PRAXAIR, INC. -- SULFUR HEXAFLUORIDE
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CKWHV
MSDS NAME: SULFUR HEXAFLUORIDE
Responsible Party
Name: PRAXAIR, INC.
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06810-5113
Info Phone: 800-PRAXAIR/800-645-4633
Emergency Phone Number: 800-645-4633
Resp. Party Other MSDS No.: P-4657-C
Preparer's Name: NOT PROVIDED
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: PRAXAIR, INC.
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06810-5113
Phone: 800-772-9247; 800-PRAXAIR
=======================================================
Ingredients
=======================================================
Cas: 2551-62-4
RTECS #: WS4900000
Name: SULFUR HEXAFLUORIDE
> Wt: 99.
Other REC Limits: NOT PROVIDED
OSHA PEL: 6000 MG/M3;1000 PPM
ACGIH TLV: 5970 MG/M3;1000 PPM
ACGIH STEL: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NOT PROVIDED
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE:
INHALATION?ASPHYXIANT. HIGH CONCENTRATIONS CAN CAUSE HEADACHE, DROWSINESS,
DIZZINESS, EXCITATION, EXCESS SALIVATION, VOMITING, AND UNCONSCIOUSNESS. LACK
OF OX YGEN CAN KILL. SKIN CONTACT?NO HARM EXPECTED FROM VAPOR. LIQUID MAY
CAUSE FROSTBITE. SWALLOWING?AN UNLIKELY ROUTE OF EXPOSURE, BUT FROSTBITE OF
THE LIPS AND MOUTH MAY RESULT FROM CONTACT WITH THE LI QUID. THIS PRODUCT IS
A GAS AT NORMAL TEMPERATURE AND PRESSURE. EYE CONTACT?NO HARM EXPECTED FROM
VAPOR. LIQUID MAY CAUSE FROSTBITE. EFFECTS OF REPEATED (CHRONIC)
OVEREXPOSURE: NO HARM EXPECTED.
Explanation Of Carcinogenicity: SULFUR HEXAFLUORIDE IS NOT LISTED BY NTP, OSHA,
OR IARC.
Signs And Symptions Of Overexposure: INHALATION? HIGH CONCENTRATIONS CAN CAUSE
HEADACHE, DROWSINESS, DIZZINESS, EXCITATION, EXCESS SALIVATION, VOMITING, AND
UNCONSCIOUSNESS. LACK OF OXYGEN CAN KILL. SKIN CONTACT? LIQUID MAY CAUSE
FROSTBI TE. SWALLOWING? FROSTBITE OF THE LIPS AND MOUTH MAY RESULT FROM
CONTACT WITH THE LIQUID. EYE CONTACT? LIQUID MAY CAUSE FROSTBITE.
Medical Cond Aggravated By Exposure: THE TOXICOLOGY AND THE PHYSICAL AND
CHEMICAL PROPERTIES OF SULFUR HEXAFLUORIDE SUGGEST THAT OVEREXPOSURE IS
UNLIKELY TO AGGRAVATE EXISTING MEDICAL CONDITIONS.
First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT
BREATHING. IF BREATHING IS DIFFICULT, QUALIFIED PERSONNEL MAY GIVE OXYGEN.
CALL PHYSICIAN. SKIN CONTACT: FOR EXPOSURE TO LIQUID, IMM EDIATELY WARM AREA
WITH WARM WATER NOT TO EXCEED 105F (41C). IN CASE OF MASSIVE EXPOSURE, REMOVE
CLOTHING WHILE SHOWERING WITH WARM WATER. CALL A PHYSICIAN. SWALLOWING: THIS
PRODUCT IS A GAS. EYE CONT ACT: FOR EXPOSURE TO LIQUID, IMMEDIATELY FLUSH
EYES THOROUGHLY WITH WARM WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN TO
ENSURE ALL SURFACES ARE FLUSHED THOROUGHLY. SEE A PHYSICIAN, PREFERABLY AN
OPHTHALMOLOGIST, IMMEDIATELY.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: CAUTION! LIQUID AND GAS UNDER PRESSURE. IMMEDIATELY
EVACUATE ALL PERSONNEL FROM DANGER AREA. USE SELF-CONTAINED BREATHING
APPARATUS WHERE NEEDED. SHUT OFF FLOW IF WITHOUT RISK. VENTILATE AREA OR MOVE
CYLINDER TO WELL-VENTILATED AREA. BEFORE ENTERING AREA, ESPECIALLY CONFINED
AREA, CHECK FOR SUFFICIENT OXYGEN WITH AN APPROPRIATE DEVICE. PREVENT RUNOFF
FROM CONTAMINATING SURROUNDING ENVIRONMENT.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: PREVENT WASTE FROM CONTAMINATING THE SURROUNDING
ENVIRONMENT. KEEP PERSONNEL AWAY. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE
CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIAN
CE WITH FEDERAL, STATE AND LOCAL REGULATIONS. IF NECESSARY CALL YOUR LOCAL
SUPPLIER FOR ASSISTANCE.
Handling And Storage Precautions: STORE AND USE WITH ADEQUATE VENTILATION.
FIRMLY SECURE CYLINDERS UPRIGHT TO KEEP THEM FROM FALLING . SCREW VALVE
PROTECTION CAP FIRMLY IN PLACE BY HAND. STORE ONLY WHERE TEMPERATURE WILL NOT
EXCEED 12 5?F (52?C). STORE FULL AND EMPTY CYLINDERS SEPARATELY. USE A
FIRST-IN, FIRST-OUT INVENTORY SYSTEM.
Other Precautions: PROTECT CYLINDERS FROM DAMAGE. USE A SUITABLE HAND TRUCK TO
MOVE CYLINDERS. NEVER ATTEMPT TO LIFT A CYLINDER BY ITS CAP. NEVER INSERT AN
OBJECT (E.G., WRENCH, SCREWDRIVER, PRY BAR) INTO CAP OPENINGS; DOING SO MAY
DAMAGE THE VALVE AND CAUSE A LEAK. USE AN ADJUSTABLE STRAP WRENCH TO REMOVE
CAPS. OPEN VALVE SLOWLY.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: SULFUR HEXAFLUORIDE CANNOT CATCH FIRE. USE MEDIA
APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures: CAUTION! CYLINDER UNDER PRESSURE. EVACUATE PERSONNEL
FROM AREA. IMMEDIATELY DELUGE CYLINDERS WITH WATER FROM MAXIMUM DISTANCE
UNTIL COOL, THEN MOVE THEM AWAY FROM FIRE AREA IF WITHOUT RISK. SELF-CONTA
INED BREATHING APPARATUS MAY BE REQUIRED BY RESCUE WORKERS. ON-SITE FIRE
BRIGADES MUST COMPLY WITH OSHA 29 CFR 1910.156.
Unusual Fire/Explosion Hazard: SULFUR HEXAFLUORIDE CANNOT CATCH FIRE. HEAT OF
FIRE CAN BUILD PRESSURE IN CYLINDER AND CAUSE IT TO RUPTURE. NO PART OF
CYLINDER SHOULD BE SUBJECTED TO A TEMPERATURE HIGHER THAN 125?F (52?C).
SULFUR HE XAFLUORIDE CYLINDERS ARE EQUIPPED WITH A PRESSURE RELIEF DEVICE.
(EXCEPTIONS MAY EXIST WHERE AUTHORIZED BY DOT.)
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE AIR-SUPPLIED RESPIRATORS WHERE LOCAL AND/OR GENERAL
EXHAUST VENTILATION ARE INSUFFICIENT TO KEEP WORKER'S EXPOSURE BELOW TLV. USE
FULL-FACE, SELF-CONTAINED BREATHING APPARATUS IN A POSITIVE PRESS URE DEMAND
MODE IN CONFINED SPACES OR IN OXYGEN DEFICIENT ATMOSPHERES. RESPIRATORY
PROTECTION USE MUST CONFORM WITH OSHA RULES AS SPECIFIED IN 29 CFR 1910.134
Ventilation: USE A LOCAL EXHAUST SYSTEM, IF NECESSARY, TO CONTROL THE
CONCENTRATION OF THIS PRODUCT IN THE WORKER'S BREATHING ZONE.
Protective Gloves: WEAR WORK GLOVES WHEN HANDLING CYLINDERS.
Eye Protection: WEAR SAFETY GLASSES WHEN HANDLING CYLINDERS. OSHA 29CFR 133.
Other Protective Equipment: WEAR METATARSAL SHOES FOR CYLINDER HANDLING. SELECT
IN ACCORDANCE WITH OSHA 29 CFR1910.132 AND 1910.133. REGARDLESS OF PROTECTIVE
EQUIPMENT, NEVER TOUCH LIVE ELECTRICAL PARTS.
Work Hygienic Practices: NOT PROVIDED
Supplemental Safety and Health: NOTES TO PHYSICIAN: THERE IS NO SPECIFIC
ANTIDOTE. THIS PRODUCT IS INERT. TREATMENT OF OVER-EXPOSURE SHOULD BE
DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION. ABBREVIATION:
N/A=NOT APP LICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT PROVIDED. N/R=NOT
RELEVANT. N/D=NOT DETERMINED. N/E=NOT ESTABLISHED.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: G3
NRC/State LIC No: NOT RELEVANT
Boiling Point: =-63.7C, -83.F
B.P. Text: SUBLIMES
Melt/Freeze Pt: =-50.6C, -59.4F
M.P/F.P Text: 325 PSIA
Decomp Text: NOT PROVIDED
Vapor Pres: 16167 @ 70F
Vapor Density: 5.11
Spec Gravity: 0.385 LBS/FT3 (0.00617)
Evaporation Rate & Reference: HIGH (BUAC=1)`
Solubility in Water: NEGLIGIBLE
Appearance and Odor: COLORLESS GAS AT NORMAL TEMPERATURE AND PRESSURE.
Percent Volatiles by Volume: 100
Corrosion Rate: NOT PROVIDED
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: TEMPERATURES IN EXCESS OF 1472F (800C).
Materials To Avoid: EXPLODES VIOLENTLY IN CONTACT WITH DISILANE.
Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY PRODUCE TOXIC FUMES
OF FLUORIDES AND SULFUR OXIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
=======================================================
Toxicological Information
=======================================================
Toxicological Information: SULFUR HEXAFLUORIDE IS A SIMPLE ASPHYXIANT.
=======================================================
Ecological Information
=======================================================
Ecological: NO ADVERSE ECOLOGICAL EFFECTS EXPECTED. SULFUR HEXAFLUORIDE DOES
NOT CONTAIN ANY CLASS I OR CLASS II OZONE-DEPLETING CHEMICALS. SULFUR
HEXAFLUORIDE IS NOT LISTED AS A MARINE POLLUTANT BY DOT.
=======================================================
MSDS Transport Information
=======================================================
Transport Information: DOT/IMO SHIPPING NAME: SULFUR HEXAFLUORIDE. HAZARD
CLASS: 2.2. IDENTIFICATION NUMBER: UN 1080 PRODUCT RQ: NONE. SHIPPING
LABEL(S): NONFLAMMABLE GAS. PLACARD (WHEN REQUIRED): NONFLAMMABLE GAS.
SPECIAL SHIPPING INFORMATION: CYLINDERS SHOULD BE TRANSPORTED IN A SECURE
POSITION, IN A WELL-VENTILATED VEHICLE. CYLINDERS TRANSPORTED IN AN ENCLOSED,
NONVENTILATED COMPARTMENT OF A VEHICLE CAN PRESENT SERIO US SAFETY HAZARDS.
SHIPMENT OF COMPRESSED GAS CYLINDERS THAT HAVE BEEN FILLED WITHOUT THE
OWNER'S CONSENT IS A VIOLATION OF FEDERAL LAW [49 CFR 173.301(B)].
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: SARA: SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:
SECTIONS 302/304: REQUIRE EMERGENCY PLANNING BASED ON THRESHOLD PLANNING
QUANTITY (TPQ) AND RELEASE REPORTING BASED ON REPORTABLE QUANTITIES (RQ) OF
EXTREMELY HAZARDOUS SUBSTANCES (40 CFR PART 355): THRESHOLD PLANNING QUANTITY
(TPQ): NONE. EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): NONE. SECTIONS
311/312: IMMEDIATE: YES PRESSURE: YES DELAYED: NO REACTIVITY: NO FIRE: NO
SECTION 313: REQUIRES SUBMISSION OF ANNUAL REPORTS OF RELEASE OF TOXIC
CHEMICALS THAT APPEAR IN 40 CFR PART 372. SULFUR HEXAFLUORIDE DOES NOT
REQUIRE REPORTING UNDER SECTION 313.
Federal Regulatory Information: CERCLA: COMPREHENSIVE ENVIRONM
CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
OF 1980 (40 CFR PARTS 117 AND 302): REPORTABLE QUANTITY (RQ): NONE. TSCA:
TOXIC SUBSTANCES CONTROL ACT: SULFUR HEXAFLUORIDE IS LISTED ON THE TSCA
INVENTORY. OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION): 29 CFR
1910.119: PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: REQUIR ES
FACILITIES TO DEVELOP A PROCESS SAFETY MANAGEMENT PROGRAM BASED ON THRESHOLD
QUANTITIES (TQ) OF H IGHLY HAZARDOUS CHEMICALS. SULFUR HEXAFLUORIDE IS NOT
LISTED IN APPENDIX A AS A HIGHLY HAZARDOUS CHEMICAL.
State Regulatory Information: CALIFORNIA: THIS PRODUCT IS NOT LISTED BY
CALIFORNIA UNDER THE SAFE DRINKING WATER TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65). PENNSYLVANIA: THIS PRODUCT IS SUBJECT TO THE PENNSYLVANIA
WORKER AN D COMMUNITY RIGHT-TO-KNOW ACT (35 P.S. SECTIONS 7301-7320).
=======================================================
Other Information
=======================================================
Other Information: CAUTION! LIQUID AND GAS UNDER PRESSURE. CAN CAUSE RAPID
SUFFOCATION. MAY CAUSE FROSTBITE. MAY CAUSE DIZZINESS AND DROWSINESS.
SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED BY RESCUE WORKERS.
ODOR: NONE
=======================================================
Transportation Information
=======================================================
Trans ID NO: 155462
MSDS NAME: SULFUR HEXAFLUORIDE
MSDS Prepared Date: 10/01/1997
Review Date: 11/30/2000
Multiple KIT Number: 0
Unit Of Issue: CY
Type Of Container: CYLINDER
Additional Data: PROPER SHIPPING NAME, UN ID NUMBER, HAZARD CLASS, PER MSDS.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: NTF
DOT Proper Shipping Name: SULFUR HEXAFLUORIDE
Hazard Class: 2.2
UN ID Num: UN1080
Label: NONFLAMMABLE GAS
Packaging Exception: 306
Non Bulk Pack: 304
Bulk Pack: 314,315
Max Qty Pass: 75 KG
Max Qty Cargo: 150 KG
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: OFB
IMO Proper Shipping Name: SULPHUR HEXAFLUORIDE
IMDG Page Number: 2179
UN Number: 1080
UN Hazard Class: 2(2.2)
IMO Packaging Group: -
EMS Number: 2-09
MED First Aid Guide NUM: 620
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: XIS
IATA UN ID Num: 1080
IATA Proper Shipping Name: SULPHUR HEXAFLUORIDE
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
Packing Note Passenger: 200
Max Quant Pass: 75KG
Max Quant Cargo: 150KG
Packaging Note Cargo: 200
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: XIS
AFI Proper Shipping Name: SULPHUR HEXAFLUORIDE
AFI Hazard Class: 2.2
AFI UN ID NUM: UN1080
Special Provisions: P5
Back Pack Reference: A6.3, A6.5
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SULFUR HEXAFLUORIDE
Company: PRAXAIR, INC.
Street: 39 OLD RIDGEBURY RD
City: DANBURY CT
Zipcode: 06810-5113
Health Emergency Phone: 800-645-4633
Label Required IND: Y
Date Of Label Review: 11/30/2000
Status Code: A
MFG Label NO: NOT PROVIDED
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: NO
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: N/P. CAUTION! LIQUID AND GAS UNDER
PRESSURE. CAN CAUSE RAPID SUFFOCATION. MAY CAUSE FROSTBITE, DIZZINESS AND
DROWSINESS. FIRST AID: INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RES
PIRATION IF NOT BREATHING. IF BREATHINGIS DIFFICULT, GIVE OXYGEN. CALL
PHYSICIAN. SKIN CONTACT: IMMEDIATELY WARM AREA WITH WARM WATER. CALL A
PHYSICIAN. SWALLOWING: THIS PRODUCT IS A GAS. EYE CONTACT: IMMEDIATELY FLUSH
WITH WARM WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN TO ENSURE ALL
SURFACES ARE FLUSHED THOROUGHLY. SEE A PHYSICIAN, PREFERABLY AN
OPHTHALMOLOGIST, IMMEDIATELY.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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