ITW PHILADELPHIA RESINS -- ANNAPOLIS ADHESIVE RESIN, 6020R
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CKWTS
MSDS NAME: ANNAPOLIS ADHESIVE RESIN, 6020R
Responsible Party
Name: ITW PHILADELPHIA RESINS
Address: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA 18936
Info Phone: 215-855-8450
Emergency Phone Number: (800)424-9300
Chemtrec IND/Phone: (800)424-9300
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ITW PHILADELPHIA RESINS CORPORATION
Address: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA 18936
Phone: 215-855-8450
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Ingredients
=======================================================
Cas: 25068-38-6
RTECS #: CE6880000
Name: BISPHENOL A DIGLYCIDYL ETHER RESIN. (DGEBPA)
% low Wt: 60.
% high Wt: 100.
Other REC Limits: N/E
OSHA PEL: N/E
ACGIH TLV: N/E
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EMERGENCY OVERVIEW: EYE AND SKIN IRRITANT. POTENTIAL SKIN
SENSITIZER. AVOID CONTACT WIITH EYES. AVOID PROLONGED OR REPEATED SKIN
CONTACT. DO NOT TAKE INTERNALLY. WASH THOROUGHLY AFTER HANDLING. EFFEC TS OF
ACUTE OVEREXPOSURE: SKIN: MODERATE IRRITANT. CONTACT AT ELEVATED TEMPERATURES
CAN CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION (RASHES, HIVES,
DEFATTING). EYES: MODERATE IRRITANT. CONTACT A T ELEVATED TEMPERATURES CAN
CAUSE THERMAL BURNS. HIGH VAPOR CONCENTRATIONS MAY ALSO BE IRRITATING.
INHALATION: VAPORS MAY IRRITATE NOSE, THROAT, AND RESPIRATORY TRACT. HIGH
VAPOR CONCENTRATIONS MAY CA USE CENTRAL NERVOUS (EFTS OF OVEREXPOS).
Signs And Symptions Of Overexposure: HEALTH HAZARDS (CONT'D) : SYSTEM (CNS)
DEPRESSION (HEADACHE, NAUSEA, GIDDINESS, DIZZINESS). INGESTION: MAY CAUSE
GASTRIC DISTRESS AND ASPIRATION (EVIDENCED BY COUGHING). MAY CAUSE CNS
DEPRESSION. EFFE CTS OF CHRONIC OVEREXPOSURE: PROLONGED OR REPEATED SKIN
CONTACT MAY CAUSE SENSITIZATION, WITH ITCHING, SWELLING, OR RASHES ON LATER
EXPOSURE. OTHER EFFECTS: NONE KNOWN.
Medical Cond Aggravated By Exposure: PREEXISTING EYE, SKIN AND RESPIRATORY
DISORDERS. DEVELOPMENT OF PREEXISTING SKIN OR LUNG ALLERGY SYMPTOMS MAY
INCREASE.
First Aid: EYES: FLUSH EYES WITH CLEAN WATER FOR AT LEAST 15 MINUTES WHILE
GENTLY HOLDING EYELIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN:
IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND EXCESS CONTAMINANT. FLU SH SKIN
WITH WATER. WASH THOROUGHLY WITH SOAP AND WARM WATER. CONSULT A PHYSICIAN IF
IRRITATION DEVELOPS. INHALATION: REMOVE PATIENT TO FRESH AIR. ADMINISTER
OXYGEN IF BREATHING IS DIFFICULT. GET MED ICAL ATTENTION IF SYMPTOMS PERSIST.
INGESTION: DO NO INDUCE VOMITING. GIVE TWO GLASSES OF WATER TO DILUTE IF
PATIENT IS CONSCIOUS. GET MEDICAL ATTENTION. NOTE TO PHYSICIAN: IN GENERAL,
EMESIS INDUCTIO N IS UNNECESSARY IN HIGH (NEUT AGENT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AVOID PERSONAL CONTACT. ELIMINATE IGNITION SOURCES.
VENTILATE AREA. DIKE, CONTAIN AND ABSORB WITH CLAY, SAND OR OTHER SUITABLE
MATERIAL. FOR LARGE SPILLS, PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESI DUE
WITH AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIAL AND DISPOSE
OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. PREVENT SPILL
FROM ENTERING DRAINAGE/SEWER (SUPP SFTY)
Neutralizing Agent: N/P. FIRST AID (CONT'D): VISCOSITY, LOW VOLATILITY
PRODUCTS, E.G., NEAT EPOXY RESINS.
Waste Disposal Methods: IF THIS RESIN BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: HANDLING: AVOID CONTACT WITH SKIN, EYES, OR
CLOTHING. HANDLE MIXED RESIN AND HARDENER IN ACCORDANCE WITH THE POTENTIAL
HAZARD OF THE CURING AGENT USED. PROVIDE APPROPRIATE VENTILATION AND
REPSPIRATORY PROTECTION AGAINST DECOMPOSITION PRODUCTS DURING WELDING/FLAME
(OTHER PREC)
Other Precautions: HANDLNG/STORAGE (CONT'D): CUTTING OPERATIONS AND TO PROTECT
AGAINST NUISANCE DUST DURING SANDING/GRINDING OF CURED PRODUCT. USE
BONDING/GROUNDING STRAPS WHEN TRANSFERRING LIQUID. STORAGE: STORE IN AN
ADEQUATELY VENTILATED, COOL, DRY AREA AWAY FROM HIGH TEMPERATURES AND FLAMES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point: >93.3C, 200.F
Flash Point Text: ESTIMATE.
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL AND FOAM.
Fire Fighting Procedures: MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER
CONFINED SPACE WITHOUT FULL BUNKER GEAR. FIREFIGHTERS SHOULD WEAR NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard: HEATING ABOVE 300 DEG F IN THE PRESENCE OF AIR
MAY CAUSE SLOW OXIDATIVE DECOMPOSITION AND ABOVE 500 DEG F MAY CAUSE
POLYMERIZATION. WHEN HEATED TO DECOMPOSITION IT EMITS FUMES OF CL-, CARBON
MONOXIDE, OTHER FUMES AND VAPORS VARYING IN COMPOSITION AND TOXICITY.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE REQUIRED AT NORMAL HANDLING TEMPERATURES AND
CONDITIONS. USE NIOSH APPROVED ORGANIC VAPOR CARTIDGES FOR UNCURED RESIN AND
DUST/PARTICLE RESPIRATORS DURING GRINDING/SANDING OPERATIONS OF CURED RES IN
AS EXPOSURE LEVELS DICTATE.
Ventilation: LOCAL EXHAUST VENT IS PREFERRED ALTHOUGH GOOD GENERAL MECHANICAL
VENTILATION IS USUALLY ADEQUATE FOR MOST INDUSTRIAL APPLICATIONS. LOCAL
EXHAUST IS (SUPP SFTY)
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL FACESHIELD (FP
N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). CHEMICAL RESISTANT GEAR TO PREVENT SKIN CONTACT.
Work Hygienic Practices: WASH THOROUGHLY WITH SOAP AND WATER AFTER USING AND
PARTICULARLY BEFORE DRINKING, SMOKING, APPLYING COSMETICS, OR USING TOILET
FACILITIES. LAUNDER CONTAMINATED CLOTHING AND PROTECTIVE (SUPP SFTY)
Supplemental Safety and Health: SPILL PROCEDURE (CONT'D): SYSTEMS, WATERWAYS
AND SURFACE WATER. VENTILATION (CONT'D): RECOMMENDED FOR CONFINED AREAS.
WORK HYGIENE PRACTICE (CONT'D): GEAR BEFORE REUSE. DISCARD CONTAMINATED
LEATHER A RTICLES. PHYSICAL/CHEMICAL PROPERTIES: PERCENT SOLIDS BY WEIGHT:
100.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >121.1C, 250.F
M.P/F.P Text: N/D
Vapor Pres: N/D AT 0 F.
Vapor Density: >1(AIR=1).
Spec Gravity: 1.17-1.22.
PH: NEUTRAL
Evaporation Rate & Reference: N/D (BUTYL ACETATE=1).
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: VISCOUS LIQUID; LITTLE ODOR.
Percent Volatiles by Volume: 0
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: OPEN FLAME, SPARKS AND EXTREME HEAT. CONDITIONS
TO AVOID POLYMERIZATION (CONT'D): THE RESIN, GENERATING UNIDENTIFIED FUMES
AND VAPORS WHICH MAY BE TOXIC.
Materials To Avoid: STRONG LEWIS OR MINERAL ACIDS, STRONG OXIDIZING AGENTS,
STRONG MINERAL AND ORGANIC BASES (ESPECIALLY PRIMARY AND SECONDARY ALIPHATIC
AMINES).
Hazardous Decomposition Products: OXIDES OF CARBON;ALDEHYDES, ACIDS AND OTHER
ORGANIC SUBSTANCES MAY BE FORMED DURING COMBUSTION OR ELEVATED TEMPERATURE
(>500 DEG F) DEGRADATION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: HEAT IS GENERATED WHEN RESIN IS MIXED WITH
CURING AGENTS; RUN-AWAY CURE REACTIONS MAY CHAR AND DECOMPOSE (STABILITY
COND).
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ACUTE ORAL EFFECTS: LD50 (RAT): NO DATA AVAILABLE.
ACUTE DERMAL EFFECTS: LD50 (RABBIT): NO DATA AVAILABLE. ACUTE INHALATION
EFFECTS: LC50 (RAT): NO DATA AVAILABLE. EXPOSURE: 8 HRS. EYE IRRITATION: NO
DATA AVAILABLE. SUBCHRONIC EFFECTS: NO DATA AVAILABLE. CARCINOGENICITY,
TERTOGENICITY, AND MUTAGENICITY: BOTH THE RESIN AND THE DIGLYCLDYL ETHER OF
BISPHENOL (A COMPONENT OF THIS PRODUCT) HAVE PROVED TO BE INACTIVE WHEN
TESTED BY IN VIVO MUTAGENICITY ASSAYS. BOTH HAVE SHOWN ACTIVITY BY IN VITRO
MICROBIAL MUTAGENICITY SCREENING AND HAVE PRODUCED CHROMOSOMAL ABERRATIONS IN
CULTURED RAT LIVER CELLS. (ECOLOGICAL INFORMATION)
=======================================================
Ecological Information
=======================================================
Ecological: ECOTOXICITY, MOBILITY AND PERSISTENCE, ENVIRONMENTAL FATE: NO DATA
AVAILBLE. TOXICOLOGICAL INFORMATION (CONT'D): OTHER CHRONIC EFFECTS: 2-YEAR
BIOASSAYS IN MICE EXPOSED BY THE DERMAL ROUTE TO EPON 82 8, DGEBPA, OR OTHER
COMMERCIAL RESINS YIELDED LIMITED EVIDENCE OF WEAK CARCINOGENICITY. THE
AUTHORS CONCLUDED THAT THE RENAL TUMOR EVIDENCE WITH EPON 828 "WAS OF NO
BIOLOGICAL SIGNIFICANCE" AND THAT T HE RESIN "IS NOT A SYSTEMIC CARCINOGEN
WHEN APPLIED TO THE DORSAL SKIN OF CF1 MICE." TOXICOLOGICAL INFORMATION ON
HAZARDOUS CHEMICAL CONSTITUENTS OF THIS PRODUCT: BISPHENOL A DIGYLCIDYL ETHER
RESIN: ( TRANSPORT)
=======================================================
MSDS Transport Information
=======================================================
Transport Information: PROPER SHIPPING NAME: NON-REGULATED. HAZARD CLASS, UN
NUMBER, PACKING GROUP, EMERGENCY RESPONSE GUIDE NO.: N/A. ECOLOGICAL
INFORMATION (CONT'D): LD5O (ORAL, RAT): 30 G/KG. LD50 (DERMAL, RABBIT):
>20 M L/KG. LC50 (INHALATION, 4 HOURS, RAT): NO DEATHS. TECHNICAL NAME:
N/P. IMDG PAGE NUMBER: N/P.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: FOR PURPOSES OF SARA SECTION 312 HAZARDOUS
MATERIALS INVENTORY REPORTING, THE FOLLOWING HAZARD CLASSES APPLY TO THIS
MATERIAL: IMMEDIATE HEALTH HAZARD - DELAYED HEALTH HAZARD.
Federal Regulatory Information: TSCA: ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED OR ARE EXEMPT FROM LISTING, ON TSCA INVENTORY. FOLLOWING RCRA CODES
APPLIES TO THIS MATERIAL IF IT BECOMES WASTE: NONE. REGULATORY STATUS OF
HAZARDOUS CHEMICAL CONSTITUENTS OF THIS PRODUST: BISPHENOL A DIGLYCIDYL
ETHER RESIN - EXTREMELY HAZARDOUS: NO. TOXIC CHEMICAL: NO. CERCLA RQ(LBS):
NONE. TSCA 12B EXPORT NOTIFICATION: REQUIRED. CANADIAN REGULATI ONS: W HAZARD
CLASS: D2B.
State Regulatory Information: N/P.
=======================================================
Other Information
=======================================================
Other Information: HEALTH -2, FLAMMABILITY-1, REACTIVITY-1. GENERAL USE: THIS
INFORMATION APPLIES TO THE RESIN COMPONENT OF THE TWO-PART KIT; HANDLE
FRESHLY-MIXED RESIN AND HARDENER AS RECOMMENDED FOR HARDENER. AF TER CURING,
THE PRODUCT IS NOT HAZARDOUS. CHEMICAL FAMILY: EPOXY RESIN.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: ANNAPOLIS ADHESIVE RESIN, 6020R
Company: ITW PHILADELPHIA RESINS CORPORATION
Street: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA
Zipcode: 18936
Health Emergency Phone: (800)424-9300
Label Required IND: Y
Date Of Label Review: 12/20/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: EYE & SKIN IRRIT. POTENTIAL SENSITIZER. AVOID
CONTACT WITH EYES. AVOID PROLONGED/REPEATED SKIN CONTACT. DO NOT TAKE
INTERNALLY. CONTACT AT ELEVATED TEMPS CAN CAUSE THERMAL BURNS. ACUTE: SKIN:
MODERATE IRRIT. MAY CAUSE SKIN SENSITIZATION, RASHES/HIVES/DEFATTING. EYES:
MODERATE IRRIT. HIGH VAPOR CONCENTRATIONS MAY BE IRRIT. INHAL: VAPORS MAY
IRRIT NOSE, THROAT, & RESP TRACT. HIGH VAPOR CONCENTRATION S MAY CAUSE
CNS DEPRESSION, HEADACHE/NAUSEA/GIDDINESS/DIZZINESS. INGEST: MAY CAUSE
GASTRIC DISTRESS & ASPIRATION. MAY CAUSE CNS DEPRESSION. CHRONIC:
PROLONGED/REPEATED SKIN CONTACT MAY CAUSE SENSITIZA TION, WITH
ITCHING/SWELLING/RASHES ON LATER EXPOS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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