MARSH COMPANY -- SPRAY MARKOVER, TAN, 27012, 3U572
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Material Safety Data Sheet
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MSDS Num: CKWTC
MSDS NAME: SPRAY MARKOVER, TAN, 27012, 3U572
Responsible Party
Name: MARSH COMPANY
Address: 707 EAST B STREET
Box: 388
City: BELLEVILLE IL 62222
Info Phone: 618-234-1122
Emergency Phone Number: 800-535-5053 (WITHIN USA)
Resp. Party Other MSDS No.: 26599EN, REVISION A
Proprietary Ind: Y
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
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Name: MARSH COMPANY
Address: 707 EAST B STREET
Box: 388
City: BELLEVILLE IL 62222
Phone: 618-234-1122
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Ingredients
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Name: *** PROPRIETARY ***
-----------------------------
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHALATION: PROLONGED EXPOSURE MAY CAUSE CNS
DEPRESSION. SYMPTOMS MAY INCLUDE INTOXICATION, SHORTNESS OF BREATH,
DIZZINESS, OR LIGHTHEADNESS, HEADACHE, NAUSEA OR COMA. EYE CONTACT: VAPOR MAY
BE IRRITATING. SYMPTOMS CAN INCLUDE SCRATCHINESS, REDNESS OR BURNING. SKIN
CONTACT: MAY CAUSE IRRITATION. PROLONGED CONTACT CAN CAUSE IRRITATION,
DEFATTING OF SKIN AND POSSIBLY DERMATITIS. INGESTION: UN LIKELY ROUTE OF
ENTRY. EFFECTS CAN INCLUDE NAUSEA AND VOMITING. CHRONIC: UNKNOWN.
Explanation Of Carcinogenicity: COMPONENTS LISTED AS CARCINOGENS BY REGULATORY
AGENCIES:
OSHA: NONE LISTED. IARC: NONE LISTED. NTP: NONE LISTED.
Signs And Symptions Of Overexposure: SEE HEALH HAZARDS.
First Aid: INHALATION: IF EXPOSED TO EXCESSIVE LEVELS OF VAPOR OR MIST, REMOVE
TO FRESH AIR AND GET IMMEDIATE MEDICAL ATTENTION. EYE CONTACT: IMMEDIATELY
FLUSH EYES WITH PLENTY OF WATER. GET IMMEDIATE MEDICAL AT TENTION. SKIN
CONTACT: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION
DEVELOPS OR PERSISTS. INGESTION: IF SWALLOWED, DO NOT INDUCE VOMITING, BUT
GIVE ONE OR TWO GLASSES OF WATER TO DRIN K AND GET IMMEDIATE MEDICAL
ATTENTION.
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Handling and Disposal
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Spill Release Procedures: SPILL: REMOVE SOURCES OF IGNITION. DIKE SPILL. ABSORB
WITH INERT MATERIAL & COLLECT FOR DISPOSAL. FLUSH AREA WITH WATER.
PREVENT WASHINGS FROM ENTERING WATERWAYS. GENERAL: NOTIFY THE APPROPRIATE
AUTH ORITIES TAKE ALL ADDITIONAL ACTION NECESSARY TO PREVENT & REMEDY
THE ADVERSE EFFECTS OF THE SPILL. CONSULT EXPERT ON DISPOSAL OF RECOVERED
MATL. ENSURE DISPOSAL IS IN COMPLIANCE W/GOVERNMENTAL REGS.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
LAWS AND REGULATIONS. DO NOT REUSE "EMPTY" CONTAINERS.
Handling And Storage Precautions: AVOID BREATHING VAPOR. AVOID CONTACT WITH
SKIN AND EYES. AVOID IGNITION SOURCES. KEEP CONTAINERS CLOSED. STORE IN A
COOL, DRY PLACE AWAY FROM HEAT AND LIGHT. KEEP FROM FREEZING. STORE BETWEEN
40-120 D EGREES FAHRENHEIT (4-49 DEGREES CELSIUS). FOLLOW ALL REGULATIONS FOR
THE STORGE OF AEROSOLS.
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Fire and Explosion Hazard Information
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Flash Point Text: N/AP FOR AEROSOL
Autoignition Temp Text: N/AV.
Lower Limits: 1.0%
Upper Limits: 12.8%
Extinguishing Media: USE CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRES. USE
ALCOHOL FOAM, UNIVERSAL FOAM OR WATER SPRAY FOR LARGE FIRES.
Fire Fighting Procedures: USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS
AND FULL PROTECTIVE EQUIPMENT (FP N). REMOVE ALL IGNITION SOURCES.
Unusual Fire/Explosion Hazard: FLAMMABLE LIQUID AND ESCAPING VAPORS MAY IGNITE
WHICH CAN RESULT IN A FLASH FIRE. CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD
UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. THERMAL DECOMPOSITION MAY PR
ODUCE SMOKE, OXIDES OF CARBON, OXIDES OF NITROGEN AND POSSIBLY TOXIC
HYDROCARBONS.
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Control Measures
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Respiratory Protection: A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN (FP N). RESPIRATORY PROTECTION EQUIPMENT SUITABLE TO WORK
CONDITIONS AND ENVIRONMENT (MFR).
Ventilation: LOCAL EXHAUST RECOMMENDED TO CONTROL EXPOSURE WHICH MAY RESULT
FROM OPERATIONS THAT GENERATE AEROSOL VAPORS OR MISTS.
Protective Gloves: WEAR IMPERVIOUS GLOVES FOR OPERATIONS WHERE CONTACT CAN
OCCUR.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). FOR OPERATIONS WHERE CONTACT CAN OCCUR, WEAR CLOTHING TO
LIMIT SKIN CONTACT.
Supplemental Safety and Health: AEROSOL WITH AROMATIC ODOR. EXTREMELY
FLAMMABLE. AVOID INHALATION. VAPOR EXPOSURE MAY CAUSE SHORTNESS OF BREATH,
DIZZINESS, LIGHTHEADNESS, SENTRAL NERVOUS SYSTEM (CNS) EFFECTS, OR LIVER AND
KIDNEY EFF ECTS. VAPOR MAY IRRITATE EYES.
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Physical/Chemical Properties
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B.P. Text: -44 TO 406F (-42 TO 206C)
M.P/F.P Text: NOT AVAILABLE.
Vapor Pres: NOT AVAILABLE.
Vapor Density: HEAV AIR
Spec Gravity: APPROXIMATELY 0.72-0.77.
PH: NOT AVAILABLE.
Viscosity: NOT AVAILABLE.
Evaporation Rate & Reference: > 1.0
Solubility in Water: SLIGHTLY.
Appearance and Odor: AEROSOL OF TAN COLOR. AROMATIC SOLVENT ODOR.
Percent Volatiles by Volume: NOT AVAIL.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXCESSIVE HEAT.
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY PRODUCE SMOKE,
OXIDES OF CARBON, OXIDES OF NITROGEN AND POSSIBLY TOXIC HYDROCARBONS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
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Toxicological Information: ACUTE TOXICITY- PRODUCTS REPRESENTED BY THIS MSDS
HAVE NOT BEEN TESTED FOR ACUTE TOXICOLOGICAL EFFECTS. THE AVAILABLE TOXICITY
DATA FOR THE HAZARDOUS INGREDIENTS LISTED IS GIVEN. INHALATION EFFECTS: A
CETONE: LC50 (RAT) = 50,100 MG/M3. DIACETONE ALCOHOL: RATS EXPOSED TO 1065
PPM IN AIR FOR 8 HOURS HAD NO DEATHS. STODDARD SOLVENT: LC50 (RAT) > 5500
MG/M3. VM & P NAPHATHA: LC50 (RAT) = 3400 PPM (4 HO UR). EYE EFECTS:
ACETONE: MODERATELY IRRITATING. DIACETONE ALCOHOL: MODERATELY IRRITATING.
STODDARD SOLVENT: MODERATELY IRRITATING. VM & P NAPHTHA: MODERATELY
IRRITATING. SKIN EFFECTS: ACETONE: MILDLY IRRITATING. DIACETONE (ECOLOGICAL)
=======================================================
Ecological Information
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Ecological: ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE. CHEMICAL FATE
INFORMATION: NO DATA AVAILABLE. TOXICOLOGICAL DATA (CONT'D): ALCOHOL: MILDLY
IRRITATING. DERMAL LD50 (RABBIT) = 13.6 G/KG. STODDARD SOLVE NT: DERMAL LD50
(RABBIT) >3.0 G/KG. ORAL EFFECTS: ACETONE: ORAL LD50 (RAT) = 5.8 G/KG.
DIACETONE ALCOHOL: ORAL LD50 (RAT) = 4.0 G/KG. STODDARD SOLVENT: ORAL LD50
(RAT) > 5.0 G/KG. SUBCHRONIC EFFECTS: PRODUCTS REPRESENTED BY THIS MSDS
HAVE NOT BEEN TESTED FOR SUBCHRONIC TOXICOLOGICAL EFFECTS. IN AN INHALATION
STUDY USING DIACETONE ALCOHOL, RATS RECEIVED DOSES UP TO 950 PPM FOR 6HR/DAY,
5 DAY/WK FO R 6 WEEKS. KIDNEY AND LIVER (TRANSPORT)
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MSDS Transport Information
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Transport Information: GROUND TRANSPORT (DOT): CONSUMER COMMODITY (ORM-D) (ERG
171). AIR TRANSPORT (IATA): CONSUMER COMMODITY, 9, ID8000, (ERG 171). OCEAN
TRANSPORT (IMCO): AEROSOLS, CLASS 2, UN1950, CONSUMER PRODUCT, IMDG 2102,
(EMS 2-13), (ERG 126). ECOLOGICAL DATA (CONT'D): DAMAGE WERE OBSERVED. IN
ANOTHER STUDY, RATS RECEIVED 40 MG/KG/DAY OF DIACETONE ALCOHOL IN THEIR
DRINKING WATER FOR 30 DAYS. KIDNEY AND LIVER D AMAGE WERE OBSERVED. THE
SIGNIFICANCE OF THESE STUDIES TO HUMANS IS NOT KNOWN. CHRONIC
EFFECTS/CARCINOGENICITY: PRODUCTS REPRESENTED BY THIS MSDS HAVE NOT BEEN
TESTED FOR CHRONIC TOXICOLOGICAL EFFECTS . (OTHER INFO)
=======================================================
Regulatory Information
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Sara Title III Information: 311/312 HAZARD CATEGORIES: IMMEDIATE (ACUTE) HEALTH
HAZARD AND PHYSICAL (FIRE) HAZARD. 313 REPORTABLE INGREDIENTS: ACETONE
(<50%).
Federal Regulatory Information: OSHA CLASSIFICATION: HAZARDOUS. TSCA STATUS: IN
COMPLIANCE.
CERCLA: ACETONE (RQ=5,000 LBS.). RCRA: IT IS UP TO THE PRODUCT USER TO
DETERMINE, AT THE TIME OF DISPOSAL, IF THE MATERIAL SHOULD BE CLASSIF IED AS
A HAZARDOUS WASTE. CLEAN AIR ACT OZONE DEPLETING SUBSTANCES: NONE. CLEAN AIR
ACT HAZARDOUS AIR POLLUTANTS: NONE. VOLATILE ORGANIC COMPOUNDS (VOC'S): NOT
AVAILABLE. CONEG/HEAVY METALS: INFORMATI ON AVAILABLE UPON REQUEST. FDA
STATUS: (21 CFR) THIS PRODUCT DOES NOT HAVE APPROVAL AS A FOOD ADDITI VE,
EITHER DIRECT OR INDIRECT. WHEN THIS PRODUCT IS APPLIED TO THE OUTSIDE
SURFACE OF FOOD CONTAINERS AND THE CONTAINER (STATE REG)
State Regulatory Information: CALIFORNIA PROPOSITION 65 STATUS: (CCR DIVISION 2
OF TITLE 22, SECTION 12000, ET SEQ.) THIS PRODUCT DOES NOT CONTAIN CHEMICALS
REGULATED BY PROPOSITION 65. FEDERAL REGS (CONT'D): ITSELF ACTS AS A FUNC
TIONAL BARRIER SO THAT THERE IS NO MIGRATION OF THE COMPONENTS OF THIS
PRODUCT TO FOOD, THEN IT WOULD NOT BE CONSIDERED A FOOD ADDITIVE. USDA
STATUS: (9CFR) THIS PRODUCT IS NOT INTENDED TO BE EITHER A DIRECT OR
INDIRECT FOOD ADDITIVE. IT IS CHEMICALLY ACCEPTABLE FOR USE ON PACKAGING
MATERIALS IF IT IS SEPARATED FROM THE MEAT OR POULTRY BY AN EFFECTIVE
BARRIER TO THE MIGRATION OF THE COMPONENTS OF THIS PRODUCT. CANADA W (OTHER
INFO)
=======================================================
Other Information
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Other Information: NFPA: HEALTH-1, FLAMMABILITY-3, REACTIVITY-0. : HEALTH-2,
FLAMMABILITY-3, REACTIVITY-0. EMERGENCY PHONE # (OUTSIDE USA, CALL COLLECT)
352-323-3500. FAX#: 618-234-1529. GENERAL USE: MARKING INK FO R PRINTING
EQUIPMENT. (TRANS, CONT'D) MUTAGENICITY: PRODUCTS REPRESENTED BY THIS MSDS
HAVE NOT BEEN TESTED FOR MUTAGENIC TOXICOLOGICAL EFFECTS OR REPRODUCTIVE
TOXICOLOGICAL EFFECTS. STATE REGULATIONS (CONT'D): CLASSIFICATION: A, B5,
D2A. DSL STATUS: IN COMPLIANCE. EUROPEAN UNION: CLASSIFICATION: HARMFUL - F;
R12 S(2)-9-16-23-24-62. EINECS STATUS: IN COMPLIANCE.
=======================================================
HAZCOM Label
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MSDS NAME: SPRAY MARKOVER, TAN, 27012, 3U572
Company: MARSH COMPANY
Street: 707 EAST B STREET
PO Box: 388
City: BELLEVILLE IL
Zipcode: 62222
Health Emergency Phone: 800-535-5053 (WITHIN USA)
Label Required IND: Y
Date Of Label Review: 12/19/2000
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMALBLE! ACUTE: INHALATION: PROLONGED
EXPOSURE MAY CAUSE CNS DEPRESSIONOR LIVER AND KIDNEY EFFECTS. SYMPTOMS MAY
INCLUDE INTOXICATION, SHORTNESS OF BREATH, DIZZINESS, OR LIGHTHEADNESS, H
EADACHE, NAUSEA OR COMA. EYE CONTACT: VAPOR MAY BE IRRITATING. SYMPTOMS CAN
INCLUDE SCRATCHINESS, REDNESS OR BURNING. SKIN CONTACT: MAY CAUSE IRRITATION.
PROLONGED CONTACT CAN CAUSE IRRITATION, DEFATT ING OF SKIN AND POSSIBLY
DERMATITIS. INGESTION: UNLIKELY ROUTE OF ENTRY. EFFECTSCAN INCLUDE NAUSEA AND
VOMITING. CHRONIC: UNKNOWN. NONE SPECIFIED BY MANUFACTURER (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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