SHERWIN-WILLIAMS CO -- ZINC-CLAD III ZINC RICH COATING BINDER PART
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Material Safety Data Sheet
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MSDS Num: BRDSN
MSDS NAME: ZINC-CLAD III ZINC RICH COATING BINDER PART
Responsible Party
Name: SHERWIN-WILLIAMS CO
Address: 101 PROSPECT AVE NW
City: CLEVELAND OH 44115
Info Phone: 216-566-2902
Emergency Phone Number: 216-566-2917
Proprietary Ind: Y
Published: Y
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Contractor Summary
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Name: SHERWIN-WILLIAMS CO THE
Address: 101 PROSPECT AVE NW
City: CLEVELAND OH 44115-1042
Phone: 800-251-2486/216-566-2242
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV
SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. CHRONIC:
LONG TERM EXPOS TO HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN SAND
/ABRAD DRY FILM, MAY CAUSE LUNG DAM (SILICOSIS) & POSS CANCER. PRLNGD
OVEREXP TO SOLV INGRED MAY CAUSE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE (QUARTZ): ANTIC TO BE A
CARCIN (NTP 6TH ANN RPT, 1991), IARC GP 2A (IARC MNGRPH VOL7,P349,1987).
Signs And Symptions Of Overexposure: HLTH HAZ: ADVERSE EFTS TO LIVER, URINARY,
BLOOD FORM, & REPROD SYS. RPTS HAVE ASSOC RPTD & PRLNGD OVEREXP TO
SOLV W/PERM BRAIN & NERV SYS DAM. SIGNS & SYMPS OF EXPOS: HDCH/DIZZ,
NAUS, & LOSS OF COORD ARE INDICATIONS OF EXCESS EXPOS TO VAPS/SPRAY
MISTS. RED & ITCH/BURN SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOSURE.
Medical Cond Aggravated By Exposure: MAY CAUSE ALLERGIC SKIN REACTION IN
SUSCEPTIBLE PERSONS OR SKIN SENSITIZATION.
First Aid: INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET.
SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED
CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH WITH L ARGE AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL
ATTENTION.
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Handling and Disposal
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Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE
WITH INERT ABSORBENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: WASTE FROM THESE PROD MAY BE HAZ AS DEFINED UNDER
RESOURCE CONSERVATION & RECOVERY ACT(RCRA) 40CFR261. WASTE MUST BE TESTED
FOR IGNITABILITY & EXTRACTABILITY TO DETERM APPLIC EPA HAZ WASTE NUMBERS.
IN CIN IN APPRVD FACILITY. DO NOT INCINERATE
Handling And Storage Precautions: KEEP AWAY FROM HEAT/SPARKS, & OPEN FLAME.
DURING USE & UNTIL ALL VAPS ARE GONE; KEEP AREA VENTD-DO NOT SMOKE.
CONSULT NFPA CODE.
Other Precautions: EXTINGUISH ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN OFF
STOVES, ELECTRIC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGNIT.
USE APPRVD BOND & GROUND. KEEP CONTR CLSD WHEN NOT IN USE. TRANSFER ONLY
TO A PPRVD CONTRS W/COMPLETE & APPROP
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Fire and Explosion Hazard Information
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Flash Point Text: 80F,26.7C
Lower Limits: 0.7%
Upper Limits: 6%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP N).
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY
BE USED TO COOL CLSD (SUPP DATA)
Unusual Fire/Explosion Hazard: KEEP CONTRS TIGHTLY CLSD.ISOLATE FROM HEAT, ELEC
EQUIP, SPARKS, & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN EXPOS TO
EXTREME HEAT. APPLICATION TO HOT (SUPP DATA)
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Control Measures
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Respiratory Protection: IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIM
BY VENT, WEAR A NIOSH/MSHA APPRVD PROPERLY FITTED ORG VAP/PARTICULATE RESP
FOR PROT AGAINST MATLS. WHEN SAND, WIREBRUSHING, ABRAD, BURN/WELD DRI ED
FILM, WEAR A NIOSH/MSHA
Ventilation: LOC EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO MATLS IS
MAINTAINED BELOW APPLIC EXPOS LIM. REFER TO OSHA
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: USE BARRIER CREAM ON EXPOSED SKIN.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRE FIGHT PROC: CONTRS TO PVNT PRESS BUILD-UP
& POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURF
REQUIRES SPECIAL PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PROD MAY CAUSE
HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. MATL TO AVOID:
DANGEROUSLY INCR PRESS IN CLSD CONTR.
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Physical/Chemical Properties
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B.P. Text: >172F,>78C
Vapor Pres: SEE INGRED
Vapor Density: HVR/AIR
Spec Gravity: 1.33 (FP N)
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume: 0-77
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: CONTAM OF ZINC-CNTNG PORTIONS/MIXT W/WATER, ACIDS/ALKALIS
CAN CAUSE EVOLUTION OF HYDROGEN, WHICH MAY RSLT IN (SUPP DATA)
Hazardous Decomposition Products: BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF METAL.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: ZINC-CLAD III ZINC RICH COATING BINDER PART
Company: SHERWIN-WILLIAMS CO THE
Street: 101 PROSPECT AVE NW
City: CLEVELAND OH
Zipcode: 44115-1042
Health Emergency Phone: 216-566-2917
Label Required IND: Y
Date Of Label Review: 01/12/1993
Status Code: C
Label Date: 01/12/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE! KEEP AWAY FROM HEAT/SPARKS & OPEN FLAME.
ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYSTEM DEPRESS.
EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS & POSSIBLY DEATH.
CHRONI C: CANCER HAZ. SILICA, CRYSTALLINE-QUARTZ IS LISTED AS A CARCIN (FP
N). LONG TERM EXPOSURE TO HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY
WHEN SAND/ABRADING DRY FILM, MAY CAUSE LUNG DAMAGE (SILIC OSIS) &
POSSIBLY CANCER. PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENT MAY
CAUSEADVERSE EFFECTS TO LIVER, URINARY, BLOOD FORM, & REPRODUCTIVE
SYSTEM. REPORTS HAVE ASSOCIATED REPEATED & PROLONGED OVREXP TO SOLVENT
W/PERM BRAIN & NERV SYS DAM.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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