carbon monoxide; bp: -312.75f (-191.53c) mp: -337.02f, -205.01c methane; (ch*4) bp: -258.74f (-161.52c) mp: -296.45f, -187.47c oxygen; (o*2) bp: -297.35f (-182.97c) mp: -361.84f, -218.80c nitrogen; (n*2) bp: -320.44f (-195.80c) mp: -346.00f, -210.00c other prec: use check valve/trap in discharge line to pvnt haz back flow ing 5: device. close valve after each use & when empty. for addnl ing 6: de gaz/compressed gas association pamphlet p-1. protect cyls from ing 7: ventd area away from heavily trafficked areas & emer exits. do ing 8: exceed 125f (52c). cyls should be stored upright & firmly ing 9: full & empty cyls should be segregated. use a ing 10: stored for excess periods of time. these mixtures are noncorr ing 11: moisture causes metal oxides which are formed w/air to be ing 12: prot role (rust form). concs of so*2, cl*2, salt, etc in moisture ing 13: compressed gas cyls should not be refilled except by qualified ing 14: of a compressed gas cyl which has not been filled by owner/with ing 15: fed law (49 cfr). always secure cyls in an upright position ing 16: cyls in trunks of vehicles, enclsd vans, truck cabs/in passenger ing 17: in open flatbed or in open pick-up type vehicles. efts of overexp: professionals concerning latest hazard list information
LIQUID AIR CORP -- 10-100 PPM CARBON MONOXIDE, 10 PPM-2.5% (SUP
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CCSQT
MSDS NAME: 10-100 PPM CARBON MONOXIDE, 10 PPM-2.5% (SUP DAT)
Responsible Party
Name: LIQUID AIR CORP
Address: 2121 NORTH CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Info Phone: 415-977-6500
Emergency Phone Number: 800-231-1366;800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Address: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Phone: 415-977-6500
=======================================================
Ingredients
=======================================================
Cas: 630-08-0
RTECS #: FG3500000
Name: CARBON MONOXIDE; BP: -312.75F (-191.53C) MP: -337.02F, -205.01C
OSHA PEL: 50 PPM
ACGIH TLV: 25 PPM
------------------------------
Cas: 74-82-8
RTECS #: PA1490000
Name: METHANE; (CH*4) BP: -258.74F (-161.52C) MP: -296.45F, -187.47C
OSHA PEL: N/K (FP N)
ACGIH TLV: ASPHYXIANT
------------------------------
Cas: 7782-44-7
RTECS #: RS2060000
Name: OXYGEN; (O*2) BP: -297.35F (-182.97C) MP: -361.84F, -218.80C
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 7727-37-9
RTECS #: QW9700000
Name: NITROGEN; (N*2) BP: -320.44F (-195.80C) MP: -346.00F, -210.00C
OSHA PEL: N/K (FP N)
ACGIH TLV: ASPHYXIANT
------------------------------
Name: OTHER PREC: USE CHECK VALVE/TRAP IN DISCHARGE LINE TO PVNT HAZ BACK FLOW
INTO CYL. DO NOT TAMPER W/(VALVE) SFTY
-----------------------------
Name: ING 5: DEVICE. CLOSE VALVE AFTER EACH USE & WHEN EMPTY. FOR ADDNL
HNDLG REC CONSULT L'AIR LIQUIDE'S ENCYCLOPEDIA
-----------------------------
Name: ING 6: DE GAZ/COMPRESSED GAS ASSOCIATION PAMPHLET P-1. PROTECT CYLS FROM
PHYSICAL DMG. STORE IN COOL, DRY, WELL-
-----------------------------
Name: ING 7: VENTD AREA AWAY FROM HEAVILY TRAFFICKED AREAS & EMER EXITS. DO
NOT ALLOW TEMP WHERE CYLS ARE STORED TO
-----------------------------
Name: ING 8: EXCEED 125F (52C). CYLS SHOULD BE STORED UPRIGHT & FIRMLY
SECURED TO PVNT FALLING/BEING KNOCKED OVER.
-----------------------------
Name: ING 9: FULL & EMPTY CYLS SHOULD BE SEGREGATED. USE A
"FIRST-IN-FIRST-OUT" INVENTORY SYS TO PVNT FULL CYLS BEING
-----------------------------
Name: ING 10: STORED FOR EXCESS PERIODS OF TIME. THESE MIXTURES ARE NONCORR
& MAY BE USED W/ALL MATLS OF CONSTRUCTION.
-----------------------------
Name: ING 11: MOISTURE CAUSES METAL OXIDES WHICH ARE FORMED W/AIR TO BE
HYDRATED SO THAT THEY INCR IN VOL & LOSE THEIR
-----------------------------
Name: ING 12: PROT ROLE (RUST FORM). CONCS OF SO*2, CL*2, SALT, ETC IN MOISTURE
ENHANCES RUSTING OF METALS IN AIR.
-----------------------------
Name: ING 13: COMPRESSED GAS CYLS SHOULD NOT BE REFILLED EXCEPT BY QUALIFIED
PRODUCERS OF COMPRESSED GASES. SHIPMENT
-----------------------------
Name: ING 14: OF A COMPRESSED GAS CYL WHICH HAS NOT BEEN FILLED BY OWNER/WITH
HIS (WRITTEN) CONSENT IS A VIOLATION OF
-----------------------------
Name: ING 15: FED LAW (49 CFR). ALWAYS SECURE CYLS IN AN UPRIGHT POSITION
BEFORE TRANSPORTING THEM. NEVER TRANSPORT
-----------------------------
Name: ING 16: CYLS IN TRUNKS OF VEHICLES, ENCLSD VANS, TRUCK CABS/IN PASSENGER
COMPARTMENTS. TRANSPORT CYLS SECURED
-----------------------------
Name: ING 17: IN OPEN FLATBED OR IN OPEN PICK-UP TYPE VEHICLES.
-----------------------------
Name: EFTS OF OVEREXP: PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION
& SAFE HANDLING & EXPOSURE INFORMATION (FP N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE/CHRONIC: BRTHG THESE GAS MIXS FOR SEVERAL HRS COULD
CAUSE SLIGHT HDCH & POSS SLIGHT DIZZ & DISCOMFORT. CARBON MONOXIDE IS
COLORLESS & ODORLESS SO THAT THERE IS NO WARNING OF ITS PRESENCE. CARBON
MONOXIDE ACTS AS A CHEM ASPHY BY REDUCING OXYGEN TRANSPORT PROPERTIES OF
BLOOD. IT REACTS W/THE (EFTS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: HEMOGLOBIN FORMING
CARBOXYHEMOGLOBIN THUS PREVENTING HEMOGLOBIN FROM TRANSPORTING OXYGEN. THE
STATE OF CALIFORNIA HAS LISTED CARBON MONOXIDE AS A CMPD WHICH IS KNOWN TO
CAUSE DEVELOPMENTAL R EPRO TOX. CARBON MONOXIDE APPEARS ON THE NAVY OCCUP
CHEM REPRO HAZ LIST. SEEK CONSULT FROM APPROP HLTH
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOSURE TO THESE MIXTURES SHOULD NOT BE ALLOWED TO
WORK OR HANDLE THESE PRODUCTS.
First Aid: PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP TO THESE
MIXTURES. INHAL: CONSCIOUS PERS SHOULD BE ASSISTED TO UNCONTAM AREA & BE
TREATED W/SUPPLEMENTAL OXYGEN. QUICK REMOVAL FROM CONTAM AREA IS MOST
IMPORTANT. THE ADMINISTERING OF OXYGEN AT ELEVATED PRESS (UP TO 2-2.5 ATM)
HAS SHOWN TO BE BENEFICIAL AS HAS TREATMENT IN HYPERBARIC CHAMBER. MD SHOULD
BE INFORMED THAT PATIENT HAS (SUP DAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE
APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN CONTAINER OR CONTAINER VALVE,
CONTACT THE CLOSEST LIQUID AIR CORPORATION LOCATION.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DO NOT ATTEMPT TO DISP OF WASTE/UNUSED QTYS. RETURN IN
SHIPPING CONTR PROPERLY LABELED, W/ANY VALVE OUTLET PLUGS/CAPS SECURED &
VALVE PROT CAP IN PLACE TO MFR FOR PROPER DISP. FOR EMER DISP, CONT CLOS EST
MFR LOCATION. DISP OF I/A/W LOC, (SUP DAT)
Handling And Storage Precautions: USE ONLY IN WELL-VENTD AREAS. VALVE PROT CAPS
MUST REMAIN IN PLACE UNLESS CONTR IS SECURED W/VALVE OUTLET PIPED TO USE
POINT.
Other Precautions: DO NOT DRAG, SLIDE/ROLL CYLS. USE SUITABLE HAND TRUCK FOR
CYL MOVEMENT. USE PRESS REDUCING REGULATOR WHEN CONNECTING CYL TO LOWER PRESS
(<3,000 PSIG) PIPING/SYS. DO NOT HEAT CYL BY ANY MEANS TO INCR D ISCHARGE
RATE OF PROD FROM CYL.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: NON-FLAMMABLE GAS MIXTURE. USE MEDIA SUITABLE FOR
SURROUNDING FIRE (FP N).
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). IF CYLINDERS ARE INVOLVED IN A FIRE, SAFELY RELOCATE OR
KEEP COOL WITH WATER SPRAY.
Unusual Fire/Explosion Hazard: THESE MIXTURES AT HIGH PRESSURE WILL ACCELERATE
THE BURNING OF MATERIALS TO A GREATER RATE THAN THEY BURN AT ATMOSPHERIC
PRESSURE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED POSITIVE PRESSURE AIR LINE MASK OR SCBA
SHOULD BE AVAILABLE FOR EMERGENCY USE.
Ventilation: HOOD WITH FORCED VENTILATION. LOCAL EXHAUST TO PREVENT
ACCUMULATION ABOVE THE TWA FOR CARBON MONOXIDE.
Protective Gloves: PLASTIC OR RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). SAFETY SHOES.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: TRADE NAME/PART #: METHANE & 19% OXYGEN IN
NITROGEN. VP: @ 70F (21.1C) ABOVE CRITICAL TEMP. FIRST AID PROC: INHALED
CARBON MONOXIDE. EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15 MIN. SEE MD (FP
N). SKI N: FLUSH W/COPIOUS AMTS OF WATER. SEE MD (FP N). INGEST: CALL MD
IMMED (FP N). WASTE DISP METH: STATE & FED REGS (FP N).
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SEE INGS
M.P/F.P Text: SEE INGS
Vapor Pres: SUP DAT
Spec Gravity: 0.99-1.00
Solubility in Water: VERY SLIGHTLY
Appearance and Odor: COLORLESS, ODORLESS GAS
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: 10-100 PPM CARBON MONOXIDE, 10 PPM-2.5% (SUP DAT)
Company: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Street: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA
Zipcode: 94596
Health Emergency Phone: 800-231-1366;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 11/26/1996
Status Code: C
Label Date: 11/26/1996
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: BREATHING THESE GAS MIXTURES FOR SEVERAL HOURS
COULD CAUSE SLIGHT HEADACHES AND POSSIBLE SLIGHT DIZZINESS AND DISCOMFORT.
CARBON MONOXIDE IS COLORLESS AND ODORLESS SO THAT THERE IS NO WARNING O F ITS
PRESENCE. CARBON MONOXIDE ACTS ASA CHEMICAL ASPHYXIANT BY REDUCING OXYGEN
TRANSPORT PROPERTIES OF BLOOD. IT REACTS WITH THE HEMOGLOBIN CAUSING LOSS OF
OXYGEN TRANSPORT. CHRONIC: CARBON MONOXIDE APPEARS ON THE NAVY OCCUPATIONAL
CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.