DSM DESOTECH, INC -- SOMOS PHOTOPOLYMER 8100 SERIES, 8100, 8110, 8
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Material Safety Data Sheet
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MSDS Num: CKWPF
MSDS NAME: SOMOS PHOTOPOLYMER 8100 SERIES, 8100, 8110, 8120
Responsible Party
Name: DSM DESOTECH, INC
Address: 1122 ST CHARLES ST
City: ELGIN IL 60120-5000
Info Phone: 708-697-0400/708-468-7726
Emergency Phone Number: 847-697-0401
Preparer's Name: W. J. NEBE
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DSM DESOTECH, INC
Address: 1122 ST CHARLES ST
City: ELGIN IL 60120-5000
Phone: 708-697-0400/708-468-7726
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Ingredients
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Name: *** PROPRIETARY ***
-----------------------------
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: THE LIQUID PHOTOPOLYMER MIXTURE HAS NOT BEEN TESTED. THE
LIQUID CONTAINS COMPONENTS THAT CAN CAUSE SKIN IRRITATION, SKIN
SENSITIZATION, EYE IRRITATION AND RESPIRATORY TRACT IRRITATION. SINCE THIS
MIX TURE HAS NOT BEEN TESTED AS A WHOLE FOR ALL ROUTES OF EXPOSURE TO
DETERMINE ITS HAZARD, TOXICITY INFORMATION IS PROVIDED FOR EACH HAZARDOUS
COMPONENT OF THE MIXTURE TO MEET THE REQUIREMENTS OF OSHA'S HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200). EPOXIES: INHALATION MAY CAUSE
IRRITATION TO NOSE, THROAT, AND RESPIRATORY TRACT. EYE CONTACT: MAY CAUSE
IRRITATION. SKIN CONTACT: MAY CAUSE IRRITATIO N AND/OR SKIN (EFTS OF
OVEREXPOS).
Explanation Of Carcinogenicity: NONE OF THE COMPONENTS PRESENT IN THIS MATERIAL
AT CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1% ARE LISTED BY IARC, NTP, OSHA
OR ACGIH AS A CARCINOGEN.
Signs And Symptions Of Overexposure: HLTH HAZ (CONT'D): SENSITIZATION WITH
ALLERGIC REACTION EVIDENCED BY SKIN RASHES OR HIVES. ACRYLATES: INHALATION OF
MISTS, AEROSOLS OR VAPORS GENERATED AT ELEVATED TEMPERATURES CAN CAUSE
RESPIRATORY T RACT IRRITATION. EYE CONTACT MAY CAUSE SLIGHT TO MODERATE
IRRITATION WITH BURNING SENSATION, TEARING, REDNESS OR SWELLING. SKIN CONTACT
MAY CAUSE IRRITATION WITH REDNESS OR SWELLING. SOME ACRYLATES AR E KNOWN TO
PRODUCE ALLERGIC RASHES AND SENSITIZATION REACTIONS. PROLONGED CONTACT MAY
CAUSE BLISTER FORMATION. IRRITATION MAY NOT OCCUR IMMEDIATELY AND CONTACT CAN
GO UNNOTICED. SOME ACRYLATE MATERIAL CAN BE ABSORBED THROUGH (TRANSPORT)
Medical Cond Aggravated By Exposure: PERSON WITH PRE-EXISTING SKIN CONDITIONS
OR ALLERGIES MAY HAVE INCREASED SUSCEPTIBILITY TO THE EFFECTS OF OVEREXPOSURE
TO THE LIQUID PHOTOPOLYMER.
First Aid: INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A
PHYSICIAN. SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP
AND WATER. EXPOSURE MAY GO UNNOTICED SINCE SKIN IRRITATION MAY NOT OCCUR
IMMEDIATELY. WASH CONTAMINATED CLOTHING BEFORE REUSE. EYE CONTACT: IN CASE OF
CONTACT, IMMEDIATELY FLUSH EYES W ITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. CALL A PHYSICIAN. INGESTION: ALL CASES OF INGESTION SHOULD BE
REFERRED IMMEDIATELY TO A PHYSICIAN OR POISON CONTROL CENTER. VOMITING SHOULD
BE INDUCED ONLY AS ADVISED AND BY THE MEANS SPECIFIED.
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Handling and Disposal
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Spill Release Procedures: REVIEW FIRE FIGHTING AND HANDLING SECTIONS OF THIS
MSDS BEFORE PROCEEDING WITH CLEAN UP. USE APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT DURING CLEAN UP. INITIAL CONTAINMENT: REMOVE SOURCE OF HEAT, SPAR
KS, FLAME, IMPACT, FRICTION OR ELECTRICITY. DIKE SPILL. PREVENT MATERIAL FROM
ENTERING SEWERS, WATERWAYS, OR LOW AREAS. SPILL CLEAN UP: SOAK UP WITH
SAWDUST, SAND, OIL DRY OR OTHER (WASTE DISP METH)
Waste Disposal Methods: TREATMENT, STORAGE, TRANSPORTATION, AND DISPOSAL MUST
BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL, AND LOCAL
REGULATIONS. SPILL PROCEDURE (CONT'D): ABSORBENT MATERIAL. LIQUID SOLIDIFI
ES WHEN EXPOSED TO SUNLIGHT OR ANOTHER ULTRAVIOLET LIGHT SOURCE. SOLIDIFY
WASTE MATERIAL BEFORE DISP OSAL.
Handling And Storage Precautions: AVOID CONTACT WITH EYES, SKIN OR CLOTHING.
PERFORM SANDING OR MACHING OPERATIONS IN WELL-VENTILATED AREA. EXPOSE FRESHLY
CUT SURFACES TO LIGHT IN ORDER TO COMPLETE THE SURFACE CURE. KEEP AWAY FROM
HEA T, SPARKS, OR FLAME. DO NOT ALLOW PRODUCT TO CONTACT OPEN FLAME OR
ELECTRICAL HEATING(OTHER PREC)
Other Precautions: HNDLG/STOR (CONT'D): ELEMENTS BECAUSE DANGEROUS
DECOMPOSITION PRODUCTS MAY FORM. OPEN CONTAINERS UNDER YELLOW LIGHT ONLY.
KEEP CONTAINER IN COOL PLACE. KEEP CONTAINER TIGHTLY CLOSED. DO NOT STORE OR
E AT FOOD, DRINK OR TOBACCO IN AREAS WHERE THEY MAY BECOME CONTAMINATED WITH
THIS MATERIAL.
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Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point: =163.C, 325.4F
Flash Point Text: SEE FIRE/EXPLOSN
Lower Limits: NOT TESTED.
Upper Limits: NOT TESTED.
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). USE ANY
AVAILABLE EXTINGUISHING MEDIA (MFR).
Fire Fighting Procedures: KEEP PERSONNEL REMOVED AND UPWIND OF FIRE. WEAR NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS. WEAR FULL PROTECTIVE EQUIPMENT.
COOL TANK/CONTAINER WITH WATER SPRAY.
Unusual Fire/Explosion Hazard: RUNAWAY POLYMERIZATION MAY CAUSE CONTAINERS TO
RUPTURE OR EXPLODE. **OTHER PMCC FLASHPOINTS: SOMOS 8100: 163C. SOMOS 8110:
NOT TESTED. SOMOS 8120: 130C.
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Control Measures
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Respiratory Protection: A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN (FP N).
Ventilation: USE ONLY WITH ADEQUATE VENTILATION. OPEN CONTAINERS AND HANDLE
UNDER YELLOW LIGHT ONLY.
Protective Gloves: NITRILE OR OTHER CHEMICAL RESISTANT GLOVES TO AVOID SKIN
CONTACT (OTHER INFO)
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N). WEAR SAFETY
GLASSES (SUP DATA)
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N).
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: EYE PROTECTION (CONT'D): WHEN HANDLING LIQUID
MATERIAL AND WHEN SANDING OR CUTTING CURED MATERIAL (MFR).
=======================================================
Physical/Chemical Properties
=======================================================
Vapor Pres: <1 MM HG @ 20C (68F).
Vapor Density: >1AIR=1.0
Spec Gravity: 1.13
Viscosity: 550-650 CPS @ 30C (86F).
Solubility in Water: SLIGHTLY SOLUBLE.
Appearance and Odor: TRANSPARENT AMBER COLORED LIQUID. ODOR: ETHER (MILD).
Percent Volatiles by Volume: <1 WT%
=======================================================
Reactivity Data
=======================================================
Stability Indicator: NO M A (ECOLOGICAL INFORMATION)
Stability Condition To Avoid: CHEMICAL STABILITY: UPON EXPOSURE TO ULTRAVIOLET
LIGHT, THIS PRODUCT GENERATES FREE RADICALS. THESE FREE RADICALS QUICKLY
REACT IN ONE OF THREE WAYS: (1) REACTION (MATLS TO AVOID).
Materials To Avoid: INCOMPATIBLE WITH STRONG OXIDIZERS, ACIDS OR BASES. STAB
CONDITION (CONT'D): WITH A MONOMER TO FORM A GROWING POLYMER (2) CHAIN
TRANSFER TO FORM DIFFERENT FREE RADICAL (3) CHAIN TERMINATION BY: REACTION
WITH A MONOMER TO FO
Hazardous Decomposition Products: N/P.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: POLYMERIZATION CAN OCCUR. CONDITIONS
LEADING TO POLYMERIZATION ARE EXPOSURE TO ACIDS, BASES, LIGHT OR EXCESSIVE
HEAT.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ANIMAL DATA: EPOXIES: THESE MATERIALS EXHIBIT
MUTAGENIC ACTIVITY IN SEVERAL IN VITRO TEST SYSTEMS. ACRYLATES: AT LEAST ONE
ACRYLATE POTENTIALLY USED IN THIS PRODUCT WAS FOUND TO PRODUCE GENETIC DAMAGE
IN MAMMALIAN CELL CULTURES. INITIATORS: AT LEAST ONE INITIATOR POTENTIALLY
USED IN THE PRODUCT HAS BEEN FOUND TO BE MUTAGENIC IN BACTERIA, BUT WAS
INACTIVE IN MOUSE IN VIVO MICRONUCLEUS TEST. EXPOSUR E GUIDELINE/LIMITS:
SOMOS PHOTOPOLYMER 8100 SERIES: PEL (OSHA): NONE ESTABLISHED. TLV (ACGIH):
NONE ESTABLISHED. (FED REG).
=======================================================
Ecological Information
=======================================================
Ecological: NO INFORMATION AVAILABLE. MATERIALS TO AVOID (CONT'D): POLYMER,
REACTION WITH OXYGEN TO FORM AN INACTIVE RADICAL, OR REACTION WITH AN
INHIBITOR TO FORM INACTIVE PRODUCTS. DUE TO HIGH CONCENTRATION OF MONOMER
AND OF OXYGEN PRESENT, IT IS EXPECTED THAT FREE RADICALS ARE VERY SHORT LIVED
IN THESE SOLUTIONS. NO SIGNIFICANT HEALTH HAZARD ASSOCIATED WITH FREE
RADICAL EXPOSURE IS EXPECTED AS LONG AS APP ROPRIATE INDUSTRIAL HYGIENE
PRACTICES, SUCH AS AVOIDING SKIN CONTACT AND USE OF ADEQUATE VENTILATION, ARE
IN PLACE WHEN HANDLING SOMOS FORMULATIONS.
=======================================================
MSDS Transport Information
=======================================================
Transport Information: SHIPPING INFORMATION: D.O.T.: NOT REGULATED. EFTS OF
OVEREXPOS (CONT'D): THE SKIN. CYCLOALIPHATIC EPOXY RESINS: MAY CAUSE SLIGHT
SKIN IRRITATION WITH ITCHING & REDNESS OR EYE IRRIT W/PAIN, REDNESS,
& SWELLING OF CONJUNCTIVA. MAY CAUSE SKIN SENSITIZATION & ALLERGIC
SKIN RASHES IN SUSCEPTIBLE INDIVIDUALS. MODERATELY TOXIC BY INGESTION &
WILL CAUSE ABDOMINAL DISCOMFORT, NAUSEA, VOMIT & DIARRHEA. NO OTHER
TOXICITY DATA ARE AVAILABLE. POLYOL: TRANSIENT IRRIT IS POSSIBLE, BUT NO
SPECIFIC HAZARDS ARE EXPECTED FROM EXPOSURE TO POLYOL. INITIATORS: TOXICITY
CHARACTERISTICS OF THE INITIATORS HAVE NOT BEEN FULLY ESTABLISHED. (STATE
REGS)
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: COMPOUNDS WHICH REQUIRE DISCLOSURE AS A TOXIC
CHEMICAL AS UNDER SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: ANTIMONY COMPOUNDS (UPPER
BOUN DARY CONCENTRATIONS: 2.0%). ADDITIONAL INFORMATION: MEDICAL USE:
CAUTION: DO NOT USE IN MEDICAL APPLICATIONS INVOVING PERMANENT IMPLANTATION
IN THE HUMAN BODY. NFPA, NPCA-: NFPA RATINGS FOR THIS P RODUCT HAVE NOT BEEN
DETERMINED AT THIS TIME. THE DATA IN THIS MATERIAL SAFETY DATA SHEET RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN
COMBINATION WITH ANY OT HER MATERIAL OR IN ANY PROCESS.
Federal Regulatory Information: TSCA INVENTORY STATUS: IN COMPLIANCE WITH TSCA
INVENTORY REQUIREMENTS FOR COMMERCIAL PURPOSES. TOX INFORMATION, (CONT'D):
EXPOS GUIDELINE COMMENTS: EXPOSURE LIMITS FOR COMPONENTS OF SOMOS 8100 HAVE
NO T BEEN ESTABLISHED. APPLICABLE EXPOSURE LIMITS FOR NUISANCE DUST MAY BE
APPROPRIATE FOR DUSTS GENERATED FROM GRINDING, SANDING OR CUTTING OF FINAL
CURED PRODUCT. STATE INFORMATION (CONT'D): EXPECTED T O CAUSE SKIN
IRRITATION. SANDLING AND/OR MACHINING CURED PRODUCT MAY CREATE DUST OR EXPOSE
INTERIOR REGIONS OF THE PRODUCT THAT ARE PARTIALLY CURED.
State Regulatory Information: N/P.TRANSPORT (CONT'D): ONE OR MORE OF THE
INITIATORS MAY CAUSE EYE OR SKIN IRRITATION OR SKIN SENSITIZATION WITH
ALLERGIC RESPONSE SUCH AS A RASH. INGEST OF LARGE AMOUNT MAY AFFECT THE
NERVOUS SYSTEM . POTENTIAL HEALTH EFFECTS: UPON EXPOSURE TO ULTRAVIOLET
LIGHT, THE 8100 SERIES COMPOSITION WILL HARDEN & POLYMERIZE. THE HARDENED
MATERIAL HAS A FAINT ODOR THAT IS SIMILAR IN SMELL TO ALMOND OIL. IT IS
BELIEVED THAT ODOR IS THAT OF BENZALDEHYDE GENERATED AS A REACTION PRODUCT
OF ONE OF THE PHOTOIN ITIATORS. HANDLING ARTICLES THAT HAVE BEEN MADE FROM
PROPERLY EXPOSED, CLEANED & THERMALLY TREATED SOMOS PHOTOPOLYMER IS NOT
(FEDERAL INFO)
=======================================================
Other Information
=======================================================
Other Information: PROTECTIVE GLOVES (CON'T): WHEN HANDLING PARTIALLY CURED
FABRICATED OBJECTS IN THE 'GREEN' STATE OF CURE (AFTER INITIAL LASER CURE).
THE OBJECT MAY BE HANDLED WITHOUT GLOVES AFTER THE OBJECT HAS BEEN PROPERLY
TREATED TO PREVENT SKIN CONTACT WITH LIQUID PHOTOPOLYMER. UNCURED LIQUID
PHOTOPOLYMER CAN BE REMOVED FROM THE OBJECT IN THE PARTIALLY CURED GREEN
STATE BY THOROUGHLY WASHING THE OBJECT WITH S OLVENT FOLLOWED BY POST
EXPOSURE TO UV LIGHT AND/OR AN OVEN BAKE AT TEMPERATURES ABOVE 130C. : HEALTH
-1, FLAMMABILITY -2, REACTIVITY -0, PERSONAL PROTECTION -X.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SOMOS PHOTOPOLYMER 8100 SERIES, 8100, 8110, 8120
Company: DSM DESOTECH, INC
Street: 1122 ST CHARLES ST
City: ELGIN IL
Zipcode: 60120-5000
Health Emergency Phone: 847-697-0401
Label Required IND: Y
Date Of Label Review: 12/12/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: MIXTURE HAS NOT BEEN TESTED. COMPONENTS: ACUTE: INHAL
MAY CAUSE IRRIT TO NOSE, THROAT, RESP TRACT. INHAL OF VAPORS GENERATED AT
ELEVATED TEMP CAN CAUSE RESP TRACT IRRIT. EYE: MAY CAUSE SLIGHT TO MODE RATE
IRRIT W/BURNING SENSATION,REDNESS,SWELLING,SWELLING OF CONJUNCTIVA. SKIN: MAY
CAUSE IRRIT W/REDNESS, SWELLING &/OR SKIN SENSIT W/ALLERGIC RXN, SKIN
RASHES,HIVES. SOME ACRYLATE MATL CAN BE ABSORBE D THRU SKIN. PROLONGED
CONTACT MAY CAUSE BLISTER FORMATION. IRRIT MAY NOT OCCURIMMED & CONTACT
CAN GO UNNOTICED. INGEST: MODERATELY TOXIC. WILL CAUSE ABDOMINAL DISCOMFORT,
NAUS/VOMIT/DIARR AND MAY AF FECT THE NERVOUS SYS. CHRONIC: SENSITIZATION
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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