DOWELL SCHLUMBERGER -- INHIBITED RED FUMING NITRIC ACID L61
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Material Safety Data Sheet
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MSDS Num: CCSPP
MSDS NAME: INHIBITED RED FUMING NITRIC ACID L61
Responsible Party
Name: DOWELL SCHLUMBERGER
Box: 2710
City: TULSA OK 74101
Info Phone: 918-582-0104
Emergency Phone Number: 918-582-0104
Preparer's Name: W.W. SHEPHERD
Published: Y
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Contractor Summary
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Name: DOWELL SCHLUMBERGER
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
Name: DOWELL SCHLUMBERGER
Box: 21
City: TULSA OK 74102
Phone: (918) 582-0104
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Ingredients
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Cas: 7697-37-2
RTECS #: QU5775000
Name: NITRIC ACID; (HNO3) (SARA 302/313) (CERCLA)
OSHA PEL: 2 PPM
ACGIH TLV: 2 PPM; 4 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 10544-72-6
RTECS #: QX1575000
Name: NITROGEN TETROXIDE; (NITROGEN DIOXIDE) (NO2) (CERCLA)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 7664-39-3
RTECS #: MW7875000
Name: HYDROFLUORIC ACID; (HYDROGEN FLUORIDE) (HF) (SARA 302/313) (CERCLA)
% Wt: <1
OSHA PEL: 3 PPM (F)
ACGIH TLV: 3 PPM (F) C
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
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Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER; (H*2O)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: CORROSIVE. RAPIDLY CAUSES PAIN, BURNS, CORNEAL
INJURY. MAY CAUSE PERMANENT DAMAGE & BLINDNESS. SKIN: TOXIC. CORROSIVE.
CAN CAUSE ILLNESS OR DEATH. RAPIDLY CAUSES BURNS, TISSUE DAMAGE & PAIN.
ING EST: TOXIC. CORROSIVE. CAUSES PAIN & SEVERE BURNS TO MOUTH, THROAT
& STOMACH. CAN CAUSE ILLNESS/DEATH. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: INHAL: TOXIC. CORROSIVE. VERY
DANGEROUS. POOR WARNING PROPERTIES. MAY CAUSE COUGHING, DIFFICULT BREATHING,
PULMONARY EDEMA & DEATH. EFFECTS MAY NOT APPEAR FOR SEVERAL HOURS OR A
FEW DAYS AFT ER EXPOSURE. OTHER: 50 PPM AS VAPOR IS IRRITATING TO EYES &
NOSE. ODOR IS PERCEPTIBLE FOR MOST PERSONS AT 0.22 PPM.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: IMMED FLUSH EYES W/WATER FOR 30 MIN WHILE HOLDING EYELIDS
OPEN. SEE MD AT ONCE. SKIN: IMMED WASH W/SOAP & WATER FOR 30 MIN. SEE MD
AT ONCE. DESTROY CONTAMD SHOES & CLTHG. INGEST: DO NOT INDUCE V OMIT.
DRINK LG QTYS OF MILK (PREFERRED)OR WATER & GIVE MILK OF MAGNESIA. TAKE
TO HOSPITAL AT ONCE. INHAL: REMOVE TO FRESH AIR. SEE MD AT ONCE. IF BRTHG HAS
STOPPED, BEGIN ARTF RESP. NOTES: (SUPDAT)
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Handling and Disposal
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Spill Release Procedures: CONTAIN W/DIKES. DILUTE WITH WATER. NEUTRALIZE WITH
SODA ASH OR LIME. PUT IN STEEL DRUM (PLASTIC DRUM IF ACIDIC). NOT
BIODEGRADABLE. TOXIC TO FISH. DO NOT ALLOW TO ENTER WATERWAY.
Neutralizing Agent: NEUTRALIZE WITH SODA ASH OR LIME.
Waste Disposal Methods: NEUTRALIZED MATERIAL IS GENERALLY ACCEPTABLE IN
SANITARY SEWERS; CHECK FEDERAL, STATE AND LOCAL REGULATIONS. CONSULT
MANUFACTURER FOR CONTAINER DISPOSAL. RCRA HAZARDOUS WASTE NUMBER: D001, D002.
Handling And Storage Precautions: AVOID CONTACT WITH CLOTHING, ORGANICS OR
OTHER COMBUSTIBLE MATERIALS. DO NOT STORE OR TRANSPORT WITH CORROSIVE
MATERIALS OR COMBUSTIBLE MATERIALS.
Other Precautions: OXIDIZER. PACKAGING REQUIREMENT: USE SPECIALLY CONSTRUCTED
CONTAINERS ONLY. THIS MATERIAL MUST BE HANDLED ONLY BY PERSONS WHO HAVE BEEN
SPECIALLY TRAINED IN ITS HAZARDS AND HANDLING PROCEDURES.
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Fire and Explosion Hazard Information
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Flash Point Text: >200F,>93C
Extinguishing Media: USE WATER PRIOR TO OTHER MEDIA.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
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Control Measures
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Respiratory Protection: USE NIOSH APPROVED SCBA OR EXTERNAL SUPPLIED AIR.
Ventilation: GENERAL AND LOCAL VENTILATION IS REQUIRED.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS (SUPDAT)
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). WEAR
SPECIAL RESISTANT FULL BODY COVERING SUIT W/HOOD, GLOVES, BOOTS.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: VP: 5 PSI @ 100F. MATL TO AVOID: REACTS W/BASES
& MANY METALS. FIRST AID PROC: EFTS OF BRTHG VAP MAY BE DELAYED FOR
HRS/DAYS. KEEP PATIENT AT REST & UNDER SURVEILLANCE A MINIMUM OF 72 HRS.
ADMIN OXYGE N IF BRTHG IS DFCLT. DO NOT USE CARBONATED ALKALIES AS ANTIDOTE
FOR SWALLOWING. EYE PROT: & FULL LENGTH FSHLD (FP N).
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Physical/Chemical Properties
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B.P. Text: 140F,60C
M.P/F.P Text: -61F,-52C
Vapor Pres: SUPDAT
Vapor Density: >1
Spec Gravity: 1.57
PH: <2
Solubility in Water: COMPLETE
Appearance and Odor: YELLOW LIQUID; PUNGENT ODOR.
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: TOXIC CORROSIVE FUMES OF NITROGEN DIOXIDE ARE
SLOWLY RELEASED AT ROOM TEMPERATURE.
Materials To Avoid: REACTS EXPLOSIVELY W/REDUCING AGENTS & MANY ORGANIC
CHEMICALS INCLUDING CYCLOHEXANE, FORMALDEHYDE & ALCOHOLS. (SUPDAT)
Hazardous Decomposition Products: TOXIC CORROSIVE FUMES OF NITROGEN OXIDES AND
HYDROGEN FLUORIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: INHIBITED RED FUMING NITRIC ACID L61
Assigned IND: Y
Company: DOWELL SCHLUMBERGER
PO Box: 21
City: TULSA OK
Zipcode: 74102
Health Emergency Phone: 918-582-0104
Label Required IND: Y
Date Of Label Review: 11/03/1996
Status Code: C
Label Date: 11/03/1996
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: CORROSIVE. ACUTE: EYES: CORROSIVE. RAPIDLY CAUSES PAIN,
BURNS, CORNEAL INJURY. MAY CAUSE PERMANENT DAMAGE AND BLINDNESS. SKIN: TOXIC.
CORROSIVE. CAN CAUSE ILLNESS OR DEATH. RAPIDLY CAUSES BURNS, TISSU E DAMAGE
AND PAIN. INGESTION: TOXIC. CORROSIVE. CAUSES PAIN AND SEVERE BURNS TO MOUTH,
THROAT AND STOMACH. CAN CAUSE ILLNESS OR DEATH. INHALATION: TOXIC. CORROSIVE.
VERY DANGEROUS. MAY CAUSE COUGHING, DIFFICULT BREATHING, PULMONARY EDEMA AND
DEATH. EFFECTS MAY BE DELAYED HOURS OR DAYS. CHRONIC: NONE LISTED BY
MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.