SHERWIN-WILLIAMS CO -- ZINC-CLAD IV ZINC RICH COATING PART U (B69A
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Material Safety Data Sheet
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MSDS Num: BRDSR
MSDS NAME: ZINC-CLAD IV ZINC RICH COATING PART U (B69A
Responsible Party
Name: SHERWIN-WILLIAMS CO
Address: 101 PROSPECT AVE NW
City: CLEVELAND OH 44115
Info Phone: 216-566-2902
Emergency Phone Number: 216-566-2917
Proprietary Ind: Y
Published: Y
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Contractor Summary
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Name: SHERWIN-WILLIAMS CO THE
Address: 101 PROSPECT AVE NW
City: CLEVELAND OH 44115-1042
Phone: 800-251-2486/216-566-2242
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV
SYS DEPRESS. EXTREME OVEREXP MAY RESULT IN UNCON & POSSIBLE DEATH.
CERTAIN ZINC CLAD PROD CONTAIN LEAD. ACUTE OCCUP EXPOS TO LEAD IS UNCOMMON,
BUT RSLTS IN EFTS & SYMPS SIMILAR TO CHRONIC OVEREXP. OVEREXP TO CADMIUM
MAY RSLT IN KIDNEY DAM. CHRONIC: (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CRYSTALLINE SILICA-QUARTZ:ANTIC TO BE A
CARC,NTP 6TH ANNUAL RPT ON CARC, 1991; GROUP 2A, IARC VOL 7, P.341,1987
Signs And Symptions Of Overexposure: HLTH HAZ:OVEREXP TO LEAD MAY RSLT IN DAM
TO BLOOD-FORMING, NERV, URIN & REPROD SYS (INCL EMBRYOTOX EFTS). SYMPS
INCL ABDOM DISCOMFORT/PAIN, CONSTIP, LOSS OF APPETITE, METALLIC TASTE, NAUS,
INSOMNIA, N ERV IRRITABILITY, WEAK, MUSCLE & JOINT PAIN, HDCH & DIZZ.
LONG TERM EXPOS TO HIGH LEVELS OF SILICA DUST,
Medical Cond Aggravated By Exposure: MAY CAUSE ALLERGIC SKIN REACTION IN
SUSCEPTIBLE PERSONS OR SKIN SENSITIZATION.
First Aid: INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET.
SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED
CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH WITH L ARGE AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL
ATTENTION.
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Handling and Disposal
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Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE
WITH INERT ABSORBENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: WASTE FROM THESE PROD MAY BE HAZ AS DEFINED RCRA
40CFR261. WASTE MUST BE TESTED FOR IGNIT & EXTRACT TO DETERM APPLIC EPA
HAZ WASTE #'S. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CONTR. DISPOSE OF
I/ A/W FED, ST & LOC REGS REGARDING POLLUTION.
Handling And Storage Precautions: KEEP AWAY FROM HEAT/SPARKS, & OPEN FLAME.
DURING USE & UNTIL ALL VAPS ARE GONE; KEEP AREA VENTD-DO NOT SMOKE.
CONSULT NFPA CODE.
Other Precautions: EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS. TURN OFF
STOVES, ELEC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGNIT. USE
APPRVD BOND & GROUND. KEEP CONTR CLSD WHEN NOT IN USE. TRANSFER ONLY TO
APPRVD C ONTRS W/COMPLETE & APPROP LBLG
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Fire and Explosion Hazard Information
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Flash Point Text: 80F,26.7C
Lower Limits: 0.7%
Upper Limits: 6%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP
N).WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTRS(SUPP DATA)
Unusual Fire/Explosion Hazard: KEEP CONTRS TIGHTLY CLSD.ISOLATE FROM HEAT, ELEC
EQUIP, SPARKS, & OPEN FLAME.CLSD CONTRS MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT.APPLICATN TO HOT SURF(SUPP DATA)
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Control Measures
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Respiratory Protection: IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIM
BY VENT, WEAR A NIOSH/MSHA APPRVD PROPERLY FITTED ORG VAP/PARTICULATE RESP
FOR PROT AGAINST MATLS. WHEN SAND, WIREBRUSHING, ABRAD, BURN/WELD DRI ED
FILM, WEAR A NIOSH/MSHA
Ventilation: LOC EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO MATLS IS
MAINTAINED BELOW APPLIC EXPOS LIM. REFER TO OSHA
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: USE BARRIER CREAM ON EXPOSED SKIN.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NOTE: L VERSION USERS REFER TO LR VERSION FOR
ADDITIONAL INFORMATION (FP N). FIRE FIGHT PROC: TO PREVENT PRESS BUILD-UP
& POSSIBLE AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:REQS
SPECIAL PREC.DURING EMER CNDTNS OVEREXP TO DECOMP PROD MAY CAUSE HLTH HAZ.
SYMPTOMS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN.
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Physical/Chemical Properties
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B.P. Text: >172F,>78C
Vapor Density: HVR/AIR
Spec Gravity: 3.42 (FP N)
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume: 0-77
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: CONTAM OF ZINC-CNTNG PORTIONS/MIXT W/H*2O, ACIDS/ALKALIS
CAN CAUSE EVOLUTION OF HYDROGEN, WHICH MAY(SEE HAZ DECOMP PROD)
Hazardous Decomposition Products: BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF METAL. MATL TO AVOID: RSLT IN DANGEROUSLY INCR PRESS IN CLOSED
CNTR.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: ZINC-CLAD IV ZINC RICH COATING PART U (B69A
Company: SHERWIN-WILLIAMS CO THE
Street: 101 PROSPECT AVE NW
City: CLEVELAND OH
Zipcode: 44115-1042
Health Emergency Phone: 216-566-2917
Label Required IND: Y
Date Of Label Review: 01/12/1993
Status Code: C
Label Date: 01/12/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMM! AVOID HEAT/SPARKS/FLAME. ACUTE: IRRIT OF EYES,
SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTR OVEREXP MAY RSLT IN
UNCON & POSS DEATH.CHRONIC:CANCER HAZ. SILICA, CRYSTALLINE-QUARTZ IS
LISTED AS CARCIN. (FP N).OVEREXP TO LEAD MAY RSLT IN DAM TO BLOOD-FORMING,
NERV, URIN & REPROD SYS. LONG TERM EXPOS TO SILICA DUST MAY CAUSE LUNG
DAM (SILICOSIS).PRLNGD OVEREXP TO SOLV CAUSE ADVERSE EFTS TO LIVER, URINARY,
BLOOD FORM, & REPROD SYS. RPTS HAVE ASSOC RPTD & PRLNGD OVEREXPTO
SOLV W/PERM BRAIN & NERV SYS DAM. NOTE: LEAD APPEARS ON NAVY LIST OF
OCCUP REPROD HAZ. DANGER! CNTNS CADMIUM. CANCER H AZ/ AVOID CREATING DUST.
CAN CAUSE KDNY&LUNG DMG.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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