carbon tetrachloride (sara 313) (cercla). ld50:(oral,rat) 2350 mg/kg. methacrylic acid; (maa). ld50:(oral,rat) 1060 mg/kg. methyl methacrylate monomer; (mma) (sara 313) (cercla). ld50:(oral,rat) volatile organic compounds: not determined. supdat:8-100 times tlv from resp & gi irrit, lung dmg, nerv sys efts ing 5:of mma at 5-100 times tlv incl lung dmg, pulm irrit, liver changes, ing 6:& upper resp irrit. long term expos of mma caused inflamm of ing 7:decreased body wt. ingest:liver & kidney efts w/altered func in ing 8:cause decr body wt & incr kidney wt. chlorocarbon matls have ing 9:lab animals & could have similar eft in humans. adrenomimetics ing 10:except for life-sustaining uses in humans acutely/chronically spill proc:properly (rcra haz waste). add inhibitor to pvnt ing 12:sewer systems, waterways & surface waters. use non-sparking ing 13:biodegradable in water. maa readily biodegraded (86% w/in 28 days) ing 14:tonnage matl in wholly cntnd systems. liq w/mod mobility. ing 15:bioaccumulation. low mobility in soil. other prec:use. do not use in gen vicin of arc welding, open flames/hot ing 17:of hcl &/or phosgene (fp n).
ITW DEVCON -- PLASTIC WELDER ADHESIVE, 14385
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CHXYF
MSDS NAME: PLASTIC WELDER ADHESIVE, 14385
Kit Part: Y
Responsible Party
Name: ITW DEVCON
Address: 30 ENDICOTT ST
City: DANVERS MA 01923
Info Phone: 508-777-1100
Emergency Phone Number: 800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: DEVCON CORP
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3753
Phone: 1-508-777-1100
Name: ITW DEVCON
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3712
Phone: 978-777-1100
=======================================================
Ingredients
=======================================================
Cas: 56-23-5
RTECS #: FG4900000
Name: CARBON TETRACHLORIDE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 2350 MG/KG.
% Wt: <1
OSHA PEL: 10 PPM
ACGIH TLV: 5 PPM;10 STEL, S
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
Ozone Depleting Chemical: 1
------------------------------
Cas: 79-41-4
RTECS #: OZ2975000
Name: METHACRYLIC ACID; (MAA). LD50:(ORAL,RAT) 1060 MG/KG.
% Wt: 5-15
OSHA PEL: 20 PPM, S
ACGIH TLV: 20 PPM
------------------------------
Cas: 80-62-6
RTECS #: OZ5075000
Name: METHYL METHACRYLATE MONOMER; (MMA) (SARA 313) (CERCLA). LD50:(ORAL,RAT)
7872 MG/KG.
% Wt: 55-65
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: NOT DETERMINED.
-----------------------------
Name: SUPDAT:8-100 TIMES TLV FROM RESP & GI IRRIT, LUNG DMG, NERV SYS EFTS
& BLOOD IN URINE. CHRONIC:INHAL:RPTD EXPOS
-----------------------------
Name: ING 5:OF MMA AT 5-100 TIMES TLV INCL LUNG DMG, PULM IRRIT, LIVER CHANGES,
EYE IRRIT, NASAL TISS CHANGES, INCOORD
-----------------------------
Name: ING 6:& UPPER RESP IRRIT. LONG TERM EXPOS OF MMA CAUSED INFLAMM OF
NASAL CAVITY, CHANGES IN NASAL SENSORY CELLS &
-----------------------------
Name: ING 7:DECREASED BODY WT. INGEST:LIVER & KIDNEY EFTS W/ALTERED FUNC IN
BOTH ORGANS. SKIN PERMEATION MAY OCCUR. CAN
-----------------------------
Name: ING 8:CAUSE DECR BODY WT & INCR KIDNEY WT. CHLOROCARBON MATLS HAVE
PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN
-----------------------------
Name: ING 9:LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS
(E.G., EPINEPHRINE) MAY BE CONTRAINDICATED
-----------------------------
Name: ING 10:EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY
EXPOS TO CHLOROCARBONS (FP N).
-----------------------------
Name: SPILL PROC:PROPERLY (RCRA HAZ WASTE). ADD INHIBITOR TO PVNT
POLYMERIZATION. PVNT SPILL FROM ENTERING DRAINAGE/
-----------------------------
Name: ING 12:SEWER SYSTEMS, WATERWAYS & SURFACE WATERS. USE NON-SPARKING
TOOLS. ECOLOGICAL INFO:MMA IS PARTIALLY
-----------------------------
Name: ING 13:BIODEGRADABLE IN WATER. MAA READILY BIODEGRADED (86% W/IN 28 DAYS)
UNDER AEROBIC CNDTNS. MMA PRDCES HIGH
-----------------------------
Name: ING 14:TONNAGE MATL IN WHOLLY CNTND SYSTEMS. LIQ W/MOD MOBILITY.
SPARINGLY SOLUBLE IN WATER. HIGH POTENTIAL FOR
-----------------------------
Name: ING 15:BIOACCUMULATION. LOW MOBILITY IN SOIL.
-----------------------------
Name: OTHER PREC:USE. DO NOT USE IN GEN VICIN OF ARC WELDING, OPEN FLAMES/HOT
SURFS. HEAT &/OR UV RADIA MAY CAUSE FORM
-----------------------------
Name: ING 17:OF HCL &/OR PHOSGENE (FP N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENTS.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:SKIN:MAY CAUSE IRRIT & SENSIT. EYES:LIQ &
VAPS CAUSES MOD IRRIT. EYE & SKIN:MAY CAUSE REDNESS, ITCH, BURNING, RASH.
INHAL:HIGH CONC IS IRRIT TO RESP TRACT & MAY CAUSE DIZZ, HDCH, NAUS,
FATG, DRO W & ANESTH EFTS. INGEST:CAUSES IRRIT, BURNING SENSATION OF
MOUTH, THROAT & GI TRACT & ABDOM PAIN. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CARBON TETRACHLORIDE:IARC MONOGRAPHS, SUPP, VOL
7, PG 143, 198:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC(SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ:CHRONIC:PRLNG EXPOS MAY LEAD TO
KIDNEY, LUNG & LIVER DMG, NOT LIKELY TO CAUSE CANCER. NOT BELIEVED TO
REPRESENT CARCIN/MUTAGENIC HAZ. DEVEL TOX OBSERVED IN ANIMAL TESTS W/MMA, BUT
ONLY AT LEV ELS TOX TO MOTHER. TOX INFO:ACUTE:ORAL:TOX OF MMA EXPOS NEAR LD50
INCL BLOOD IN URINE & LIVER CHANGES. INHAL:TOX(SUPDAT)
Medical Cond Aggravated By Exposure: PREEXISTING EYE & SKIN DISORDERS.
First Aid: EYES:FLUSH W/CLEAN WATER FOR AT LST 15 MINS WHILE GENTLY HOLDING
LIDS OPEN. GET IMMED MED ATTN. SKIN:IMMED REMOVE CONTAM CLTHG & EXCESS
CONTAM. FLUSH SKIN W/WATER. WASH THORO W/WARM SOAP & WATER. CONS ULT MD
IF IRRIT DEVELOPS. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN OXYG IF BRTHG IS
DFCLT. GET MED ATTN IF SYMPS PERSIST. INGEST:DO NOT INDUCE VOMIT. GIVE 2
GLASSES OF WATER TO DILUTE IF (SUPP DATA)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AVOID PERSONAL CONT. ELIM IGNIT SOURCES. VENT AREA.
DIKE, CONTAIN & ABSORB W/CLAY, SAND/OTHER SUITABLE NON-COMBUST MATL. FOR
LG SPILLS, PUMP TO STOR/SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB SUCH AS C
LAY, SAND/OTHER SUITABLE MATL & DISP OF
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS (FP N). DO NOT DISPOSE OF IN A LANDFILL. INCINERATION IS THE
PREFERRED METHOD OF DISPOSAL. RCRA CODE:D001, D019.
Handling And Storage Precautions: DO NOT BREATHE VAP/MIST. DO NOT GET IN EYES,
ON SKIN/CLTHG. CLOSE CNTNR AFTER EACH USE. GROUND CNTNR WHEN POURING. KEEP
AWAY FROM HEAT, FLAME/SPKS.
Other Precautions: DO NOT TAKE INTERNALLY. USE NON-SPARKING TOOLS. KEEP IN COOL
PLACE, W/OUT DIRECT EXPOS TO SUNLIGHT. KEEP CNTNR TIGHTLY CLSD &
OTHERWISE I/A/W NFPA REGS. MAINTAIN AIR SPACE IN STOR CNTNRS. OBSERVE LBL
PRECS. NO SMOKING IN AREA OF
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 50.0F,10.0C
Lower Limits: 2.1%
Upper Limits: 12.5%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPRVD PRESS DEMAND SCBA & FULL PROT
EQUIP (FP N). KEEP PERS REMOVED & UPWIND FROM FIRE. COOL TANK W/WATER
SPRAY. FIGHT FIRE FROM DIST AS HEAT(SUPDAT)
Unusual Fire/Explosion Hazard: VAP FORMS EXPLO MIXT W/AIR. SEALED CNTNRS AT
ELEVATED TEMPS MAY RUPTURE DUE TO POLYMERIZATION. VAPS ARE HVR/AIR & MAY
TRAVEL TO IGNIT SOURCES & FLASH (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: A NIOSH APPROVED AIR PURIFYING RESPIRATOR W/ORGANIC
VAPOR CARTRIDGE MAY BE PERMISSIBLE, HOWEVER USE A POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, OR U
NKNOWN EXPOSURE LEVELS.
Ventilation: USE VENTILATION THAT IS ADEQUATE TO KEEP EMPLOYEE EXPOSURE TO
AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER (FP
N). WEAR IMPERVIOUS BUTYL RUBBER CLOTHING TO PREVENT ANY CONTAINMENT.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: PH (5% SOLN/SLURRY IN WATER):3.0-3.5. FIRE
FIGHT PROC:RUPTURES TANKS. EXPLO HAZ:BACK. THERMAL DECOMP PRODS MAY INCL HCL
& PHOSGENE (FP N). EXPLAN OF CARCIN:TO BE CARCIN. ANIMAL:LIVER, KIDNEYS,
LUNG DM G. FIRST AID PROC:PATIENT IS CONSCIOUS.GET MED ATTN. EYE PROT:FULL
LGTH FSHLD (FP N). EFTS OF OVEREXP:OF MMA AT
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 213F,101C
Vapor Pres: 28 @ 68F
Vapor Density: >1
Spec Gravity: 1.03
PH: SUPDAT
Evaporation Rate & Reference: 3 (BUTYL ACETATE=1)
Appearance and Odor: OFF-WHITE PASTE W/VARIED FRAGRANT ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: NO
Stability Condition To Avoid: UNSTABLE W/HEAT.
Materials To Avoid: INCOMPAT W/STRONG OXIDIZING AGENTS & REDUCING AGENTS, ACIDS
& BASES. MATL IS STRONG SOLV & CAN SOFTEN PAINT & RUBBER.
Hazardous Decomposition Products: HCL, PHOSGENE (FP N). CARBON MONOXIDE, CARBON
DIOXIDE & SMOKE.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: EXCESSIVE HEAT, STORAGE IN THE ABSENCE OF
INHIBITOR & INADVERTENT ADDITION OF CATALYST.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PLASTIC WELDER ADHESIVE, 14385
Company: ITW DEVCON
Street: 30 ENDICOTT ST
City: DANVERS MA
Zipcode: 01923-3712
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 10/26/1998
Status Code: C
Label Date: 10/26/1998
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: Slight
Hazard And Precautions: FLAMMABLE. ACUTE:SKIN:MAY CAUSE IRRITATION AND
SENSITIZATION. EYES:LIQUID AND VAPORS CAUSES MODERATE IRRITATION. EYE AND
SKIN:MAY CAUSE REDNESS, ITCHING, BURNING, RASH. INHALATION:HIGH CONCENTRATION
I S IRRITATING TO RESPIRATORY TRACT AND MAY CAUSE DIZZINESS, HEADACHE,
NAUSEA, FATIGUE, DROWSINESS AND ANESTHETIC EFFECTS. INGESTION:CAUSES
IRRITATION, BURNING SENSATION OF MOUTH, THROAT AND GASTROINTES TINAL TRACT
AND ABDOMINAL PAIN. CHRONIC:CANCER HAZARD. CONTAINS CARBON TETRACHLORIDE
WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). PROLONGED EXPOSURE MAY
LEAD TO KIDNEY, LUNG AND LIVER DAMAGE. SKIN SENSITIZATION.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.