| MSDS | : | TOLUOL 55GAL, 26-10036-09 | | CAS | : | 108-88-3 | | NAME | : | toluene (sara 313) (cercla)
efts of overexp: continuing expos, so unsatisfactory as a means of
ing 2: chronic, adverse systemic efts. ingest: mod tox. causes burning
ing 3: prdce symps similar to those described for inhal. more serious haz
ing 4: in aspir (brthg) of vomitus into lungs-which may rslt in chem
ing 5: coughing, labored brthg & cyanosis (bluish skin) & which
ing 6: indus acceptable levels of toluol have prdced card efts in humans,
ing 7: of high levels of toluol prdced card sensit. such sensit may cause
ing 8: latter eft was shown to be enhanced by hypoxia/injection of
ing 9: ppm/1200 ppm of toluol for 14hr/day for 4-5 wks (respectively)
ing 10: significance of this info to man is unknown. chronic: sev bone
ing 11: been reported although it was usually not clear whether toluol
ing 12: of heart, liver & adrenal glands from chronic overexp has
ing 13: for many yrs to toluene vaps do not show any carcin efts. prlng
ing 14: appetite, nose bleeds, & liver, kidney & neural disfunc.
ing 15: toluene appears on the navy occup chem repro haz list. seek
ing 16: concerning latest hazard list information & safe handling
first aid proc: give artf resp if not brthg. get med attn. ingest: do not
ing 18: keep head below hips to pvnt aspir of liq into lungs. get med
ing 19: ingested, & vomit has not occurred, emesis should be induced
ing 20: pvnt aspir. if symps such as loss of gag reflex, convls/uncon
ing 21: cuffed endotracheal tube should be considered.
spill proc: leak. dike & contain. soak up. flush area. for more
other prec: inspect all elec & mech equip used w/or near toluol. for
eye prot: and full length faceshield (fp n).
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HARCROS CHEMICALS INC -- TOLUOL 55GAL, 26-10036-09
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CDTMG
MSDS NAME: TOLUOL 55GAL, 26-10036-09
Responsible Party
Name: HARCROS CHEMICALS INC
Address: 5200 SPEAKER RD
City: KANSAS CITY KS 66106
Info Phone: 913-321-3131
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Preparer's Name: GENE TURNER
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: HARCROS CHEMICALS INC.
Address: 5200-SPEAKER ROAD
Box: 2383
City: KANSAS CITY KS 66106-1095
Phone: 913-321-3131
=======================================================
Ingredients
=======================================================
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA)
% Wt: 100
OSHA PEL: 200 PPM
ACGIH TLV: 50 PPM, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Name: EFTS OF OVEREXP: CONTINUING EXPOS, SO UNSATISFACTORY AS A MEANS OF
DETECTION. RPTD EXCESS EXPOS MAY CAUSE
-----------------------------
Name: ING 2: CHRONIC, ADVERSE SYSTEMIC EFTS. INGEST: MOD TOX. CAUSES BURNING
SENSATION IN MOUTH & STOM & IS LIKELY TO
-----------------------------
Name: ING 3: PRDCE SYMPS SIMILAR TO THOSE DESCRIBED FOR INHAL. MORE SERIOUS HAZ
POSED BY VOMIT AFTER SWALLOWING RSLTG
-----------------------------
Name: ING 4: IN ASPIR (BRTHG) OF VOMITUS INTO LUNGS-WHICH MAY RSLT IN CHEM
PNEUMIT & PULM EDEMA/HEMORR (EVIDENCED BY
-----------------------------
Name: ING 5: COUGHING, LABORED BRTHG & CYANOSIS (BLUISH SKIN) & WHICH
MAY BE FATAL. WHILE THERE IS NOT EVIDENCE THAT
-----------------------------
Name: ING 6: INDUS ACCEPTABLE LEVELS OF TOLUOL HAVE PRDCED CARD EFTS IN HUMANS,
ANIMAL STUDIES HAVE SHOWN THAT INHAL
-----------------------------
Name: ING 7: OF HIGH LEVELS OF TOLUOL PRDCED CARD SENSIT. SUCH SENSIT MAY CAUSE
FATAL CHANGES IN HEART RHYTHMS. THIS
-----------------------------
Name: ING 8: LATTER EFT WAS SHOWN TO BE ENHANCED BY HYPOXIA/INJECTION OF
ADRENALIN-LIKE AGENTS. RATS EXPOSED TO 1400
-----------------------------
Name: ING 9: PPM/1200 PPM OF TOLUOL FOR 14HR/DAY FOR 4-5 WKS (RESPECTIVELY)
EXHIBITED HIGH FREQUENCY HEARING DEFICITS.
-----------------------------
Name: ING 10: SIGNIFICANCE OF THIS INFO TO MAN IS UNKNOWN. CHRONIC: SEV BONE
MARROW DEPRESS & APLASTIC ANEMIA HAVE
-----------------------------
Name: ING 11: BEEN REPORTED ALTHOUGH IT WAS USUALLY NOT CLEAR WHETHER TOLUOL
WAS CONTAM W/BENZENE. FATTY DEGENERATION
-----------------------------
Name: ING 12: OF HEART, LIVER & ADRENAL GLANDS FROM CHRONIC OVEREXP HAS
ALSO BEEN REPORTED. STUDIES OF WORKERS EXPOSED
-----------------------------
Name: ING 13: FOR MANY YRS TO TOLUENE VAPS DO NOT SHOW ANY CARCIN EFTS. PRLNG
EXPOS TO HIGH CONCS MAY PRDCE LOSS OF
-----------------------------
Name: ING 14: APPETITE, NOSE BLEEDS, & LIVER, KIDNEY & NEURAL DISFUNC.
TARGET ORGANS: CNS, LUNGS, LIVER, & KIDNEYS.
-----------------------------
Name: ING 15: TOLUENE APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ LIST. SEEK
CONSULT FROM APPROP HLTH PROFESSIONALS
-----------------------------
Name: ING 16: CONCERNING LATEST HAZARD LIST INFORMATION & SAFE HANDLING
& EXPOSURE INFORMATION (FP N).
-----------------------------
Name: FIRST AID PROC: GIVE ARTF RESP IF NOT BRTHG. GET MED ATTN. INGEST: DO NOT
INDUCE VOMIT. IF VOMIT OCCURS SPONT,
-----------------------------
Name: ING 18: KEEP HEAD BELOW HIPS TO PVNT ASPIR OF LIQ INTO LUNGS. GET MED
ATTN PROMPTLY. NOTE TO MD: IF >2.0 ML/KG
-----------------------------
Name: ING 19: INGESTED, & VOMIT HAS NOT OCCURRED, EMESIS SHOULD BE INDUCED
W/SUPERVISION. KEEP HEAD BELOW HIPS TO
-----------------------------
Name: ING 20: PVNT ASPIR. IF SYMPS SUCH AS LOSS OF GAG REFLEX, CONVLS/UNCON
OCCUR BEFORE EMESIS, GASTRIC LAVAGE USING
-----------------------------
Name: ING 21: CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED.
-----------------------------
Name: SPILL PROC: LEAK. DIKE & CONTAIN. SOAK UP. FLUSH AREA. FOR MORE
SPECIFIC INFORMATION CONTACT NEHC (FP N).
-----------------------------
Name: OTHER PREC: INSPECT ALL ELEC & MECH EQUIP USED W/OR NEAR TOLUOL. FOR
MORE SPECIFIC INFORMATION CONTACT NEHC (FP N).
-----------------------------
Name: EYE PROT: AND FULL LENGTH FACESHIELD (FP N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50 (ORAL RAT): 5 G/KG.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYES: SHORT TERM CONT MAY RSLT IN SEV IRRIT &
CONJ. PRLNG CONT W/LIQ CAN RSLT IN CORNEAL BURNS. HIGH VAP CONCS >APPROX
1000 PPM ARE IRRIT. SKIN: PRLNG & RPTD LIQ CONT CAN CAUSE DEFAT &
DRYING O F SKIN, WHICH MAY RSLT IN IRRIT & DERM.PRACTICALLY NON-TOX IF
ABSORBED. SKIN ABSORPTION MAY ADD (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: SIGNIFICANTLY TO EXPOS. INHAL:
CNS DEPRESS. MILD EXPOS CAN CAUSE DIZZ, WEAK, HDCH, NAUS, ETC. MORE SEV
EXPOS, >APPROX 1000 PPM, MAY CAUSE RESP DEPRESS, CONVLS & DEATH. CARD
ARRHYS, INCL FATA L VENTRICULAR FIBRILLATION, MAY OCCUR. OLFACTORY DETECTION
LEVEL IS 50 PPM. HOWEVER, SENSE OF SMELL IS DULLED BY
Medical Cond Aggravated By Exposure: PREEXISTING EYE, SKIN, AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
First Aid: EYES: FLUSH W/WATER FOR AT LEAST 15 MIN WHILE HOLDING EYELIDS OPEN.
GET MED ATTN. SKIN: FLUSH W/WATER WHILE REMOVING CONTAM CLTHG & SHOES.
FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE CLTHG/SHOES UN TIL
CLEANED. PROPERLY DISP OF CONTAM LEATHER ARTICLES, INCL SHOES THAT CANNOT BE
DECONTAM. IF IRRIT PERSISTS, GET MED ATTN. INHAL: REMOVE TO FRESH AIR &
PROVIDE OXYGEN IF BRTHG IS DFCLT.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLAMMABLE! ELIMINATE ALL IGNITION SOURCES. GROUND.
MONITOR W/FIRE HOSE TEAM. LARGE SPILLS: EVACUATE HAZARD AREA OF UNPROTECTED
PERSONNEL. WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR & PROTECTIVE CLOTHI
NG. SHUT OFF SOURCE OF
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS (FP N). FOR MORE SPECIFIC INFORMATION CONTACT NEHC (FP N).
Handling And Storage Precautions: KEEP AWAY FROM HEAT, SPKS & OPEN FLAMES.
KEEP CONTRS TIGHTLY CLSD. STORE AWAY FROM STRONG OXIDIZING AGENTS IN COOL,
DRY PLACE W/ADEQ EXPLO-PROOF VENT.
Other Precautions: GROUND EQUIP TO PVNT ACCUM OF STATIC CHARGE. IF
POURING/TRANSFERRING MATLS, CONTRS MUST BE BONDED & GROUNDED. EXTING
PILOT LIGHTS, CIGARETTES, & TURN OFF OTHER SOURCES OF IGNIT PRIOR TO USE
& UNTIL AL L VAPS ARE GONE. REGULARLY
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 45.0F,7.2C
Lower Limits: 1.2%
Upper Limits: 7.1%
Extinguishing Media: WATER FOG, FOAM, DRY CHEM/CARBON DIOXIDE. DO NOT USE
DIRECT WATER STREAM (PROD WILL FLOAT, MAY REIGNITE & SPREAD FIRE).
Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
W/LGE FIRES USE WATER TO COOL SURROUNDING EQUIP & STRUCTURES, AS WELL AS
FIRE-EXPOSED CONTRS. EVACUATE(SUP DAT)
Unusual Fire/Explosion Hazard: AVOID CONT OF TOLUOL W/NITRIC ACID &
SULFURIC ACID, NITROGEN TETROXIDE, & SILVER PERCHLORATE. VAPS WILL TRAVEL
CONSIDERABLE DIST TO SOURCE OF IGNIT & (SUP DAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: FOR EXPOSURES ABOVE THE LIMITATIONS AND UP TO 1000 PPM
USE A NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE. FOR MORE SPECIFIC INFORMATION CONTACT NEHC (FP N).
Ventilation: MECHANICAL (GENERAL) WITH STRONG POSITIVE VENTILATION PREFERRED.
FOR MORE SPECIFIC INFORMATION CONTACT NEHC (FP N).
Protective Gloves: NEOPRENE OR BUNA-N RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGG
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
PLASTIC APRON. STATIC-FREE CLTHG. IMPERVIOUS APRON & FOOTWEAR.
Work Hygienic Practices: WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMKNG/USING TOILET FACILITIES. NO SMKNG WHERE MATL IS USED/STORED.
Supplemental Safety and Health: FIRE FIGHT PROC: UNPROT PERS FROM HAZ AREA.
EXPLO HAZ: FLASH BACK. EXPLO MAY RSLT IF VAPS ARE IGNITED IN CONFINED AREA.
SURFS THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN LIQ PROD IN ABSENCE OF
SPKS/FLAM E. MATLS TO AVOID: COMBINATION W/SULFURIC ACID, WILL FORM
NITROCRESOLS THAT CAN DECOMPOSE VIOLENTLY W/FURTHER NITRATION.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 231F,111C
Vapor Pres: 22 @ 68F
Vapor Density: 3.2
Spec Gravity: 0.87 (H*2O=1)
PH: NEUT
Evaporation Rate & Reference: 2.0 (N-BUTYL ACETATE=1)
Solubility in Water: NEGLIGIBLE (
Appearance and Odor: COLORLESS MOBILE LIQUID, MILD AROMATIC ODOR
Percent Volatiles by Volume: 100
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID HEAT, SPARKS, OR OPEN FLAMES. TOLUENE IS A
FLAMMABLE LIQUID.
Materials To Avoid: STRONG OXIDIZING AGENTS (CONC OXYGEN, SODIUM/CALCIUM
HYPOCHLORITES & INCL HALOGENS). NITRIC ACID, ESP IN (SUP DAT)
Hazardous Decomposition Products: FUMES, SMOKE, CARBON MONOXIDE AND
UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: TOLUOL 55GAL, 26-10036-09
Company: HARCROS CHEMICALS INC.
Street: 5200-SPEAKER ROAD
PO Box: 2383
City: KANSAS CITY KS
Zipcode: 66106-1095
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 04/24/1997
Status Code: C
Label Date: 04/24/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: EYES: SEVERE IRRIT &
CONJUNCTIVITIS. CORNEAL BURNS. SKIN: DEFATTING & DRYING, IRRIT &
DERMATITIS. INHAL: CNS DEPRESSION; DIZZINESS, WEAKNESS, HEADACHE, NAUSEA,
RESP DEPRESSION, CONVU LSIONS, DEATH, CARDIAC ARRHYTHMIAS, VENTRICULAR
FIBRILLATION-FATAL. DULLED SENSE OF SMELL. INGESTION: BURNING MOUTH, STOMACH.
SYMPTOMS SIMILAR TO INHALATION. VOMITING-ASPIRATION HAZARD-PNEUMONITIS; PU
LMONARY EDEMA/HEMORRAGE; COUGHING, CYANOSIS, DIFFICULTY BREATHING. CARDIAC
SENSITIZATION. CHRONIC: TOLUENE APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL
REPRODUCTIVE HAZARDS LIST (FP N). BONE MARROW DEPRE SSION, ANEMIA. LIVER,
KIDNEY & NEURAL DISFUNCTION.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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