US PAINT CORPORATION -- HIGH SOLIDS MAX COR PRIMER, R4001
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Material Safety Data Sheet
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MSDS Num: CJNZY
MSDS NAME: HIGH SOLIDS MAX COR PRIMER, R4001
Responsible Party
Name: US PAINT CORPORATION
Address: 831 S 21ST ST
City: ST LOUIS MO 63103-3092
Info Phone: 314-621-0525
Emergency Phone Number: 703-527-3887
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: US PAINT CORPORATION
Address: 831 SOUTH 21ST STREET
City: ST LOUIS MO 63103-3092
Phone: 314-621-0525
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Item Description Information
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Ingredients
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE; (DIMETHYL BENZENE) VP: 5.1 MM HG @ 20C; LD50: 4.3 G/KG; LC50:
5000 PPM/4 HR
Percent by Wt: 3.
Other REC Limits: N/K (FP N)
OSHA PEL: 100 PPM
OSHA STEL: 150 PPM
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 651 MG/M3;150 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 64742-95-6
RTECS #: WF3400000
Name: LIGHT AROMATIC SOLVENT NAPHTHA (PETROLEUM); (AROMATIC PETROLEUM
DISTILLATES) VP: 3.0 MM HG @ 20C; LD50: 4.7 G/KG; LC50: >3670 PPM/8 HR
Percent by Wt: 2.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: 100 PPM
ACGIH STEL: N/K (FP N)
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Cas: 123-42-2
RTECS #: SA9100000
Percent by Wt: 3.
Other REC Limits: N/K (FP N)
OSHA PEL: 240 MG/M3;50 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 238 MG/M3;50 PPM
ACGIH STEL: N/K (FP N)
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Cas: 78-93-3
RTECS #: EL6475000
Name: METHYL ETHYL KETONE; (2-BUTANONE) VP: 70 MM HG @ 20C; LD50: 2.7 G/KG;
LC50: 23.5 G/M3/8 HR
Percent by Wt: 4.
Other REC Limits: N/K (FP N)
OSHA PEL: 590 MG/M3;200 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 590 MG/M3;200 PPM
ACGIH STEL: 885 MG/M3;300 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 108-83-8
RTECS #: MJ5775000
Percent by Wt: 8.
Other REC Limits: N/K (FP N)
OSHA PEL: 290 MG/M3;50 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 145 MG/M3;25 PPM
ACGIH STEL: N/K (FP N)
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Percent by Wt: 27.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Cas: 14807-96-6
RTECS #: WW2710000
Percent by Wt: 8.
Other REC Limits: N/K (FP N)
OSHA PEL: see Table Z-3
OSHA STEL: N/K (FP N)
ACGIH TLV: 2 MG/M3
ACGIH STEL: N/K (FP N)
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Cas: 7789-06-2
RTECS #: GB3240000
Percent by Wt: 26.
Other REC Limits: N/K (FP N)
OSHA PEL: see Table Z-2
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.0005 MG/M3
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: EYES: MAY CAUSE MOD IRRIT, REDNESS, TEARING &
BLURRED VISION. CAN CAUSE SEV INJURY - DMG REVERSIBLE. MAY CAUSE BURNS. SKIN:
PRLNG/RPTD CONT CAN CAUSE MOD IRRIT, DEFAT & DERM. PRLNG CONT MAY RSL T
IN CHEM BURNS & PERM DMG. CAN BE ABSORBED THRU SKIN, & MAY CONTRIBUTE
TO SYMPS OF TOXICITY FROM OTHER RTES OF EXPOS. SENSITIZER - CAN CAUSE
ALLERGIC SKIN RXN WHICH MAY BE SEV IN CERTAIN INDIVIDUALS. INHAL: MAY CAUSE
IRRIT OF MUC MEMBS, COUGH, DISCOMFORT, RAPID/DFCLT BRTHG/SHORTNESS OF BREATH.
SENSITIZER - MAY CAUSE ALLERGIC RESP RXN. CAN CAUSE CNS EFTS INCL FATG, WEAK,
HDCH, DIZZ, NAUS, VOMIT, U NCON, COMA, (EFTS OF OVERREXP)
Explanation Of Carcinogenicity: STRONTIUM CHROMATE: IARC MONOGRAPHS,
SUPPLEMENT, VOLUME 49, PAGE 49, 1998: GROUP 1. NTP 8TH ANNUAL REPORT ON
CARCINOGENS, 1998: KNOWN TO BE HUMAN CARCINOGEN.
Signs And Symptions Of Overexposure: HLTH HAZ: RESP FAILURE & DEATH. PRLNG
EXPOS CAN CAUSE HEARING IMPAIRMENT. INGEST: MOD TOX BY INGEST. CAN CAUSE
IRRIT OF DIGESTIVE TRACT, NAUS, VOMIT & DIARR. MAY CAUSE SIGNS OF NERV
SYS DEPRESS INCL D ROW, DIZZ, LOSS OF COORD, FATG, HDCH & NAUS. ASPIR OF
MATL INTO LUNGS CAN CAUSE CHEM PNEUMIT WHICH CAN BE FATAL. CHRONIC: PRLNG
& RPTD BRTHG OF VAPS, SPRAY MIST &/OR SANDING DUST OVER A PERIOD OF
YRS MAY CAUSE DISEASES OF LUNGS. CANCER. CHROMIUM & CERTAIN CHROMIUM
CMPDS HAVE BEEN REPORTED TO CAUSE DMG TO LUNGS. FROM RSLTS OF TESTING W/LAB
ANIMALS, CHROMIUM & CERTAIN CHROMIUM CMPDS ARE SUSPECTED OF CAUSING
CANCER. (TOXICOLOGICAL INFO)
Medical Cond Aggravated By Exposure: PERSONS WITH PREEXISTING SKIN DISORDERS
MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS MATERIAL. MAY AGGRAVATE AN
EXISTING DERMATITIS OR OTHER ALLERGIC REACTIONS.
First Aid: EYES: FLUSH W/WATER FOR AT LEAST 15 MINS WHILE HOLDING EYELIDS
APART. SEEK MED ATTN. SKIN: REMOVE CONTAM CLTHG & FLUSH CONTAM SKIN W/LGE
AMT OF WATER. IF SKIN IS DAMAGED/IF SYMPS PERSIST SEEK MED ATTN . LAUNDER
CLTHG BEFORE REUSE. INHAL: IF SYMPS DEVELOP, IMMED MOVE INTO FRESH AIR. SEEK
IMMED MED ATTN. KEEP PERS WARM & QUIET. IF NOT BRTHG, BEGIN ARTF RESP. IF
BRTHG IS DFCLT, ADMIN OXYGEN. INGEST: D O NOT INDUCE VOMIT UNLESS DIRECTED BY
MED PERS. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUMIT WHICH MAY BE FATAL.
IF DROWSY/UNCON, PLACE ON SIDE W/HEAD DOWN. SEEK MED ATTN. IF POSS, DO NOT
LEAVE IND IVIDUAL UNATTENDED.
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Handling and Disposal
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Spill Release Procedures: SML SPILL: ABSORB LIQ ON INERT MATL SUCH AS PAPER,
VERMICULITE, FLOOR ABSORB, & TRANSFER TO HOOD. LGE SPILL: ELIM ALL IGNIT
SOURCES (FLARES, FLAMES, INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING PRO
T EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN
COMPLETED. STOP SPILL AT SOURCE, CONTAIN AREA OF SPILL TO PVNT SPREADING,
PUMP LIQ TO SALVAGE TANK. (SUP DAT)
Waste Disposal Methods: DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND
UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO
NOT INCINERATE CLOSED CONTAINERS.
Handling And Storage Precautions: USE ONLY W/ADEQ VENT. DO NOT BREATHE VAPS,
SPRAY MISTS/SANDING DUSTS. SENSITIVITY TO STATIC DISCHARGE: GROUNDING/BONDING
REQD. KEEP CONTR TIGHT & UPRIGHT TO PVNT LEAKAGE. KEEP CONTR CLSD WHEN
NOT IN U SE. DO NOT STORE > 49C/120F. DO NOT TRANSFER TO BOTTLES/OTHER
UNLABELED CONTRS. PROT FROM FREEZING.
Other Precautions: CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED
BECAUSE THEY MAY RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, &/OR SOLID).
WHEN EMPTY, MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE/WELD ON/N EAR
THIS CONTAINER. ALL HAZARD PRECAUTIONS GIVEN IN THIS MSDS MUST BE OBSERVED
FOR EMPTY CONTAINERS.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =-6.1C, 21.F
Autoignition Temp: =396.1C, 745.F
Extinguishing Media: SML FIRES: CARBON DIOXIDE/DRY CHEM. LGE FIRES:
ALCOHOL-TYPE AQUEOUS FILM-FORMING FOAM/WATER SPRAY. WATER MAY BE INEFFECTIVE
BUT SHOULD BE USED TO COOL FIRE-EXPOS STRUCTURES/VESSELS.
Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
IN CASE OF FIRE, USE DRY CHEM, FOAM, CARBON DIOXIDE/OTHER APPRVD METH FOR
TREATING A CLASS B FIRE. SUMMON PROFESSIONAL FIREFIGHTERS. DURING FIRE, TOX G
ASES & SMOKE ARE IRRITANTS PRESENT FROM DECOMP/COMBUST. CLSD CONTRS MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard: FLAMM CLASSIFICATION: 1B. EXPLO LEVEL: LOW
0.60%; HIGH 11.50%. KEEP AWAY FROM HEAT, SPKS & FLAME. DO NOT SMOKE.
EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF IGNIT, INCL HEATERS,
FANS, & OTHER NON -EXPLO PROOF ELEC EQUIP, DURING USE & UNTIL ALL
VAPS ARE GONE. VAPS MAY IGNITE EXPLO. (FED REGS)
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Control Measures
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Respiratory Protection: MAINTAIN CONTINUOUS FLOW OF FRESH AIR. WEAR APPROPRIATE
PROPERLY FITTED RESPIRATOR (NIOSH APPROVED) DURING AND AFTER APPLICATION
UNLESS AIR MONITORING DEMONSTRATES VAPOR AND PARTICULATE LEVELS ARE BEL OW
APPLICABLE LIMITS. FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR
USE.
Ventilation: ENGINEERING/ADMINISTRATIVE CTLS SHOULD BE IMPLEMENTED TO REDUCE
EXPOS. PROVIDE SUFFICIENT MECH (GEN &/OR LOCAL EXHAUST) VENT TO MAINTAIN
EXPOS BELOW TLV(S).
Protective Gloves: SOLVENT IMPERMEABLE GLOVES SHOULD BE WORN TO PREVENT SKIN
CONTACT.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER
(FP N). SOLVENT IMPERMEABLE CLOTHING AND BOOTS SHOULD BE WORN TO PREVENT SKIN
CONTACT.
Work Hygienic Practices: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
Supplemental Safety and Health: SPILL PROC: REMAINING LIQ MAY BE ABSORBED
W/INERT MATL SUCH AS SAND, CLAY, EARTH/FLOOR ABSORB, & SHOVELED INTO
CONTRS W/NON-SPKG TOOLS. PVNT RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF
WATER. IF RUN-OF F OCCURS, NOTIFY AUTH AS REQUIRED THAT A SPILL HAS OCCURRED.
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Physical/Chemical Properties
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Boiling Point: >79.4C, 175.F
Vapor Pres: SEE INGREDIENTS
Spec Gravity: 1.56
Evaporation Rate & Reference: 0.0 (N-BUTYL ACETATE=1)
Percent Volatiles by Volume: 38.94
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HEATING IN THE PRESENCE OF CATALYTIC AMOUNTS OF
ALKALIS AND ACIDS.
Materials To Avoid: ACIDS, ALKANOLAMINES, ALDEHYDES, AMINES, AMMONIA, STRONG
BASES, CAUSTICS, CHLORINATED COMPOUNDS, OXIDIZING AGENTS AND ALIPHATIC
AMINES. THIS PRODUCT WILL DISSOLVE SOME PLASTICS, RUBBER, AND COATINGS.
Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE, TOXIC FUMES,
VARIOUS HYDROCARBONS, ACRID SMOKE, PHENOL AND VARIOUS PHENOLIC COMPOUNDS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR BY ITSELF. MASSES OF >1LB OF
PROD + ALIPHATIC AMINE WILL CAUSE IRREVERSIBLE POLYM W/CONSIDERABLE HEAT
BUILDUP.
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Toxicological Information
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Toxicological Information: EFTS OF OVEREXP: RPTS HAVE ASSOC RPTD & PRLNG
OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY
DELIB CONCENTRATING & INHALING PROD MAY BE HARMFUL/FATAL. LONG TERM
EXCESS EXPOS MAY CAUSE TALCOSIS, A PULM FIBROSIS W/SHORTNESS OF BREATH,
CHRONIC COUGH & RESP-ASSISTED HEART FAILURE. PRLNG EXPOS TO TALC CAN
PRDCE MILD SYMPTOMATIC PNEUMOCONIOSIS. TARGET ORGANS: OVEREXP TO THIS M
ATL/ITS COMPONENTS HAS BEEN SUGGESTED AS A CAUSE OF THE FOLLOWING EFTS IN LAB
ANIMALS &/OR HUMANS, & MAY AGGRAVATE PREEXISTING DISORDERS OF THESE
ORGANS IN HUMANS: ABNORMS OF REPRO ORGANS, ANEMIA, BLO OD DISORDERS,
(ECOLOGICAL INFO)
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Ecological Information
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Ecological: NO ECOLOGICAL DATA AVAILABLE FOR THIS PRODUCT. --TOXICOLOGICAL
INFO: BRAIN DMG, CARD ABNORM, EYE DMG, KIDNEY DMG, KIDNEY DMG SECONDARY TO
RED BLOOD CELL BREAKDOWN & LIVER DMG MAY OCCUR FROM INGEST OF THIS MATL,
LIVER ABNORMS, LUNG DMG, MENSTRUAL & FERTILITY DISORDERS, NERV SYS DMG,
SKIN DMG, RESP SYS, CNS & PERIPHERAL NERV SYS (PNS).
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MSDS Transport Information
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Transport Information: D.O.T. HAZARD CLASS: 3. D.O.T. PROPER SHIPPING NAME:
PAINT. D.O.T. PACKAGING GROUP: II. D.O.T. PLACARD: FLAMMABLE. D.O.T. LABEL:
FLAMMABLE LIQUID. UN/NA NUMBER: 1263.
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Regulatory Information
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Sara Title III Information: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
XYLENE , CAS # 1330-20-7, 3% BY WEIGHT; METHYL ETHYL KETONE, CAS # 78-93-3,
4% BY WEIGHT; STRONTIUM CHROMATE, CAS # 7789-06-2, 26% BY WEIGHT.
Federal Regulatory Information: FIRE/EXPLOSION HAZARDS: VAPORS MAY SPREAD LONG
DISTANCES AND BEYOND CLOSED DOORS. PREVENT BUILD-UP OF VAPORS BY MAINTAINING
A CONTINUOUS FLOW OF FRESH AIR. PHYSICAL/CHEMICAL PROPERTIES: FORMULA WEIGHT
PER VOL: 13.00 LBS/GAL; VOC OF MATERIAL: 328 G/L OR 2.74 LBS/GAL; % VOLATILE
BY WEIGHT: 21.08; COEFFICIENT OF WATER/OIL DIST: N/A.
State Regulatory Information: CALIFORNIA PROPOSITION 65: WARNING: THIS PRODUCT
CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
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Other Information
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Other Information: PROD CLASS: MODIFIED EPOXY RESIN. THIS PROD CONTAINS
PIGMENTS WHICH MAY BECOME A DUST NUISANCE WHEN REMOVED BY ABRASIVE BLASTING,
SANDING/GRINDING. AIRBORNE NUISANCE PARTICULATES HAVE AN ACGIH TLV FOR TOTAL
DUST OF 10 MG/M3. IMPORTANT: THIS PROD MAY BE BLENDED W/OTHER PRODS PRIOR TO
USE. READ ALL WARNINGS & PREC ON MSDS'S & LABELS OF ALL PRODS BEING
BLENDED AS COMBINATION MAY CONTAIN HAZS OF EACH COMPONENT. FOR INDUS USE
ONLY: THIS PROD IS FOR USE BY PROFESSIONAL, TRAINED PERSONNEL USING PROPER
EQUIP, & IS NOT INTENDED FOR SALE TO, OR USE BY GENERAL PUBLIC.
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HAZCOM Label
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MSDS NAME: HIGH SOLIDS MAX COR PRIMER, R4001
Company: US PAINT CORPORATION
Street: 831 SOUTH 21ST STREET
City: ST LOUIS MO
Zipcode: 63103-3092
Health Emergency Phone: 703-527-3887
Label Required IND: Y
Date Of Label Review: 10/06/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMM CLASS IB. ACUTE: EYES: MAY CAUSE MOD IRRIT,
REDNESS, TEARING & BLURRED VISION. MAY CAUSE BURNS. SKIN: CAN CAUSE MOD
IRRIT, DEFAT & DERM. PRLNG CONT MAY RSLT IN CHEM BURNS & PERM DMG.
CAN BE ABSO RBED THRU SKIN, & MAY CONTRIBUTE TO SYMPS OF TOXICITY FROM
OTHER RTES OF EXPOS. INHAL: MAY CAUSE IRRIT OF MUC MEMBS, COUGH, DISCOMFORT,
RAPID/DFCLT BRTHG/SHORTNESS OF BREATH. CAN CAUSE CNS EFTS. INGES T: MOD
TOXIC. CAN IRRITATE DIGESTIVE TRACT & CAUSE NAUS, VOMIT & DIARRHEA.
ASPIR HAZ. CHRONIC: SENSITIZER - CAN CAUSE ALLERGIC SKIN REACTION WHICH MAY
BE SEVERE IN CERTAIN INDIVIDUALS. MAY CAUSE ALLE RGIC RESPIRATORY REACTION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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