silicon dioxide, amorphous; (amorphous silica) supp data: that temp, it may become unsuitable. vent: must be conducted in an area that is ventilated out of work area. epichlorohydrin bis-phenol a; (bisphenol a-epichlorohydrin copolymer) aniline, 4,4'-methylenedi-; (4,4'-methylene dianiline) titanium oxide; (titanium dioxide) iron (iii) oxide 4-cyclohexene-1,2-dicarboxylic anhydride; (tetrahydrophthalic anhydride)
3M GENERAL OFFICES -- SCOTCHKOTE BRAND 214 SPRAY GRADE FUSION (SU
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Material Safety Data Sheet
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MSDS Num: BRDWS
MSDS NAME: SCOTCHKOTE BRAND 214 SPRAY GRADE FUSION (SU
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 612-733-1110
Emergency Phone Number: 612-733-1110
Published: Y
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Contractor Summary
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Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
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Ingredients
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Cas: 7631-86-9
Name: SILICON DIOXIDE, AMORPHOUS; (AMORPHOUS SILICA)
% Wt: 0.1-0.6
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Name: SUPP DATA: THAT TEMP, IT MAY BECOME UNSUITABLE.
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Name: VENT: MUST BE CONDUCTED IN AN AREA THAT IS VENTILATED OUT OF WORK AREA.
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Cas: 25068-38-6
RTECS #: SL6475000
Name: EPICHLOROHYDRIN BIS-PHENOL A; (BISPHENOL A-EPICHLOROHYDRIN COPOLYMER)
% Wt: 85-88
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Cas: 101-77-9
RTECS #: BY5425000
Name: ANILINE, 4,4'-METHYLENEDI-; (4,4'-METHYLENE DIANILINE)
% Wt: 8-10
ACGIH TLV: 0.1 PPM, S
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 1-4
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST; 9293
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Cas: 1309-37-1
RTECS #: NO7400000
Name: IRON (III) OXIDE
% Wt: 1-4
OSHA PEL: 10 MG/M3 (FE)
ACGIH TLV: 5 MG/M3(FE),B2; 9293
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Cas: 85-43-8
RTECS #: GW5775000
Name: 4-CYCLOHEXENE-1,2-DICARBOXYLIC ANHYDRIDE; (TETRAHYDROPHTHALIC ANHYDRIDE)
% Wt: 0.1-1
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: EYE:PROD IS IRRIT TO EYES IF IT COMES IN DIRECT CNTCT.
SKIN:PROD MAY IRRIT SKIN IF IT REMAINS IN DIRECT CNTCT FOR A PRLNGD PERIOD.
IT MAY CAUSE AN ALLERGIC SKIN SENSIT IN SUSCEPTIBLE INDIVIDUALS WHO A RE
REPEATEDLY IN DIRECT CNTCT W/PROD. INHAL: BRGHG OF DUST & VAPS MAY BE
IRRIT TO NOSE, THROAT & (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: METHYLENE DIANILINE: IARC GP 2B (IARC MNGRPH
VOL7, P56, 1987), ANTICIP TO BE A CARCIN (NTP 6TH ANN RPT, 1991).
Signs And Symptions Of Overexposure: HLTH HAZ: RESPIRATORY SYSTEM. TITANIUM
DIOXIDE HAS BEEN SHOWN TO CAUSE BENIGN & CANCEROUS LUNG TUMORS IN RATS
EXPOSED TO 250 MG/M3 OF AIR, SIX HOURS A DAY, FIVE DAYS A WEEK FOR TWO YEARS.
INGEST:METHY LENE DIANILINE HAS BEEN SHOWN TO CAUSE CANCER IN LABORATORY
ANIMALS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15
MIN. CALL A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. INHAL: PROVIDE FRESH
AIR. IF COUGHING, WHEEZING OR SHORTNESS OF BREATH OCCUR, CA LL A PHYSICIAN.
INGEST: GIVE ONE/TWO GLASSES OF WATER. CALL A PHYSICIAN.
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Handling and Disposal
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Spill Release Procedures: EXTING ALL IGNIT SOURCES. OBSERVE PRECAUTIONS
DESCRIBED IN OTHER SECTIONS. WETTING THE SPILLED POWDER CAN HELP REDUCE THE
DUSTING PROBLEM. COLLECT THE SPILL BY VACUUM OR OTHER METHOD USING CARE TO
AVO ID DUSTING. PLACE THE COLLECTED MATL (SUPP DATA)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE OR BURY IN A SANITARY LANDFILL IN COMPLIANCE
WITH LOCAL, STATE AND FEDERAL REGULATIONS.
Handling And Storage Precautions: AS W/ANY FINELY DIVIDED ORGANIC MATL, DUST
CLOUDS OF POWDER CAN BE IGNITED BY OPEN FLAME OR WEAK ELEC SPARKS.
Other Precautions: RESIN DUST COLLECTION EQUIP SHLD BE PROVIDED W/ADEQ
EXPLOSION RELEASE. POSSIBLE SOURCES OF IGNITION SHLD BE ELIMINATED. TO AVOID
BUILDUP OF STATIC ELECTRICITY, EQUIP SHLD BE GROUNDED. USE ONLY IN WELL -VENT
AREAS W/SUFFICIENT AIR (SUPP DATA)
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Fire and Explosion Hazard Information
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Extinguishing Media: CARBON DIOXIDE, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED SCBA AND
FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: GUARD AGAINST DUST EXPLOSION.
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Control Measures
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Respiratory Protection: WHEN DUST AND/OR VAPOR IS PRESENT, THE USE OF
RESPIRATORY PROTECTION IS RECOMMENDED. WEAR A NIOSH/MSHA APPROVED RESPIRATOR
W/ORGANIC VAPOR CARTRIDGES AND A TOXIC DUST PRE-FILTER.
Ventilation: LOC EXHST IS RECOMMENDED. COOL DOWN AREAS SHOULD BE VENT TO PVNT
VAPS FROM ENTERING WORK AREA. HEAT CURING
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N)
Other Protective Equipment: PROTECTIVE CLOTHING.
Work Hygienic Practices: LAUNDER CONTAMINATED CLOTHING BEFORE WEARING AGAIN.
Supplemental Safety and Health: MFR TRADE NAME/PART NO:BONDED EPOXY COATING.
SPILL PROC:INTO A CLOSED CNTNR. CAUTION:A VACUUM CLEANER MAY BE A SOURCE OF
IGNIT. OTHER PREC: MOVEMENT TO MAINTAIN AIRBORNE CONC OF MATL AT RECOGNIZED
HLT H & SFTY LEVELS. AVOID BRTHG DUST & VAPS. AVOID SKIN & EYE
CNTCT. DO NOT STORE PROD >80F(27C); IF STORED ABOVE
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Physical/Chemical Properties
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Spec Gravity: 1.22
Solubility in Water: NIL
Appearance and Odor: BROWN POWDER.
Percent Volatiles by Volume: 0
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE.
Hazardous Decomposition Products: MAY INCLUDE CARBON MONOXIDE, CARBON DIOXIDE
AND OXIDES OF NITROGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: SCOTCHKOTE BRAND 214 SPRAY GRADE FUSION (SU
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 612-733-1110
Label Required IND: Y
Date Of Label Review: 01/07/1993
Status Code: C
Label Date: 01/07/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: DUST CLOUDS OF POWDER CAN BE IGNITED BY OPEN FLAME OR
WEAK ELECTRICAL SPARKS. ACUTE: EYE/SKIN CONTACT CAUSES IRRITATION. INHALATION
MAY BE IRRITATING TO THE NOSE, THROAT, AND RESPIRATORY SYSTEM. CHRON IC:
CANCER HAZARD. METHYLENE DIANILINE IS LISTED AS A CARCINOGEN (FP N).
SUSCEPTIBLE INDIVIDUALS WHO ARE REPEATEDLY IN DIRECT CONTACT WITH THE PRODUCT
MAY DEVELOP AN ALLERGIC SKIN SENSITIZATION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.