| MSDS | : | 76 DIESEL 2 LS, 01614 | | CAS | : | 91-20-3
8002-05-9
68476-34-6 | | NAME | : | naphthalene (sara 313) (cercla)
petroleum distillate
petroleum mid-distillate; (diesel fuel no 2)
supdat: areas. if container is not properly cooled, it may explode in the
efts of overexp: lab animals. it has been identified as carcin by iarc.
ing 5: & liver dmg in lab animals. relevance of these findings to
ing 6: naphthalene as having "some evidence of carcinogenic activity" in
first aid: if skin surf is not dmgd cleanse affected area(s) thoroughly
ing 8:waterless skin cleanser. if irrit/redness develops, seek immed med
ing 9:fresh air. if symps persist, seek med attn. if not brthg immed
ing 10:oxygen should be admin by qualified pers. seek immed med attn.
ing 11:anything by mouth; matl can enter lungs & cause sev lung dmg.
ing 12:down. if poss do not leave unattended. seek med attn. note:if
spill proc:spilled matl from entering sewers/storm drains/other unauth
ing 14: dike far ahead of spill for later recovery/disp. absorb spilled
ing 15:auths & approp fed, state & loc agencies. immed cleanup
ing 16: waters, contiguous zone or adjoining shorelines, notify nrc at
other precs: codes). do not enter confined spaces such as tanks/pits
ing 18: astm d-4276. outdoor/detached stor pref. indoor stor should meet
ing 19:niosh apprvd resp prot advised when concs exceed any established
ing 20:(liq &/or vap) & can be dangerous. do not
ing 21: flame, spks or other ignit sources; may explode & cause
ing 22:promptly ship to supplier/drum reconditioner empty drums. disp of
ing 23: i/a/w govt regs. refer to osha regs, ansi z49.1 & other govt
vent: exhst systems may be reqd. where explo mixtures may be present,
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UNION OIL COMPANY OF CALIFORNI -- 76 DIESEL 2 LS, 01614
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CDTSC
MSDS NAME: 76 DIESEL 2 LS, 01614
Responsible Party
Name: UNION OIL COMPANY OF CALIFORNIA
Address: 1201 W 5TH ST
City: LOS ANGELES CA 90017
Info Phone: 213-977-7589
Emergency Phone Number: 800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: UNION OIL CO OF CA UNION 76 DIV- WESTERN RGION
Address: 1201 W 5TH ST
Box: 7600
City: LOS ANGELES CA 90017-1443
Phone: UNKNOWN
Name: UNION OIL COMPANY OF CALIFORNIA
Address: 1345 NORTH MEACHAM ROAD
City: SCHAUMBURG IL 60196
Phone: 800-438-2968
=======================================================
Ingredients
=======================================================
Cas: 91-20-3
RTECS #: QJ0525000
Name: NAPHTHALENE (SARA 313) (CERCLA)
% Wt: <0.5
OSHA PEL: 10 PPM
ACGIH TLV: 10 PPM; 15 STEL
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 8002-05-9
RTECS #: SE7449000
Name: PETROLEUM DISTILLATE
Other REC Limits: 400 PPM (MFR)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 68476-34-6
Name: PETROLEUM MID-DISTILLATE; (DIESEL FUEL NO 2)
% Wt: >99.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: SUPDAT: AREAS. IF CONTAINER IS NOT PROPERLY COOLED, IT MAY EXPLODE IN THE
HEAT OF A FIRE.
-----------------------------
Name: EFTS OF OVEREXP: LAB ANIMALS. IT HAS BEEN IDENTIFIED AS CARCIN BY IARC.
DIESEL #2 PRDCED LIMITED EVID OF KIDNEY
-----------------------------
Name: ING 5: & LIVER DMG IN LAB ANIMALS. RELEVANCE OF THESE FINDINGS TO
HUMANS IS UNCERTAIN. NTP HAS IDENTIFIED
-----------------------------
Name: ING 6: NAPHTHALENE AS HAVING "SOME EVIDENCE OF CARCINOGENIC ACTIVITY" IN
LAB ANIMALS.
-----------------------------
Name: FIRST AID: IF SKIN SURF IS NOT DMGD CLEANSE AFFECTED AREA(S) THOROUGHLY
BY WASHING W/MILD SOAP & WATER & IF NEC,
-----------------------------
Name: ING 8:WATERLESS SKIN CLEANSER. IF IRRIT/REDNESS DEVELOPS, SEEK IMMED MED
ATTN. INHAL:MOVE AWAY FROM EXPOS & INTO
-----------------------------
Name: ING 9:FRESH AIR. IF SYMPS PERSIST, SEEK MED ATTN. IF NOT BRTHG IMMED
BEGIN ARTF RESP. IF BRTHG DFCLTY DEVELOPS,
-----------------------------
Name: ING 10:OXYGEN SHOULD BE ADMIN BY QUALIFIED PERS. SEEK IMMED MED ATTN.
INGEST:ASPIR HAZ:DO NOT INDUCE VOMIT/GIVE
-----------------------------
Name: ING 11:ANYTHING BY MOUTH; MATL CAN ENTER LUNGS & CAUSE SEV LUNG DMG.
IF DROWSY/UNCON, PLACE ON LEFT SIDE W/HEAD
-----------------------------
Name: ING 12:DOWN. IF POSS DO NOT LEAVE UNATTENDED. SEEK MED ATTN. NOTE:IF
ALLERGIC RXN TO MATL DEVELOPS, AVOID FURTHER CNTCT.
-----------------------------
Name: SPILL PROC:SPILLED MATL FROM ENTERING SEWERS/STORM DRAINS/OTHER UNAUTH
TREATMENT DRAINAGE SYS & NATRL WATERWAYS.
-----------------------------
Name: ING 14: DIKE FAR AHEAD OF SPILL FOR LATER RECOVERY/DISP. ABSORB SPILLED
MATL W/APPROP ABSORB MATL. NOTIFY FIRE
-----------------------------
Name: ING 15:AUTHS & APPROP FED, STATE & LOC AGENCIES. IMMED CLEANUP
RECD. IF ANY AMT OF SPILL MADE INTO US NAVIGABLE
-----------------------------
Name: ING 16: WATERS, CONTIGUOUS ZONE OR ADJOINING SHORELINES, NOTIFY NRC AT
800-424-8802.
-----------------------------
Name: OTHER PRECS: CODES). DO NOT ENTER CONFINED SPACES SUCH AS TANKS/PITS
W/OUT FOLLOWING PROPER ENTRY PROCS SUCH AS
-----------------------------
Name: ING 18: ASTM D-4276. OUTDOOR/DETACHED STOR PREF. INDOOR STOR SHOULD MEET
OSHA STDS & APPROP FIRE CODES. USE OF
-----------------------------
Name: ING 19:NIOSH APPRVD RESP PROT ADVISED WHEN CONCS EXCEED ANY ESTABLISHED
EXPOS LIMS. EMPTY CNTNRS RETAIN RESIDUE
-----------------------------
Name: ING 20:(LIQ &/OR VAP) & CAN BE DANGEROUS. DO NOT
PRESSURIZE/CUT/WELD/BRAZE/SOLDER/DRILL/GRIND/EXPOSE TO HEAT,
-----------------------------
Name: ING 21: FLAME, SPKS OR OTHER IGNIT SOURCES; MAY EXPLODE & CAUSE
INJURY/DEATH. COMPLETELY DRAIN, PROPERLY BUNG &
-----------------------------
Name: ING 22:PROMPTLY SHIP TO SUPPLIER/DRUM RECONDITIONER EMPTY DRUMS. DISP OF
OTHER CNTNRS IN ENVIRONMENTALLY SAFE
-----------------------------
Name: ING 23: I/A/W GOVT REGS. REFER TO OSHA REGS, ANSI Z49.1 & OTHER GOVT
& INDUS REFERENCES BEFORE WORKING ON/IN TANKS.
-----------------------------
Name: VENT: EXHST SYSTEMS MAY BE REQD. WHERE EXPLO MIXTURES MAY BE PRESENT,
ELEC SYSTEMS SAFE FOR SUCH LOCATIONS MUST BE USED.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES:MAY CAUSE MILD IRRIT. DIRECT CNTCT W/LIQ OR EXPOS TO
VAPS/MISTS MAY CAUSE STINGING, TEARING & REDNESS. SKIN CNTCT:SEV SKIN
IRRITANT. DIRECT CNTCT/EXPOS TO VAPS/MISTS MAY CAUSE REDNESS, BURNING, D
RYING & CRACKING & SEV SKIN DMG. RPTD CNTCT MAY CAUSE ALLERGIC SKIN
RXN. NO HARMFUL EFTS SHOWN IN SKIN (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:ABSORPTION STUDIES. INHAL:BRTHG
HIGH CONCS OF VAPS/MISTS MAY CAUSE NOSE & THROAT IRRIT. INGEST:MATL HAS
LOW DEGREE OF TOX BUT INGEST OF EXCESS QTYS MAY CAUSE ASPIR HAZ-MATL CAN
ENTER LUNGS DU RING SWALLOW/VOMIT & CAUSE LUNG INFLAM & DMG.
COMMENTS: DIESEL EXHST IS PROBABLE CANCER HAZ BASED ON TESTS IN
Medical Cond Aggravated By Exposure: PERSONS WITH PRE-EXISTING SKIN DISORDERS
MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS MATERIAL.
First Aid: HAVE MD CALL LOS ANGELES POIS CTL CTR 800-356-3129. EYES:IF
IRRIT/REDNESS DEVELOPS, MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH EYES
W/CLEAN WATER FOR AT LST 15 MIN. IF SYMPS PERSIST, SEEK MED ATTN. SKIN:IMMED
WIPE MATL FROM SKIN. REMOVE CONTAMD SHOES, CLTHG & CONSTRICTIVE JEWELRY
& FLUSH AFFECTED AREA(S) W/LG AMTS OF WATER. IF SKIN SURF DMGD, APPLY
CLEAN DRESSING & SEEK IMMED MED ATTN.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: COMBUST. KEEP ALL IGNIT SOURCES AWAY FROM SPILL/RELS.
STAY UPWIND & AWAY FROM SPILL/RELS. ISOLATE HAZ AREA & LIM ENTRY TO
AUTH PERS. STOP SPILL/RELS IF W/OUT RISK. WEAR APPROP PROT EQUIP INCL NIOSH
AP PRVD RESP PROT AS CNDTNS WARRANT. PVNT
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL, COUNTY,
STATE AND FEDERAL REGULATIONS.
Handling And Storage Precautions: KEEP CNTNR(S) TIGHTLY CLSD. USE & STORE
MATL IN COOL, DRY, WELL VENTD AREAS AWAY FROM HEAT & ALL SOURCES OF
IGNIT. POST AREA "NO SMKNG OR OPEN FLAME."
Other Precautions: BOND & GROUND ALL EQUIP WHEN TRANSFERRING FROM ONE
VESSEL TO ANOTHER. STORE ONLY IN APPRVD CNTNRS. KEEP AWAY FROM INCOMPAT
MATLS. PROTECT CNTNR(S) AGAINST PHYSICAL DMG. USE OF EXPLO-PROOF EQUIP IS REC
D & MAY BE REQD (SEE APPROP FIRE
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point Text: 125F,52C
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, HALON, FOAM OR WATER SPRAY
IS RECOMMENDED.
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). STOP
SPILL/RELS IF W/OUT RISK. MOVE UNDMGD CNTNRS FROM FIRE AREA IF W/OUT RISK.
WATER SPRAY MAY BE USEFUL IN(SUPDAT)
Unusual Fire/Explosion Hazard: MATL IS COMBUST & MAY BE IGNITED BY HEAT,
SPKS, FLAME/OTHER IGNIT SOURCES (EG STATIC ELEC, PILOT LIGHTS, MECH/ELEC
EQUIP). VAPS MAY TRAVEL CONSIDERABLE(SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: THE USE OF RESPIRATORY PROTECTION IS ADVISED WHEN CONCS
EXCEED THE ESTABLISHED EXPOSURE LIMITS. DEPENDING ON THE AIRBORNE CONC USE A
NIOSH APPROVED RESPIRATOR OR GAS MASK W/APPROPRIATE CARTRIDGES & CA
NNISTERS OR SUPPLIED AIR EQUIPMENT.
Ventilation: IF CURRENT VENT PRACTICES ARE NOT ADEQ TO MAINTAIN AIRBORNE CONCS
BELOW ESTABLISHED EXPOS LIMS, ADDNL VENT OR
Protective Gloves: IMPERMEABLE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER(FPN).
THOROUGHLY CLEAN SHOES & WASH CONTAMD CLTHG BEFORE REUSE. IMPERVIOUS APRON.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. DO NOT WEAR
CONTAMINATED CLOTHING OR SHOES. USE GOOD PERSONAL HYGIENE PRACTICE.
Supplemental Safety and Health: FIRE FIGHT PROC: MINIMIZING/DISPERSING VAPS
& COOLING EQUIP EXPOS TO HEAT & FLAME. AVOID SPREADING BURNING LIQ
W/WATER USED FOR COOLING PURPOSES. EXPLO HAZ: DISTS TO IGNIT SOURCE WHERE
THEY MAY IGNITE , FLASHBACK OR EXPLODE. VAP/AIR EXPLO HAZ INDOORS/OUTDOORS OR
IN SEWERS. VAPS ARE HVR/AIR & MAY ACCUM IN LOW
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >490F,>254C
Vapor Density: >1
Spec Gravity: 0.82-0.88
Solubility in Water: NEGLIGIBLE
Appearance and Odor: CLEAR TO YELLOW LIQUID; CHARACTERISTIC PETROLEUM ODOR.
Percent Volatiles by Volume: 100
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID CONTACT WITH ANY SOURCE OF HEAT OR FLAME.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: COMBUSTION MAY YIELD MAJOR AMOUNTS OF OXIDES
OF CARBON AND MINOR AMOUNTS OF OXIDES OF SULFUR AND NITROGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: 76 DIESEL 2 LS, 01614
Company: UNION OIL COMPANY OF CALIFORNIA
Street: 1345 NORTH MEACHAM ROAD
City: SCHAUMBURG IL
Zipcode: 60196
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 05/13/1997
Status Code: C
Label Date: 05/13/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: EYES: IRRITATION, STINGING, TEARING
AND REDNESS. SKIN: REDNESS, BURNING, DRYING, CRACKING AND SEVERE SKIN DAMAGE.
INHALATION: IRRITATION OF THE NOSE AND THROAT. INGESTION: ASPIRATI ON OF
MATERIAL INTO LUNGS DURING SWALLOWING OR VOMITING CAN CAUSE LUNG INFLAMMATION
AND DAMAGE. CHRONIC: ALLERGIC SKIN REACTION. KIDNEY AND LIVER DAMAGE IN LAB
ANIMALS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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