ethyl cyanoacrylate polymethylmethacrylate;(poly(methyl methacrylate)) silica, amorphous fumed;(silica, amorphous treated) hydroquinone (sara iii) volatile organic compounds first aid proc:then remove from skin w/soap & water. do not try to ing 6:action. burns should be treated normally after lump of ing 7:in event that eyelids are stuck together or bonded to eyeball, wash ing 8:patch. the eye will open w/out further action, typically in 1-4 ing 9:do not try to open the eyes by manipulation. surgery:it should ing 10:method to seperate accidentally bonded skin. accidents due to ing 11:nonsurgical first aid. supp data:increase in temperature enough to cause a burn. target
LOCTITE CORP -- PRISM 454 SURFACE INSENSITIVE GEL INSTANT (
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BQTQM
MSDS NAME: PRISM 454 SURFACE INSENSITIVE GEL INSTANT (
Responsible Party
Name: LOCTITE CORP
Address: 703 NORTH MOUNTAIN RD
City: NEWINGTON CT 06111
Info Phone: 203-278-1280
Emergency Phone Number: 203-278-1280
Preparer's Name: STEPHEN REPETTO
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORP
Address: 705 N MT RD
City: NEWINGTON CT 06111
Phone: 312-689-6200
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
=======================================================
Ingredients
=======================================================
Cas: 7085-85-0
Name: ETHYL CYANOACRYLATE
% Wt: 85-90
Other REC Limits: 2 PPM (MFR)
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE;(POLY(METHYL METHACRYLATE))
% Wt: 5-10
------------------------------
Cas: 112945-52-5
RTECS #: VV7310000
Name: SILICA, AMORPHOUS FUMED;(SILICA, AMORPHOUS TREATED)
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE (SARA III)
% Wt: 0.1-0.5
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS
% Wt: 85.4
-----------------------------
Name: FIRST AID PROC:THEN REMOVE FROM SKIN W/SOAP & WATER. DO NOT TRY TO
PULL SURFS APART W/DIRECT OPPOSING
-----------------------------
Name: ING 6:ACTION. BURNS SHOULD BE TREATED NORMALLY AFTER LUMP OF
CYANOACRYLATE IS RELSD FROM TISS AS NOTED. EYE:
-----------------------------
Name: ING 7:IN EVENT THAT EYELIDS ARE STUCK TOGETHER OR BONDED TO EYEBALL, WASH
THORO W/WARM WATER & APPLY A GAUZE
-----------------------------
Name: ING 8:PATCH. THE EYE WILL OPEN W/OUT FURTHER ACTION, TYPICALLY IN 1-4
DAYS. THERE WILL BE NO RESIDUAL DAMAGE.
-----------------------------
Name: ING 9:DO NOT TRY TO OPEN THE EYES BY MANIPULATION. SURGERY:IT SHOULD
NEVER BE NECESSARY TO USE SUCH A DRASTIC
-----------------------------
Name: ING 10:METHOD TO SEPERATE ACCIDENTALLY BONDED SKIN. ACCIDENTS DUE TO
CYANOACRYLATES ARE HANDLED BEST BY PASSIVE,
-----------------------------
Name: ING 11:NONSURGICAL FIRST AID.
-----------------------------
Name: SUPP DATA:INCREASE IN TEMPERATURE ENOUGH TO CAUSE A BURN. TARGET
ORGANS:LUNGS, SKIN.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50:(ORAL RAT)>5000 MG/KG.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE IRRITANT.
VAPOR IS IRRITATING TO EYES & MUCOUS MEMBRANES ABOVE TLV. PRLNGD/RPTD
OVEREXP TO VAPS MAY PRODUCE ALLERG RXNS W/ASTHMA-LIKE SYMPS IN SENSITIVE I
NDIV. CYANOACRYLATE ADHESIVE IS VERY FAST SETTING & STRONG ADHESIVE. IT
BONDS HUMAN TISS INCL SKIN (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:IN SECONDS. ADHESIVE ON
EYEBALL:CYANOACRYLATE INTRODUCED INTO EYES WILL ATTACH ITSELF TO EYE PROTEIN
& WILL DISASSOCIATE FROM IT OVER INTERMITTENT PERIODS, GENERALLY COVERING
SEVERAL HOURS. T HIS WILL CAUSE PERIODS OF WEEPING UNTILCLEARANCE ACHIEVED.
DURING PERIOD OF CONTAM, DOUBLE VISION MAY BE (SUPP DATA)
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INGEST:IF LIPS ACCIDENTALLY STUCK TOGETHER, APPLY LOTS OF WARM WATER
TO LIPS & ENCOURAGE MAX WETTING & PRESS FROM SALIVA INSIDE MOUTH.
PEEL/ROLL LIPS APART. DO NOT TRY TO PULL LIPS W/DIRECT OPPOSING A CTION.
INHAL:MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. SKIN:FIRST IMMERSE BONDED
SURF IN WARM SOAPY WATER. PEEL OR ROLL SURFACE APART W/AID OF A BLUNT EDGE,
E.G., SPATULA OR TEASPOON HANDLE;
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE. SOAK UP WITH AN INERT
MATERIAL.
Neutralizing Agent: NONE NORMALLY REQUIRED.
Waste Disposal Methods: POLYMERIZE AS NOTED. INCINERATE FOLLOWING EPA AND LOCAL
REGULATIONS. DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS (FP N).
Handling And Storage Precautions: STORE AT OR BELOW 75F TO MAXIMIZE SHELF LIFE.
Other Precautions: AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >150F,>66C
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: POLYETHYLENE GLOVES.
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: DO NOT USE COTTON GLOVES.
Supplemental Safety and Health: MFR PT#/TRADE NAME:ADHESIVE, 45440. EFTS OF
OVEREXP:EXPERIENCED TOGETHER W/LACHRYMATORY EFT, & IT IS IMPORTANT TO
UNDERSTAND CAUSE & REALIZE THAT DISASSOCIATION WILL NORMALLY OCCUR W/IN
MATTER OF HOUR S, EVEN W/GROSS CONTAM. BURNS:CYANOACRYLATES GIVE OFF HEAT ON
SOLIDIFICATION. IN RARE CASES A LRG DROP WILL
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >300F,>149C
Vapor Pres: <0.2
Vapor Density: 3
Spec Gravity: 1.05
Solubility in Water: POLYMERIZED BY WATER
Appearance and Odor: CLEAR LIQUID WITH SHARP, IRRITATING ODOR
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: NONTHERMAL:NONE. BY FIRE OR THERMAL
DECOMPOSITION:IRRITATING ORGANIC VAPORS.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: POLYMERIZED BY CONTACT WITH WATER,
ALCOHOLS, AMINES, ALKALIES.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
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MSDS Transport Information
=======================================================
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Regulatory Information
=======================================================
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Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PRISM 454 SURFACE INSENSITIVE GEL INSTANT (
Company: LOCTITE CORP
Street: 705 N MT RD
City: NEWINGTON CT
Zipcode: 06111
Health Emergency Phone: 203-278-1280
Label Required IND: Y
Date Of Label Review: 12/11/1992
Status Code: C
Label Date: 12/11/1992
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: COMBUSTIBLE LIQUID. AVOID WATER. CONTACT MAY BOND
TISSUE INCLUDING SKIN IN SECONDS. SKIN AND EYE CONTACT MAY CAUSE IRRITATION.
SKIN CONTACT WITH LARGE AMOUNTS MAY CAUSE BURNS. EYE CONTACT MAY CAUSE WE
EPING AND DOUBLE VISION. VAPORS MAY BE IRRITATING TO EYES AND MUCOUS
MEMBRANES. INGESTION MAY CAUSE LIPS TO BE STUCK TOGETHER OR MAY CAUSE
ADHESIVE TO SOLIDIFY, ADHERE IN MOUTH, OR FORM LUMP. CHRONIC: PROLONGED AND
REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE ALLERGIC REACTIONS WITH
ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.