carbon tetrachloride (sara 313) (cercla). ld50: (oral, rat) 2350 mg/kg. methacrylic acid. ld50: (oral, rat) 1060 mg/kg. methacrylic acid, methyl ester; (methyl methacrylate monomer) (sara 313) volatile organic compound: not determined supdat: at levels tox to mother. toxicological info: acute: ingest:tox of ing 5: urine & liver chgs. skin:derm. inhal:tox of mma at 8-100 times ing 6: sys efts & blood in urine. subchronic efts: inhal:rptd expos ing 7: pulm irrit, liver chgs, eye irrit, nasal tiss chgs, incoord & ing 8: efts w/altered func in both organs. skin permeation may occur. ing 9: of mma caused inflam of nasal cavity, chgs in nasal sensory cells ing 10: cause decreased body weight & increased kidney weight. first aid proc: to dilute if patient is conscious. get med attn. spill proc: dispose of properly (rcra haz waste). add inhibitor to ing 13: entering drainage/sewer systems, waterways & surface waters. hndlg/stor precs: pouring. keep away from heat, flame or sparks. use ing 15: direct expos to sunlight. keep container tightly closed & ing 16: in storage containers.
ITW DEVCON -- PLASTIC WELDER ADHESIVE, DA310
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CHXLP
MSDS NAME: PLASTIC WELDER ADHESIVE, DA310
Kit Part: Y
Responsible Party
Name: ITW DEVCON
Address: 30 ENDICOTT ST
City: DANVERS MA 01923
Info Phone: 508-777-1100
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: DEVCON CORP
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3753
Phone: 1-508-777-1100
Name: ITW DEVCON
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3712
Phone: 978-777-1100
=======================================================
Ingredients
=======================================================
Cas: 56-23-5
RTECS #: FG4900000
Name: CARBON TETRACHLORIDE (SARA 313) (CERCLA). LD50: (ORAL, RAT) 2350 MG/KG.
% Wt: <1
OSHA PEL: 10 PPM
ACGIH TLV: 5 PPM; 10 STEL, S
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
Ozone Depleting Chemical: 1
------------------------------
Cas: 79-41-4
RTECS #: OZ2975000
Name: METHACRYLIC ACID. LD50: (ORAL, RAT) 1060 MG/KG.
% Wt: 5-15
OSHA PEL: 20 PPM, S
ACGIH TLV: 20 PPM
------------------------------
Cas: 80-62-6
RTECS #: OZ5075000
Name: METHACRYLIC ACID, METHYL ESTER; (METHYL METHACRYLATE MONOMER) (SARA 313)
(CERCLA). LD50: (ORAL, RAT) 7872 MG/KG.
% Wt: 55-65
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: NOT DETERMINED
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: AT LEVELS TOX TO MOTHER. TOXICOLOGICAL INFO: ACUTE: INGEST:TOX OF
MMA EXPOSED NEAR LD50 INCL BLOOD IN
-----------------------------
Name: ING 5: URINE & LIVER CHGS. SKIN:DERM. INHAL:TOX OF MMA AT 8-100 TIMES
TLV FROM RESP & GI IRRIT, LUNG DMG, NERVOUS
-----------------------------
Name: ING 6: SYS EFTS & BLOOD IN URINE. SUBCHRONIC EFTS: INHAL:RPTD EXPOS
OF MMA AT 5-100 TIMES TLV INCL LUNG DMG,
-----------------------------
Name: ING 7: PULM IRRIT, LIVER CHGS, EYE IRRIT, NASAL TISS CHGS, INCOORD &
UPPER RESP IRRIT. INGEST:LIVER & KIDNEY
-----------------------------
Name: ING 8: EFTS W/ALTERED FUNC IN BOTH ORGANS. SKIN PERMEATION MAY OCCUR.
OTHER CHRONIC EFTS: INHAL:LONG TERM EXPOS
-----------------------------
Name: ING 9: OF MMA CAUSED INFLAM OF NASAL CAVITY, CHGS IN NASAL SENSORY CELLS
& DECREASED BODY WEIGHT. INGEST:CAN
-----------------------------
Name: ING 10: CAUSE DECREASED BODY WEIGHT & INCREASED KIDNEY WEIGHT.
-----------------------------
Name: FIRST AID PROC: TO DILUTE IF PATIENT IS CONSCIOUS. GET MED ATTN.
-----------------------------
Name: SPILL PROC: DISPOSE OF PROPERLY (RCRA HAZ WASTE). ADD INHIBITOR TO
PREVENT POLYMERIZATION. PREVENT SPILL FROM
-----------------------------
Name: ING 13: ENTERING DRAINAGE/SEWER SYSTEMS, WATERWAYS & SURFACE WATERS.
USE NON-SPARKING TOOLS.
-----------------------------
Name: HNDLG/STOR PRECS: POURING. KEEP AWAY FROM HEAT, FLAME OR SPARKS. USE
NON-SPKG TOOLS. KEEP IN COOL PLACE W/OUT
-----------------------------
Name: ING 15: DIRECT EXPOS TO SUNLIGHT. KEEP CONTAINER TIGHTLY CLOSED &
OTHERWISE I/A/W NFPA REGS. MAINTAIN AIR SPACE
-----------------------------
Name: ING 16: IN STORAGE CONTAINERS.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50: (ORAL, RAT) >2000 MG/KG ESTIMATE
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT FOR
LIFE-SUSTAININ G USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS
(FP N). SKIN: MAY CAUSE IRRIT & SENSIT. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CARBON TETRACHLORIDE:IARC MONO, SUPP, VOL 7, PG
143, 1987:GRP2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE CARCIN.
Signs And Symptions Of Overexposure: HLTH HAZ: EYES: LIQ & VAP CAUSES MOD
IRRIT. INHAL: HIGH CONC IS IRRITANT TO RESP TRACT & MAY CAUSE DIZZ, HDCH
& ANESTH EFTS. INGEST:CAUSES IRRIT, BURNING SENSATION OF MOUTH, THROAT
& GI TRACT & ABDOM PAIN. CHRONIC: PRLNGD EXPOS MAY LEAD TOKIDNEY,
LUNG & LIVER DMG. NOT LIKELY TO CAUSE CANCER. NOT BELIEVED TO (SUPDAT)
Medical Cond Aggravated By Exposure: PREEXISTING EYE AND SKIN DISORDERS.
First Aid: EYES: FLUSH EYES W/CLEAN WATER FOR AT LEAST 15 MIN WHILE GENTLY
HOLDING EYELIDS OPEN. GET IMMED MED ATTN. SKIN: IMMED REMOVE CONTAM CLTHG
& EXCESS CONTAMINANT. FLUSH SKIN W/WATER. WASH THOROUGHLY W/WA RM SOAP
& WATER. CONSULT MD IF IRRIT DEVELOPS. INHAL: REMOVE TO FRESH AIR. ADMIN
OXYGEN IF BRTHG IS DFCLT. GET MED ATTN IF SYMPS PERSIST. INGEST: DO NOT
INDUCE VOMIT. GIVE 2 GLASSES OF WATER
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AVOID PERSONAL CNTCT. ELIM IGNIT SOURCES. VENT AREA.
DIKE, CNTN & ABSORB W/CLAY, SAND OR OTHER SUITABLE NON-COMBUST MATL. FOR
LG SPILLS, PUMP TO STORAGE/SALVAGE VESSLES. SOAK UP RESIUDE W/ABSORB SUCH AS
CLAY, SAND OR OTHER SUITABLE MATL & (ING 13_
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS (FP N). DO NOT DISPOSE OF IN A LANDFILL. INCINERATION IS
THE PREFERRED METHOD OF DISPOSAL. THE FOLLOWING RCRA CODES APPLY TO TH IS
MATERIAL IF IT BECOMES WASTE: D001, D019.
Handling And Storage Precautions: DO NOT BREATHE VAP/MIST. DO NOT GET IN EYES,
ON SKIN OR CLTHG. WASH THOROUGHLY AFTER HNDLG. CLOSE CNTNR AFTER EACH USE.
GROUND CNTNR WHEN
Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF
ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIATION MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE (FP N). KEEP CONTAINER TIGHTLY CL
OSED. OBSERVE LABEL PRECAUTIONS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 50.0F,10.0C
Lower Limits: 2.1%
Upper Limits: 12.5%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: WEAR NIOSH APPRVD PRESS DEMAND SCBA & FULL PROT
EQUIP (FP N). KEEP PERS REMOVED & UPWIND FROM FIRE. COOL TANK W/WATER
SPRAY. FIGHT FIRE FROM DISTANCE (SUPDAT)
Unusual Fire/Explosion Hazard: THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE
(FP N). VAP FORMS EXPLO MIX W/AIR. SEALED CNTNRS AT ELEVATED TEMPS MAY
RUPTURE DUE TO POLYM. VAPS ARE (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPRVD AIR PURIFYING RESPIRATOR WITH AN ORGANIC
VAPOR CARTRIDGE MAY BE PERMISSIBLE, HOWEVER, USE A NIOSH APPRVD POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLL ED
RELEASE OR UNKNOWN EXPOSURE LEVELS.
Ventilation: USE VENTILATION THAT IS ADEQUATE TO KEEP EMPLOYEE EXPOSURE TO
AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). WEAR
IMPERVIOUS BUTYL RUBBER CLOTHING TO PREVENT ANY CONTAMINATION.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: PH (5% SOLN OR SLURRY IN WATER): 3.0-3.5. FIRE
FIGHT PROC: AS HEAT MAY RUPTURE THE TANKS. EXPLO HAZ: HVR/AIR & MAY
TRAVEL TO IGNIT SOURCES & FLASH BACK. HAZ COMBUST PRODS:CO, CO*2 &
SMOKE. EFTS OF OVE REXP: REPRESENT CARCIN OR MUTAGENIC HAZ. OTHER
EFTS:DEVELOPMENTAL TOX OBSERVED IN ANIMAL TESTS W/MMA BUT ONLY
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 213F,101C
Vapor Pres: 28 @ 685
Vapor Density: >1
Spec Gravity: 1.03
PH: SUPDAT
Evaporation Rate & Reference: 3 (BUTYL ACETATE=1)
Appearance and Odor: OFF-WHITE PASTE WITH VARIED FRAGRANT ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: NO
Stability Condition To Avoid: UNSTABLE WITH HEAT.
Materials To Avoid: INCOMPAT W/STRONG OXIDIZING AGENTS & REDUCING AGENTS, ACIDS
& BASES. MATL IS STRONG SOLVENT & CAN SOFTEN PAINT & RUBBER.
Hazardous Decomposition Products: HCL, PHOSGENE (FP N). CARBON MONOXIDE, CARBON
DIOXIDE AND SMOKE.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: EXCESSIVE HEAT, STORAGE IN ABSENCE OF
INHIBITOR AND INADVERTANT ADDITION OF CATALYST.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PLASTIC WELDER ADHESIVE, DA310
Company: ITW DEVCON
Street: 30 ENDICOTT ST
City: DANVERS MA
Zipcode: 01923-3712
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 10/14/1998
Status Code: C
Label Date: 10/14/1998
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: Moderate
Hazard And Precautions: FLAMMABLE. HAZARDOUS POLYMERIZATION MAY OCCUR.
DECOMPOSITION PRODUCTS MAY BE HAZARDOUS. ACUTE: INHALATION OF VAPORS MAY
CONTRIBUTE TO THE OCCURRENCE OF IRREGULAR HEARTBEAT (FP N). SKIN: MAY CAUSE
IRRI TATION AND SENSITIZATION. EYES: LIQUID AND VAPORS CAUSE MODERATE
IRRITATION. INHALATION: HIGH CONCENTRATION IS IRRITANT TO RESPIRATORY TRACT
AND MAY CAUSE DIZZINESS, HEADACHE AND ANESTHETIC EFFECTS. I NGESTION: CAUSES
IRRITATION, BURNING SENSATION OF MOUTH, THROAT AND GI TRACT AND ABDOMINAL
PAIN. CHRONIC: CANCER HAZARD. CONTAINS CARBON TETRACHLORIDE WHICH IS LISTED
AS AN ANIMAL LIVER CARCINOGEN (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.