DU PONT E I DE NEMOURS & INC -- SUVA HP80 (R402A)
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CKWPH
MSDS NAME: SUVA HP80 (R402A)
Responsible Party
Name: DU PONT E I DE NEMOURS & CO INC
Address: 1007 MARKET STREET
Box: 1635
City: WILMINGTON DE 19898
Info Phone: 800-441-7515/MSDS 302-992-3511
Emergency Phone Number: 800-441-3637
Resp. Party Other MSDS No.: DU005613
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: DU PONT FLUOROPRODUCTS
Address: 1007 MARKET STREET
City: WILMINGTON DE 19898
Phone: 1-800-441-7515
Name: E.I. DUPONT DE NEMOURS & CO
Address: 1007 MARKET STREET
City: WILMINGTON DE 19898
Phone: 800-441-7515;800-441-9442
=======================================================
Ingredients
=======================================================
Cas: 354-33-6
Name: ETHANE, PENTAFLUORO- (HFC-125)
Percent by Wt: 60.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 75-45-6
RTECS #: PA6390000
Name: METHANE, CHLORODIFLUORO- (HCFC-22)
Percent by Wt: 38.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM; 9596
Ozone Depleting Chemical: 2
------------------------------
Cas: 74-98-6
RTECS #: TX2275000
Name: PROPANE
Percent by Wt: 2.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 1000 PPM
ACGIH TLV: ASPHYXIANT; 9596
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50(RAT): 220,000PPM
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION OF HIGH CONCENTRATIONS OF VAPOR IS HARMFUL AND
MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS, OR DEATH. INTENTIONAL MISUES
OR DELIBERATE INHALATION MAY CAUSE DEATH WITHOUT WARNING. VAPOR REDUCES
OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN AIR. LIQUID CONTACT CAN
CAUSE FROSTBITE.
Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR
GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Signs And Symptions Of Overexposure: SKIN CONTACT MAY CAUSE FROSTBITE FROM
EXPOSURE TO THE LIQUID. INHALATION MAY INCLUDE NONSPECIFIC DISCOMFORT, SUCH
AS NAUSEA, HEADACHE, OR WEAKNESS OR TEMPORARY NERVOUS SYSTEM DEPRESSION WITH
ANESTHETI C EFFECTS SUCH AS DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION
AND LOSS OF CONSCIOUSNESS.
Medical Cond Aggravated By Exposure: INDIVIDUALS WITH PREEXISTING DISEASES OF
THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED
SUSCEPTIBILITY TO THE TOXICITY OF INCREASED EXPOSURES.
First Aid: INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. KEEP PERSON CALM. IF
NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. CALL DOCTOR. SKIN: FLUSH AREA WITH LUKEWARM WATER . DO NOT USE HOT
WATER. IF FROSTBITE HAS OCCURRED, CALL A PHYSICIAN. EYES: IMMEDIATELY FLUSH
WITH PLENTY OF WATER FOR AT LEAST 15 MIN. CALL DOCTOR. INGESTION: NOT A
PROBABLE ROUTE. HOWEVER, IN CASE OF ACCIDENTAL INGESTION, CALL DOCTOR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: VENTILATE AREA, ESPECIALLY LOW/ENCLOSED PLACES WHERE
HEAVY VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. USE SELF- CONTAINED BREATHING
APPARATUS IF LARGE SPILL OR LEAK OCCURS. REVIEW FIRE FIGHTING MEASURE S AND
HANDLING SECTIONS BEFORE PROCEEDING WITH CLEAN-UP.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS FOR
REPORTING RELEASES.
Handling And Storage Precautions: STORE IN A CLEAN, DRY PLACE. DO NOT HEAT
ABOVE 52C (126F). AVOID PROLONGED OR REPEATED EXPOSURE.
Other Precautions: AVOID BREATHING VAPORS OR MIST. AVOID CONTACT WITH EYES OR
SKIN. USE WITH SUFFCIENT VENTILATION TO KEEP EMPLOYEE EXPOSURE BELOW THE
RECOMMENDED LIMIT.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: WILL NOT BURN
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: USE MEDIA APPROPRIATE FOR SURROUNDING MATERIAL.
Fire Fighting Procedures: SELF-CONTAINED BREATHING APPARATUSIS REQUIRED IF
CYLINDERS RUPTURE AND CONTENTS ARE RELEASED UNDER FIRE CONDITIONS. USE WATER
TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CYLINDERS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR.
=======================================================
Control Measures
=======================================================
Respiratory Protection: SELF-CONTAINED BREATHING APPARATUS IS REQUIRED IF LARGE
RELEASE OCCURS.
Ventilation: LOCAL EXHAUST IF LARGE AMOUNTS ARE RELEASED. MECHANICAL
VENTILATION SHOULD BE USEDD IN LOW/ENCLOSED PLACES.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: CHEMICAL SPLASH GOGGLES.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: NOTE TO PHYSICIAN: BECAUSE OF POSSIBLE
DISTURBANCES OF CARDIAC RHYTHM, CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE,
SHOULD ONLY BE USED WITH SPECIAL CAUTION.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: G3
Boiling Point: =-49.2C, -56.4F
M.P/F.P Text: UNKNOWN
Vapor Pres: 193 PSIA
Spec Gravity: 1.152 GM/CC
Evaporation Rate & Reference: >1 (CCL4=1)
Solubility in Water: UNKNOWN
Appearance and Odor: CLEAR, COLORLESS LIQUIFIED GAS, ETHER (SLIGHT) ODOR.
Percent Volatiles by Volume: 100
Corrosion Rate: UNKNOWN
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Materials To Avoid: INCOMPATIBLE W/ALKALI OR ALKALINE EARTH METALS- POWEDERED
AL, ZN, BE, ETC.
Hazardous Decomposition Products: HYDROCHLORIC & HYDROFLUORIC ACID & POSSIBLE
CARBONYL HALIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: POLYMERIZATION WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ETHANE, PENTAFLUORO: INHALATION 4 HOUR ALC:
>709,000 PPM IN RATS. SINGLE, HIGH INHALATION EXPOSURE CAUSED LETHARGY,
DECREASED ACTIVITY, LABORED BREATHING AND WEIGHT LOSS. WEAK CARDIAC
SENSITIZATION EF FECT, A POTENTIALLY FATAL DISTURBANCE OF HEART RHYTHM CAUSED
BY A HEIGHTENED SENSITIVITY TO THE ACTION OF EPINEPHRINE.
LOWEST-OBSERVED-ADVERSE-EFFECT-LEVEL FOR CARDIAC SENSITIZATION: 100,000 PPM.
MET HANE, CHLORODIFLUORO: THE COMPOUND IS A SKIN IRRITANT AND A SLIGHT EYE
IRRITANT, BUT IS NOT A SKIN SENSITIZER IN ANIMALS. EFFECTS FROM SINGLE HIGH
EXPOSURES INCLUDE CENTRAL NERVOUS SYSTEM DEPRESSION, ANESTHESIA, RAPID
BREATHING, ETC.
=======================================================
Ecological Information
=======================================================
Ecological: AQUATIC TOXICITY: HCFC-22 48 HOUR EC50 - DAPHNIA MAGNA: 433 MG/L.
=======================================================
MSDS Transport Information
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Transport Information: DOT/IMO: LIQUEFIED GAS, NOS (CHLORODIFLUOROMETHANE AND
PENTAFLUOROETHANE), HAZARD CLASS 2.2, UN3163, LABEL NONFLAMMABLE GAS.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: TITLE III HAZARD CLASSIFICATIONS SECTION 311,312-
ACUTE, YES. CHRONIC, NO. FIRE, NO. REACTIVITY, NO. PRESSURE, YES. SARA
EXTREMELY HAZARDOUS SUBSTANCE: NO. METHANE, CHLORODIFLUORO- (HCFC-22): DI
SCLOSURE AS A TOXIC CHEMICAL IS REQUIRED UNDER SECTION 313 OF TITLE III OF
THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372.
Federal Regulatory Information: TSCA INVENTORY STATUS: REPORTED/INCLUDED.
=======================================================
Other Information
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Other Information: CAUTION: DO NOT USE IN MEDICAL APPLICATIONS INVOLVING
PERMANENT IMPLANTATION IN THE HUMAN BODY.
=======================================================
Transportation Information
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Trans ID NO: 155554
MSDS NAME: SUVA HP80 (R402A)
MSDS Prepared Date: 03/23/1999
Review Date: 12/12/2000
Tech Entry NOS Shipping Nm: CHLORODIFLUOROMETHANE AND PENTAFLUOROETHANE
Multiple KIT Number: 0
Unit Of Issue: CY
Type Of Container: CYLINDER
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: IID
Symbols: G
DOT Proper Shipping Name: LIQUEFIED GAS, N.O.S.
Hazard Class: 2.2
UN ID Num: UN3163
Label: NON-FLAMMABLE GAS
Packaging Exception: 306
Non Bulk Pack: 304
Bulk Pack: 314,315
Max Qty Pass: 75 KG
Max Qty Cargo: 150 KG
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: IZS
IMO Proper Shipping Name: LIQUEFIED GAS, N.O.S. o
IMDG Page Number: 2155-1
UN Number: 3163
UN Hazard Class: 2(2.2)
IMO Packaging Group: -
Subsidiary Risk Label: -
EMS Number: 2-09
MED First Aid Guide NUM: 620
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: PDH
IATA UN ID Num: 3163
IATA Proper Shipping Name: LIQUEFIED GAS, N.O.S. *
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
Packing Note Passenger: 200
Max Quant Pass: 75 KG
Max Quant Cargo: 150 KG
Packaging Note Cargo: 200
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: PDE
AFI Symbols: *
AFI Proper Shipping Name: LIQUEFIED GAS, N.O.S.
AFI Hazard Class: 2.2
AFI UN ID NUM: UN3163
Special Provisions: P5
Back Pack Reference: A6.3, A6.5
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SUVA HP80 (R402A)
Company: E.I. DUPONT DE NEMOURS & CO
Street: 1007 MARKET STREET
City: WILMINGTON DE
Zipcode: 19898
Health Emergency Phone: 800-441-3637
Label Required IND: Y
Date Of Label Review: 12/12/2000
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: N/P. INHALATION OF HIGH CONCENTRATIONS
OF VAPOR IS HARMFUL AND MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS, OR
DEATH. INTENTIONAL MISUES OR DELIBERATE INHALATION MAY CAUSE DEATH WI THOUT
WARNING. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN
AIR. LIQUID CONTACT CAN CAUSE FROSTBITE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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