ing 6: diglycidyl ether of bisphenol a (component of this prod) have ing 7: mutagenicity assays. both have shown activity by in vitro ing 8: chromosomal aberrations in cultured rat liver cells. first aid proc: water to dilute if patient is conscious. get med attn. ing 10: is unnecessary in high viscosity, low volatility products, eg, spill proc: dispose of properly. flush area w/water to remove trace ing 12: drainage/sewer systems, waterways & surface waters. other precs: discard contam leather articles. handle mixed resin & ing 14: used. provide approp vent/niosh apprvd resp prot against decomp ing 15: operations & to protect against nuisance dust during vent: applications. local exhaust is recommended for confined areas. eye prot: & full length faceshield (fp n). msds toxicity property">
butyl glycidyl ether. ld50: (oral, rat) 1000 mg/kg. bisphenol a diglycidyl ether resin. ld50: (oral, rat) 30 g/kg. volatile organic compound: 0 g/l efts of overexp: concluded that the renal tumor evididence w/epon 828 ing 5: the resin "is not a systemic carcinogen when applied to the dorsal ing 6: diglycidyl ether of bisphenol a (component of this prod) have ing 7: mutagenicity assays. both have shown activity by in vitro ing 8: chromosomal aberrations in cultured rat liver cells. first aid proc: water to dilute if patient is conscious. get med attn. ing 10: is unnecessary in high viscosity, low volatility products, eg, spill proc: dispose of properly. flush area w/water to remove trace ing 12: drainage/sewer systems, waterways & surface waters. other precs: discard contam leather articles. handle mixed resin & ing 14: used. provide approp vent/niosh apprvd resp prot against decomp ing 15: operations & to protect against nuisance dust during vent: applications. local exhaust is recommended for confined areas. eye prot: & full length faceshield (fp n). msds toxicity property">
MSDS
:
MARINE TEX GRAY RESIN, 3001R
CAS
:
1333-86-4 2426-08-6 25068-38-6
NAME
:
carbon black butyl glycidyl ether. ld50: (oral, rat) 1000 mg/kg. bisphenol a diglycidyl ether resin. ld50: (oral, rat) 30 g/kg. volatile organic compound: 0 g/l efts of overexp: concluded that the renal tumor evididence w/epon 828 ing 5: the resin "is not a systemic carcinogen when applied to the dorsal ing 6: diglycidyl ether of bisphenol a (component of this prod) have ing 7: mutagenicity assays. both have shown activity by in vitro ing 8: chromosomal aberrations in cultured rat liver cells. first aid proc: water to dilute if patient is conscious. get med attn. ing 10: is unnecessary in high viscosity, low volatility products, eg, spill proc: dispose of properly. flush area w/water to remove trace ing 12: drainage/sewer systems, waterways & surface waters. other precs: discard contam leather articles. handle mixed resin & ing 14: used. provide approp vent/niosh apprvd resp prot against decomp ing 15: operations & to protect against nuisance dust during vent: applications. local exhaust is recommended for confined areas. eye prot: & full length faceshield (fp n).
ITW PHILADELPHIA RESINS -- MARINE TEX GRAY RESIN, 3001R
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CHXVK
MSDS NAME: MARINE TEX GRAY RESIN, 3001R
Kit Part: Y
Responsible Party
Name: ITW PHILADELPHIA RESINS
Address: 130 COMMERCE DR
City: MONTGOMERYVILLE PA 18936
Info Phone: 215-855-8450
Emergency Phone Number: 800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ITW PHILADELPHIA RESINS
Address: 130 COMMERCE DR
City: MONTGOMERYVILLE PA 18936
Phone: 215-855-8450
Name: ITW PHILADELPHIA RESINS
Address: 130 COMMERCE DRIVE
Box: 454
City: MONTGOMERYVILLE PA 18936
Phone: 508-777-1100
=======================================================
Ingredients
=======================================================
Cas: 1333-86-4
RTECS #: FF5800000
Name: CARBON BLACK
% Wt: <1
OSHA PEL: 3.5 MG/M3
ACGIH TLV: 3.5 MG/M3
------------------------------
Cas: 2426-08-6
RTECS #: TX4200000
Name: BUTYL GLYCIDYL ETHER. LD50: (ORAL, RAT) 1000 MG/KG.
% Wt: 1-10
OSHA PEL: 50 PPM
ACGIH TLV: 25 PPM
------------------------------
Cas: 25068-38-6
RTECS #: SL6475000
Name: BISPHENOL A DIGLYCIDYL ETHER RESIN. LD50: (ORAL, RAT) 30 G/KG.
% Wt: 30-40
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: 0 G/L
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: EFTS OF OVEREXP: CONCLUDED THAT THE RENAL TUMOR EVIDIDENCE W/EPON 828
"WAS OF NO BIOLOGICAL SIGNIFICANCE" & THAT
-----------------------------
Name: ING 5: THE RESIN "IS NOT A SYSTEMIC CARCINOGEN WHEN APPLIED TO THE DORSAL
SKIN OF CF1 MICE." BOTH THE RESIN & THE
-----------------------------
Name: ING 6: DIGLYCIDYL ETHER OF BISPHENOL A (COMPONENT OF THIS PROD) HAVE
PROVED TO BE INACTIVE WHEN TESTED IN VIVO
-----------------------------
Name: ING 7: MUTAGENICITY ASSAYS. BOTH HAVE SHOWN ACTIVITY BY IN VITRO
MICROBIAL MUTAGENICITY SCREENING & HAVE PRDCED
-----------------------------
Name: ING 8: CHROMOSOMAL ABERRATIONS IN CULTURED RAT LIVER CELLS.
-----------------------------
Name: FIRST AID PROC: WATER TO DILUTE IF PATIENT IS CONSCIOUS. GET MED ATTN.
NOTE TO MD: IN GENERAL, EMESIS INDUCTION
-----------------------------
Name: ING 10: IS UNNECESSARY IN HIGH VISCOSITY, LOW VOLATILITY PRODUCTS, EG,
HEAT EPOXY RESINS.
-----------------------------
Name: SPILL PROC: DISPOSE OF PROPERLY. FLUSH AREA W/WATER TO REMOVE TRACE
RESIDUE. PREVENT SPILL FROM ENTERING
-----------------------------
Name: ING 12: DRAINAGE/SEWER SYSTEMS, WATERWAYS & SURFACE WATERS.
-----------------------------
Name: OTHER PRECS: DISCARD CONTAM LEATHER ARTICLES. HANDLE MIXED RESIN &
HARDENER I/A/W POTENTIAL HAZ OF CURING AGENT
-----------------------------
Name: ING 14: USED. PROVIDE APPROP VENT/NIOSH APPRVD RESP PROT AGAINST DECOMP
PRODS DURING WELDING/FLAME CUTTING
-----------------------------
Name: ING 15: OPERATIONS & TO PROTECT AGAINST NUISANCE DUST DURING
SANDING/GRINDING OF CURED PRODUCT.
-----------------------------
Name: VENT: APPLICATIONS. LOCAL EXHAUST IS RECOMMENDED FOR CONFINED AREAS.
-----------------------------
Name: EYE PROT: & FULL LENGTH FACESHIELD (FP N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50: (ORAL, RAT) 11,400 MG/KG
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: SKIN: MODERATE IRRITANT. CONTACT AT ELEVATED TEMPS CAN
CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSIT (RASHES, HIVES). EYES: MODERATE
IRRITANT. CONTACT AT ELEVATED TEMPS CAN CAUSE THERMAL BURNS. INHAL: LO W
VAPOR PRESS OF RESIN MAKES INHAL UNLIKELY IN NORM USE. INGEST: ACUTE ORAL
TOXICITY IS LOW. MAY CAUSE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS, VOL 65, PG 149,
1996:GROUP 2B.
Signs And Symptions Of Overexposure: HLTH HAZ: GASTRIC DISTRSS. CHRONIC:
PRLNGD/RPTD SKIN CNTCT MAY CAUSE SENSIT W/ITCHING, SWELLING OR RASHES ON
LATER EXPOS. TOXICOLOGICAL INFO: CHRONIC EFTS: 2-YR BIOASSAYS IN MICE EXPOSED
BY DERMAL ROU TE TO EPON 828, DGEBPA OR OTHER COMMERCIAL RESINS YIELDED
LIMITED EVIDENCE OF WEAK CARCINOGENICITY. AUTHORS
Medical Cond Aggravated By Exposure: PREEXISTING EYE AND SKIN DISORDERS.
DEVELOPMENT OF PREEXISTING SKIN OR LUNG ALLERGY SYMPTOMS MAY INCREASE.
First Aid: EYES: FLUSH EYE W/CLEAN WATER FOR AT LEAST 15 MIN WHILE GENTLY
HOLDING EYELIDS OPEN. GET IMMED MED ATTN. SKIN: IMMED REMOVE CONTAM CLTHG
& EXCESS CONTAMINANT. FLUSH SKIN W/WATER. WASH THOROUGHLY W/SOA P &
WARM WATER. CONSULT MD IF IRRIT DEVELOPS. INHAL: REMOVE TO FRESH AIR. ADMIN
OXYGEN IF BRTHG IS DFCLT. GET MED ATTN IF SYMPS PERSIST. INGEST: DO NOT
INDUCE VOMITING. GIVE TWO GLASSES OF
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AVOID PERSONAL CONTACT. ELIMINATE IGNIT SOURCES. VENT
AREA. DIKE, CONTAIN & ABSORB W/CLAY, SAND OR OTHER SUITABLE MATL. FOR
LARGE SPILLS, PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB SUCH
AS CLAY, SAND OR OTHER SUITABLE MATL &
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: IF THIS RESIN BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40CFR261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY AREA AWAY FROM HIGH
TEMPERATURES AND FLAME.
Other Precautions: AVOID CONTACT W/SKIN, EYES OR CLTHG. WASH THOROUGHLY W/SOAP
& WATER AFTER USING & PARTICULARLY BEFORE EATING, DRINKING, SMOKING,
APPLYING COSMETICS OR USING TOILET FACILITIES. LAUNDER CONTAM CLTHG & P
ROTECTIVE GEAR BEFORE REUSE.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point Text: >400F,>204C
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED SPACE W/OUT
FULL BUNKER GEAR. COOL FIRE (SUPDAT)
Unusual Fire/Explosion Hazard: HEATING ABOVE 300F IN PRESENCE OF AIR MAY CAUSE
SLOW OXIDATIVE DECOMP & ABOVE 500F MAY CAUSE POLYM. WHEN HEATED TO DECOMP
IT EMITS FUMES OF CL, CARBON (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE REQUIRED AT NORMAL HANDLING TEMPERATURES AND
CONDITIONS. USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGES FOR UNCURED RESIN AND
DUST/PARTICLE RESPIRATORS DURING GRINDING/SANDING OPERATIONS OF CURED RE SIN
AS EXPOSURE LEVELS DICTATE.
Ventilation: LOCAL EXHAUST VENT IS PREFERRED ALTHOUGH GOOD GENERAL MECHANICAL
VENT IS USUALLY ADEQUATE FOR MOST INDUSTRIAL
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
OTHER GEAR AS REQUIRED TO PREVENT SKIN CONTACT.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: PH (5% SOLN OR SLURY IN WATER): NEUTRAL. FIRE
FIGHT PROC: EXPOSED CNTNRS W/WATER. EXPLO HAZ: MONOXIDE, OTHER FUMES &
VAPS VARYING IN COMPOSITION & TOXICITY. CNDTNS TO AVOID: WAY CURE RXNS
MAY CHAR & D ECOMPOSE RESIN, GENERATING UNIDENTIFIEDFUMES & VAPS
WHICH MAY BE TOXIC. MATLS TO AVOID: SECONDARY ALIPHATIC AMINES).
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >500F,>260C
Vapor Pres: 0.03 @171F
Vapor Density: >1
Spec Gravity: 1.7
PH: SUPDAT
Solubility in Water: NEGLIGIBLE
Appearance and Odor: GREY VISCOUS LIQUID WITH LITTLE ODOR.
Percent Volatiles by Volume: 0
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: OPEN FLAME & EXTREME HEAT. CNDTNS OF HAZ POLYM:
HEAT IS GENERATED WHEN RESIN IS MIXED W/CURING AGENTS; RUN-A- (SUPDAT)
Materials To Avoid: STRONG LEWIS OR MINERAL ACIDS, STRONG OXIDIZING AGENTS,
STRONG MINERAL & ORGANIC BASES (ESPECIALLY PRIMARY & (SUPDAT)
Hazardous Decomposition Products: OXIDES OF CARBON; ALDEHYDES, ACIDS & OTHER
ORG SUBSTANCES MAY BE FORMED DURING COMBUST/ELEVATED TEMP(>500F) DEGRADATION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: MARINE TEX GRAY RESIN, 3001R
Company: ITW PHILADELPHIA RESINS
Street: 130 COMMERCE DRIVE
PO Box: 454
City: MONTGOMERYVILLE PA
Zipcode: 18936
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 10/26/1998
Status Code: C
Label Date: 10/26/1998
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SKIN: MODERATE IRRITANT. CONTACT AT ELEVATED
TEMPS CAN CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION (RASHES, HIVES).
EYES: MODERATE IRRITANT. CONTACT AT ELEVATED TEMPS CAN CAUSE THERMAL BU RNS.
INGESTION: MAY CAUSE GASTRIC DISTRESS. CHRONIC: CANCER HAZARD. CONTAINS
CARBON BLACK WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). PROLONGED
OR REPEATED SKIN CONTACT MAY CAUSE SENSITIZATIO N WITH ITCHING, SWELLING OR
RASHES ON LATER EXPOSURE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.