LOS ANGELES CHEMICAL CO -- CHROMIUM TRIOXIDE TECHNICAL
=======================================================
Material Safety Data Sheet
=======================================================
NIIN: 00-264-3939
MSDS Num: BQSWR
MSDS NAME: CHROMIUM TRIOXIDE TECHNICAL
Responsible Party
Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE ST
Box: 1987
City: SOUTH GATE CA 90280-2534
Emergency Phone Number: 213-562-9500
Preparer's Name: B. MARTINEZ
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE ST
Box: 1987
City: SOUTH GATE CA 90280
Phone: 213-562-9500
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: CHROMIUM TRIOXIDE,TECHNICAL
Unit of Issue: DR
Quantitative Expression: 00000000050LB
UI Container Qty: 1
Type of Container: DRUM
=======================================================
Ingredients
=======================================================
Cas: 1333-82-0
RTECS #: GB6650000
Name: CHROMIC ACID
% Wt: 99
Other REC Limits: NONE SPECIFIED
OSHA PEL: 100 MICRO GRAMS/M3
ACGIH TLV: 50 MICRO GRAMS/M3
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50, ORAL (RAT) 80 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE-INHALATION: MIST/DUST MAY CAUSE IRRITATION OF THE
NASAL SEPTUM & RESPIRATORY TRACT. EYE: MAY CAUSE SEVERE EYE DAMAGE &
EVEN BLINDNESS. SKIN: CORROSIVE,CAN CAUSE BURNS/IRRITATION. ABSORPTION MAY
LEAD TO KIDNEY FAILURE & DEATH. INGESTION: EXTREME TISSUE DESTRUCTION,
KIDNEY/LIVER FAILURE & DEATH.
Explanation Of Carcinogenicity: CHROMIUN AND CERTAIN CHROMIUM COMPOUNDS
(HEXAVALENT V1) ARE LISTED AS CARCINOGENS.
Signs And Symptions Of Overexposure: INHALATION OF MIST OR DUST MAY CAUSE
IRRITATION OF THE NASAL SEPTUM & RESPIRATORY TRACT. IT IS CORROSIVE AND
MAY CAUSE SEVERE EYE DAMAGE & EVEN BLINDNESS. CORROSIVE TO SKIN, CAN
CAUSE BURNS/IRRITATION . ABSORPTION THROUGH SKIN MAY LEAD TO KIDNEY FAILURE
& DEATH. KIDNEY/LIVER FAILURE & DEATH IF INGESTED.
Medical Cond Aggravated By Exposure: ANY CHRONIC LUNG OR SKIN CONDITION.
First Aid: GET MEDICAL CARE IN ALL CASES. INHALATION: REMOVE TO FRESH AIR.GIVE
CPR IF NOT BREATHING. EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES
HOLDING EYELIDS OPEN. DO NOT LET VICTIM RUB EYES OR KEEP THE M TIGHTLY SHUT.
SKIN: FLUSH WITH WATER FOR 15 MINUTES.PROMPTLY REMOVE CONTAMINATED CLOTHING.
INGESTION: DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK PLENTY OF WATER OR
MILK.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: NOTIFY SAFETY PERSONNEL AND EVACUATE ALL UNNECESSARY
PERSONNEL. CLEANUP PERSONNEL SHOULD PROTECT AGAINST DUST INHALATION AND EYE
CONTACT. KEEP COMBUSTIBLES AWAY FROM SPILLED MATERIAL. WHENEVER POSSIBL E,
USE WET CLEANUP METHODS.
Neutralizing Agent: AGRICULTURAL LIME, CRUSHED LIMESTONE OR SODIUM BICARBONATE
FOR WATER SPILLS.
Waste Disposal Methods: CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY
AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. EMPTY CONTAINERS CAN HAVE
RESIDUES, GASES AND MISTS AND ARE SUBJECT TO PROPER DISPOSAL METHODS .
Handling And Storage Precautions: STORE IN GLASS BOTTLES, CANS, OR DRUMS.
PROTECT AGAINST PHYSICAL DAMAGE. SEPERATE FROM COMBUSTIBLE, ORGANIC, OR OTHER
EASILY OXIDIZABLE MATERIALS.
Other Precautions: INSTITUTE PREPLACEMENT AND PERIODIC MEDICAL EXAMS OF EXPOSED
WORKERS WITH ATTENTION TO THE SKIN AND RESPIRATORY TRACT. CONSIDER
PREPLACEMENT AND PERIODIC CHEST RADIOGRAPHS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONE
Extinguishing Media: FOR SMALL FIRES, USE ONLY WATER, NOT DRY CHEMICAL, CARBON
DIOXIDE OR HALON.
Fire Fighting Procedures: ISOLATE HAZARD AREA AND DENY ENTRY. COOL FIRE-EXPOSED
CONTAINERS WITH FLOODING AMOUNTS OF WATER. WEAR A SELF- CONTAINED BREATHING
APPARATUS WITH FULL FACE PIECE
Unusual Fire/Explosion Hazard: A POWERFUL OXIDIZER, CHROMIC ACID IGNITES ON
CONTACT WITH ACETIC ACID AND ALCOHOL. IT MAY REACT RAPIDLY ENOUGH WITH
ORGANIC MATERIALS TO CAUSE IGNITION.
=======================================================
Control Measures
=======================================================
Respiratory Protection: SEEK PROFESSIONAL ADVICE PRIOR TO RESPIRATOR SELECTION
AND USE.
Ventilation: LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING DUST
EMISSIONS AT THE POINT OF USE BELOW THE PEL.
Protective Gloves: IMPERVIOUS
Eye Protection: CHEMICAL SAFETY GOGGLES
Other Protective Equipment: EYE WASH STATION, SAFETY SHOWER, BOOTS, APRONS, AND
GAUNTLETS
Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health: NOTE TO PHYSICIAN: AFTER DECONTAMINATION AND
NEUTRALIZATION, TREATMENT OF ACID BURNS IS SIMILAR TO THAT OF THERMAL BURNS.
FOR SEVERE ACID BURNS, FLUID RESUSCITATION IS CRITICAL TO PREVENT MORTALITY
FR OM HYPOVOLEMIA AND RENAL FAILURE. MONITOR SERIAL VITAL SIGNS, URINE
OUTPUT, ELECTROLYTES, BLOOD COUNT, AND URINALYSIS.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: D3
M.P/F.P Text: 385F,196C
Decomp Text: 482F,250C
Spec Gravity: 2.7
Appearance and Odor: DARK, PURPLISH-RED, PRISMATIC, DELIQUESCENT (MOISTURE
ABSORBING FROM AIR NO ODO
Corrosion Rate: UNKNOWN
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXCESS HEAT
Materials To Avoid: COMBUSTIBLE OR ORGANIC MATERIALS
Hazardous Decomposition Products: CARBON DIOXIDE, SMOKE AND IRRITATING TOXIC
FUMES.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 63027
MSDS NAME: CHROMIUM TRIOXIDE TECHNICAL
MSDS Prepared Date: 05/18/1993
Review Date: 03/13/1996
Net Unit Weight: 50 POUNDS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 1
Type Of Container: DRUM
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: DJH
Symbols: D
DOT Proper Shipping Name: CHROMIC ACID, SOLID
Hazard Class: 5.1
UN ID Num: NA1463
DOT Packaging Group: II
Label: OXIDIZER, CORROSIVE
Non Bulk Pack: 212
Bulk Pack: 242
Max Qty Pass: 5 KG
Max Qty Cargo: 25 KG
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: EKD
IMO Proper Shipping Name: CHROMIUM TRIOXIDE, ANHYDROUS
IMDG Page Number: 5145
UN Number: 1463
UN Hazard Class: 5.1
IMO Packaging Group: II
Subsidiary Risk Label: CORROSIVE
EMS Number: 5.1-05
MED First Aid Guide NUM: 700
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: GVR
IATA UN ID Num: 1463
IATA Proper Shipping Name: CHROMIUM TRIOXIDE, ANHYDROUS
IATA UN Class: 5.1
Subsidiary Risk Class: 8
IATA Label: OXIDIZER & CORROSIVE
UN Packing Group: II
Packing Note Passenger: 508
Max Quant Pass: 5KG
Max Quant Cargo: 25KG
Packaging Note Cargo: 511
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: GUD
AFI Symbols: D
AFI Proper Shipping Name: CHROMIC ACID, SOLID
AFI PSN Modifier: CHROMIC ACID, SOLID; ALSO SEE CHROMIUM TRIOXIDE, ANHYDROUS
AFI Hazard Class: 5.1
AFI UN ID NUM: NA1463
AFI Packing Group: II
AFI Label: 8
Special Provisions: P5
Back Pack Reference: A9.8
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: CHROMIUM TRIOXIDE TECHNICAL
Company: LOS ANGELES CHEMICAL CO
Street: 4545 ARDINE ST
PO Box: 1987
City: SOUTH GATE CA
Zipcode: 90280
Health Emergency Phone: 213-583-4761
Label Required IND: Y
Date Of Label Review: 06/01/1993
Status Code: C
Label Date: 06/01/1993
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: ACUTE-INHALATION: MIST/DUST MAY CAUSE IRRITATION OF THE
NASAL SEPTUM & RESPIRATORY TRACT. EYE: MAY CAUSE SEVERE EYE DAMAGE &
EVEN BLINDNESS. SKIN: CORROSIVE,CAN CAUSE BURNS/IRRITATION. ABSORPTION MAY
LEAD TO KIDNEY FAILURE & DEATH. INGESTION: EXTREME TISSUE DESTRUCTION,
KIDNEY/LIVER FAILURE & DEATH. STORE IN GLASS BOTTLES, CANS, OR DRUMS.
PROTECT AGAINST PHYSICAL DAMAGE. SEPERATE FROM COMBUSTIBLE, ORGANIC, OR
OTHER EASILY OXIDIZABLE MATERIALS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|