| MSDS | : | PURGEABLE MIXTURE AT 100 UG/ML IN METHANOL, | | CAS | : | 71-55-6
79-01-6
75-69-4
75-01-4
75-25-2
74-83-9
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
124-48-1
95-50-1
107-06-2
78-87-5
10061-01-5
100-41-4
75-09-2
127-18-4
108-88-3
67-56-1
71-43-2
75-27-4 | | NAME | : | ethane, 1,1,1-trichloro-; (1,1,1-trichloroethane). ld50 (oral,rat): 5660
ethylene, trichloro-; (trichloroethene). ld50 (oral,rat): 4920 mg/kg.
methane, trichlorofluoro-; (trichlorofluoromethane) (cfc-11) (sara
ethylene, chloro-; (vinyl chloride) (sara iii). ld50 (oral,rat): 500
methane, tribromo-; (bromoform) (sara iii). ld50 (oral,rat): 1147 mg/kg.
methane, bromo-; (bromomethane). ld50 (oral,rat): <100 mg/kg.
carbon tetrachloride (sara iii). ld50 (oral,rat): 1770 mg/kg.
benzene, chloro-; (chlorobenzene) (sara iii). ld50 (oral,rat): 2910
ethane, chloro-; (chloroethane)
chloroform (sara iii). ld50 (oral,rat): 800 mg/kg.
methane, chloro-; (chloromethane) (sara iii)
methane, chlorodibromo-; (dibromochloromethane). ld50 (oral,rat): 848
benzene, o-dichloro-; (1,2-dichlorobenzene) (sara iii). ld50 (oral,rat):
ethane, 1,2-dichloro-; (1,2-dichloroethane) (sara iii). ld50 (oral,rat):
propane, 1,2-dichloro-; (1,2-dichloropropane) (sara iii). ld50
propene, 1,3-dichloro-, (z)-; (cis-1,3-dichloropropene). ld50 (oral,rat):
benzene, ethyl-; (ethylbenzene) (sara iii). ld50 (oral,rat): 3500 mg/kg.
methane, dichloro-; (methylene chloride). ld50 (oral,rat): 2136 mg/kg.
ethylene, tetrachloro-; (tetrachloroethene) (sara iii). ld50 (oral,rat):
toluene (sara iii). ld50 (oral,rat): 5000 mg/kg.
methanol; (methyl alcohol). ld50 (oral,rat): 12,900 mg/kg.
benzene (sara iii). ld50 (oral,rat): 3306 mg/kg.
methane, bromodichloro-; (bromodichloromethane). ld50 (oral,rat): 916
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ULTRA SCIENTIFIC -- PURGEABLE MIXTURE AT 100 UG/ML IN METHANOL,
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Material Safety Data Sheet
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MSDS Num: BRDQG
MSDS NAME: PURGEABLE MIXTURE AT 100 UG/ML IN METHANOL,
Responsible Party
Name: ULTRA SCIENTIFIC
Address: 250 SMITH ST
City: NORTH KINGSTOWN RI 02852
Info Phone: 401-294-9400
Emergency Phone Number: 401-294-9400
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ULTRA SCIENTIFIC
Address: 250 SMITH STREET
City: NORTH KINGSTOWN RI 02852-5000
Phone: 401-294-9400
=======================================================
Ingredients
=======================================================
Cas: 71-55-6
RTECS #: KJ2975000
Name: ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE). LD50 (ORAL,RAT): 5660
MG/KG.
% Wt: 0.013
OSHA PEL: 350 PPM;450 PPM STEL
ACGIH TLV: 350 PPM;450 PPM STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
Ozone Depleting Chemical: 1
------------------------------
Cas: 79-01-6
RTECS #: KX4550000
Name: ETHYLENE, TRICHLORO-; (TRICHLOROETHENE). LD50 (ORAL,RAT): 4920 MG/KG.
% Wt: 0.013
OSHA PEL: 100 PPM/100 STEL
ACGIH TLV: 50 PPM/100,A5STEL;93
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 75-69-4
RTECS #: PB6125000
Name: METHANE, TRICHLOROFLUORO-; (TRICHLOROFLUOROMETHANE) (CFC-11) (SARA
III). LD50 (ORAL,RAT): 1743 MG/KG.
% Wt: 0.013
OSHA PEL: 1000 PPM
ACGIH TLV: C, 1000 PPM; 9293
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
Ozone Depleting Chemical: 1
------------------------------
Cas: 75-01-4
RTECS #: KU9625000
Name: ETHYLENE, CHLORO-; (VINYL CHLORIDE) (SARA III). LD50 (ORAL,RAT): 500
MG/KG.
% Wt: 0.013
OSHA PEL: SEE 1910.1017
ACGIH TLV: 5 PPM, A1; 9293
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 75-25-2
RTECS #: PB5600000
Name: METHANE, TRIBROMO-; (BROMOFORM) (SARA III). LD50 (ORAL,RAT): 1147 MG/KG.
% Wt: 0.013
OSHA PEL: 0.5 PPM, S
ACGIH TLV: 0.5 PPM, S
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 74-83-9
RTECS #: PA4900000
Name: METHANE, BROMO-; (BROMOMETHANE). LD50 (ORAL,RAT): <100 MG/KG.
% Wt: 0.013
OSHA PEL: S,C, 20 PPM
ACGIH TLV: S, 5 PPM; 9293
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 56-23-5
RTECS #: FG4900000
Name: CARBON TETRACHLORIDE (SARA III). LD50 (ORAL,RAT): 1770 MG/KG.
% Wt: 0.013
OSHA PEL: 10 PPM
ACGIH TLV: S,5PPM/10 STEL,A3 93
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
Ozone Depleting Chemical: 1
------------------------------
Cas: 108-90-7
RTECS #: CZ0175000
Name: BENZENE, CHLORO-; (CHLOROBENZENE) (SARA III). LD50 (ORAL,RAT): 2910
MG/KG.
% Wt: 0.013
OSHA PEL: 75 PPM
ACGIH TLV: 10 PPM
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 75-00-3
RTECS #: KH7525000
Name: ETHANE, CHLORO-; (CHLOROETHANE)
% Wt: 0.013
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 67-66-3
RTECS #: FS9100000
Name: CHLOROFORM (SARA III). LD50 (ORAL,RAT): 800 MG/KG.
% Wt: 0.013
OSHA PEL: (C) 50 PPM
ACGIH TLV: 10 PPM; A2; 9293
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 74-87-3
RTECS #: PA6300000
Name: METHANE, CHLORO-; (CHLOROMETHANE) (SARA III)
% Wt: 0.013
OSHA PEL: 100 PPM
ACGIH TLV: S,50 PPM/100 STEL 94
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 124-48-1
RTECS #: PA6360000
Name: METHANE, CHLORODIBROMO-; (DIBROMOCHLOROMETHANE). LD50 (ORAL,RAT): 848
MG/KG.
% Wt: 0.013
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 95-50-1
RTECS #: CZ4500000
Name: BENZENE, O-DICHLORO-; (1,2-DICHLOROBENZENE) (SARA III). LD50 (ORAL,RAT):
500 MG/KG.
% Wt: 0.013
OSHA PEL: C 50 PPM
ACGIH TLV: S, 25PPM/50 STEL9394
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 107-06-2
RTECS #: KI0525000
Name: ETHANE, 1,2-DICHLORO-; (1,2-DICHLOROETHANE) (SARA III). LD50 (ORAL,RAT):
680 MG/KG.
% Wt: 0.013
OSHA PEL: 50 PPM/C,100PPM
ACGIH TLV: 10 PPM; 9293
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 78-87-5
RTECS #: TX9625000
Name: PROPANE, 1,2-DICHLORO-; (1,2-DICHLOROPROPANE) (SARA III). LD50
(ORAL,RAT): 2796 MG/KG.
% Wt: 0.013
OSHA PEL: 75 PPM;110 PPM STEL
ACGIH TLV: 75 PPM;110 PPM STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 10061-01-5
RTECS #: UC8325000
Name: PROPENE, 1,3-DICHLORO-, (Z)-; (CIS-1,3-DICHLOROPROPENE). LD50 (ORAL,RAT):
250 MG/KG.
% Wt: 0.013
------------------------------
Cas: 100-41-4
RTECS #: DA0700000
Name: BENZENE, ETHYL-; (ETHYLBENZENE) (SARA III). LD50 (ORAL,RAT): 3500 MG/KG.
% Wt: 0.013
OSHA PEL: 100 PPM;125 PPM STEL
ACGIH TLV: 100 PPM;125 PPM STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 75-09-2
RTECS #: PA8050000
Name: METHANE, DICHLORO-; (METHYLENE CHLORIDE). LD50 (ORAL,RAT): 2136 MG/KG.
% Wt: 0.013
OSHA PEL: 500 PPM;1000 PPM, C
ACGIH TLV: 50 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 127-18-4
RTECS #: KX3850000
Name: ETHYLENE, TETRACHLORO-; (TETRACHLOROETHENE) (SARA III). LD50 (ORAL,RAT):
8850 MG/KG.
% Wt: 0.013
OSHA PEL: 100 PPM
ACGIH TLV: 25PPM/100,A3 STEL;94
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA III). LD50 (ORAL,RAT): 5000 MG/KG.
% Wt: 0.013
OSHA PEL: 200 PPM/150 STEL
ACGIH TLV: 50 PPM; 9293
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 67-56-1
RTECS #: PC1400000
Name: METHANOL; (METHYL ALCOHOL). LD50 (ORAL,RAT): 12,900 MG/KG.
% Wt: 99.90
OSHA PEL: S,200PPM/250STEL
ACGIH TLV: S,200PPM/250STEL; 93
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE (SARA III). LD50 (ORAL,RAT): 3306 MG/KG.
% Wt: 0.013
OSHA PEL: 10 PPM,25, C
ACGIH TLV: 10 PPM
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 75-27-4
RTECS #: PA5310000
Name: METHANE, BROMODICHLORO-; (BROMODICHLOROMETHANE). LD50 (ORAL,RAT): 916
MG/KG.
% Wt: 0.013
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TOX; IRRIT. ALL CHEMS SHOULD BE CONSIDERED HAZ-DIRECT PHYS
CONT SHOULD BE AVOIDED. CONTAINS CARCIN(S)/CANCER SUSPECT AGENT(S).
CHLOROFLUOROCARBON MATLS HAVE PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE I N
LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G.,
EPINEPHRINE) MAY BE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: CONTRAINDICATED EXCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS (FP
N). NOTE: TOLUENE, 108-88-3, APPEARS ON NAVY LISTING OF OCCUP REPROD HAZS.
SEEK CONSU LTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST
INFO AND SAFE HNDLG AND EXPOS RECOM (FP N).
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR.
GIVE OXYGEN, IF NECESSARY. CONTACT PHYSICIAN. INGESTION: C ALL MD IMMEDIATELY
(FP N).
=======================================================
Handling and Disposal
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Spill Release Procedures: DUE TO SMALL QUANTITY INVOLVED, SPILLS OR LEAKS
SHOULD NOT POSE A SIGNIFICANT PROBLEM. A LEAKING BOTTLE MAY BE PLACED IN A
PLASTIC BAG AND NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE AB
SORBED ON VERMICULITE OR SAND.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS
CONCERNING DISPOSAL.
Handling And Storage Precautions: THIS MATL SHOULD ONLY BE USED BY THOSE
PERSONS TRAINED IN THE CARE HANDLING OF HAZARDOUS CHEMICALS. KEEP TIGHTLY
CLOSED, AND STORE IN COOL, DRY PLACE.
Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF
ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE
FORMATION OF CHLORIDES, FLUORIDES OR PHOSGENE (FP N).
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER, OR WATER SPRAY.
Fire Fighting Procedures: WEAR NISOH/MSHA APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE
CHLORIDES, FLUORIDES AND PHOSGENE (FP N).
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation: GENERAL VENTILATION SUFFICIENT TO KEEP AIRBORNE CONCENTRATION
BELOW CURRENT EXPOSURE LIMITS (FP N).
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: CHEM WORK GOG/FULL LGTH FACESHLD (FP N).
Other Protective Equipment: WEAR LABORATORY COAT AND/OR RUBBER APRON TO PREVENT
CONTACT WITH EYES, SKIN, AND CLOTHING.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: F5
Appearance and Odor: COLORLESS LIQUID
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: CHLORIDES, FLUORIDES, AND PHOSGENE (FP N).
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: PURGEABLE MIXTURE AT 100 UG/ML IN METHANOL,
Company: ULTRA SCIENTIFIC
Street: 250 SMITH STREET
City: NORTH KINGSTOWN RI
Zipcode: 02852-5000
Health Emergency Phone: 401-294-9400
Label Required IND: Y
Date Of Label Review: 01/14/1993
Status Code: C
Label Date: 01/14/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE! THIS MATERIAL SHOULD ONLY BE USED BY THOSE
PERSONS TRAINED IN THE CARE HANDLING OF HAZARDOUS CHEMICALS. KEEP TIGHTLY
CLOSED, AND STORE IN COOL, DRY PLACE. ACUTE: TOXIC; IRRITANT. ALL CHEM ICALS
SHOULD BE CONSIDERED HAZARDOUS-DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED.
CHRONIC: CONTAINS CARCINOGEN(S)/CANCER SUSPECT AGENT(S) (MFR). NOTE: TOLUENE
APPEARS ON NAVY LISTING OF OCCUPATIONAL CH EMICAL REPRODUCTIVE HAZARDS (FP
N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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