX CHAIN LUBE, 122GA
| 71-55-6
8008-20-6
74-98-6 |
|
CATALYST SOLUTION B-5, HD5005
| |
|
ETHYLENE GLYCOL, C00057
| 107-21-1 |
|
OXYGEN, COMPRESSED
| 7782-44-7 |
|
IRIDITE 14, 78658
| |
|
CHEMLOK 8007
| 111-76-2
50-00-0
1314-13-2 |
|
POTASSIUM PERSULFATE 5%, LC20080
| 7727-21-1
7732-18-5 |
|
ACCUFAX CODE 70920
| 112945-52-5
31714-55-3
1309-37-1
9003-07-4
26655-10-7 |
|
PROFESSIONAL LINE DAWN, 08082
| 64-17-5
7732-18-5 |
|
PROFESSIONAL LINE DAWN, 08764
| 64-17-5
7732-18-5 |
|
PROFESSIONAL LINE DAWN, 08460
| 64-17-5
7732-18-5 |
|
PROFESSIONAL LINE DAWN, 08536
| 64-17-5
7732-18-5 |
|
PROFESSIONAL LINE DAWN, 08684
| 64-17-5
7732-18-5 |
|
PROFESSIONAL LINE DAWN, 08095
| 64-17-5
7732-18-5 |
|
PROFESSIONAL LINE DAWN, 08047
| 64-17-5
7732-18-5 |
|
PROFESSIONAL LINE DAWN, 08021
| 64-17-5
7732-18-5 |
|
PROFESSIONAL LINE DAWN, 08077
| 64-17-5
7732-18-5 |
|
C10
| |
|
DRI WASH'N GUARD WATERLESS WASH & PROTECTIVE GLAZE
| 8008-20-6 |
|
INHIBITED RED FUMING NITRIC ACID L61
| 7697-37-2
10544-72-6
7664-39-3
7732-18-5 |
|
QM 1, 03384
| 1310-73-2 |
|
SURFACE TREATED & PROCESSED CELLULOSE FIBERS
| 9004-34-6
7429-90-5
7429-90-5
7439-89-6
12001-26-2
7429-90-5 |
|
OIL-PRECISION B+, 69125, CPS253000
| 64742-54-7 |
|
SERPIFLEX SHIELD (AEROSOL) SSA12
| 107-21-1 |
|
PPC DEVELOPER TYPE 1, 888455
| |
|
10-100 PPM CARBON MONOXIDE, 10 PPM-2.5% (SUP DAT)
| 630-08-0
74-82-8
7782-44-7
7727-37-9 |
|
LUSTER-GUARD, 0918
| |
|
HITEC 580 PERFORMANCE ADDITIVE
| |
|
FLUOROSILICIC ACID
| 16961-83-4
7732-18-5 |
|
IRIDITE 14-2, 24010
| |
|
E 100 ALL SOL FLUX
| 12125-02-9
7647-01-0
7646-85-7 |
|
RYDLYME, RID-LIME
| |
|
H-7 PUT A HALT TO RUST
| |
|
H-8 PUT A HALT TO RUST
| |
|
H-6 PUT A HALT TO RUST
| |
|
H-5 PUT A HALT TO RUST
| |
|
PF
| |
|
60-9800-1020-5 00-51144-14061-9, GLASS (SUPDAT)
| 7732-18-5
1306-38-3 |
|
HYDROSEP (BACTERIOSTATIC ADDITIVE)
| 18472-51-0 |
|
MANCOZEB DG
| 8018-01-7
7440-66-6
30525-89-4 |
|
SODIUM NITRATE
| |
|
DEER-AWAY BIG GAME REPELLENT FORMULA 2104
| |
|
4019 CORROSION INHIBITOR
| |
|
ARGON
| 7440-37-1 |
|
NITROUS OXIDE
| 10024-97-2 |
|
ADHESIVE-CARRIER-LINER LAMINATE, 1173D
| |
|
POLISH AND SEALANT, DRI WASH'N GUARD FOR (SUP DAT)
| 8008-20-6 |
|
|