LOCTITE CORPORATION -- PRISM 401 SURF-INSENSITIVE INST ADH, 40140
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Material Safety Data Sheet
=======================================================
MSDS Num: CKWLY
MSDS NAME: PRISM 401 SURF-INSENSITIVE INST ADH, 40140
Responsible Party
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Info Phone: 860-571-5100
Emergency Phone Number: 860-571-5100
Preparer's Name: STEPHEN REPETTO
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
=======================================================
Ingredients
=======================================================
Cas: 7085-85-0
RTECS #: UD3330000
Name: ETHYL CYANOACRYLATE
% low Wt: 90.
% high Wt: 95.
Other REC Limits: NONE
OSHA PEL: NONE
ACGIH TLV: 0.2 PPM TWA
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLY (METHYL METHACRYLATE)
% low Wt: 5.
% high Wt: 10.
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE
% low Wt: .1
% high Wt: .5
Other REC Limits: 2/4 MG/M3 TWA/STEL
OSHA PEL: 2 MG/M3 TWA
ACGIH TLV: 2 MG/M3 TWA
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: ORAL LD 50 > 5000 MG/KG (ESTIMATED)
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TOXICITY: SKIN CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY
AND STRONGLY. SKIN AND EYE IRRITANT. PRIMARY ROUTES OF ENTRY: NONE KNOWN.
SIGNS AND SYMPTOMS OF EXPOSURE: VAPOR IS IRRITATING TO EYES AND M UCOUS
MEMBRANES ABOVE TLV. PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAY
PRODUCE SYMPTOMS OF NON-ALLERGIC ASTHMA IN SENSITIVE INDIVIDUALS.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS ACUTE AND CHRONIC (FP
N).
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INGESTION: INGESTION IS NOT LIKELY. SEE SUPPLEMENTAL PAGE FOR
EMERGENCY PROCEDURES. INHALATION: REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST,
OBTAIN MEDICAL ATTENTION. SKIN CONTACT: SOAK IN WARM WATER. SEE
SUPPLEMENTAL PAGE FOR EMERGENCY PROCEDURES. EYE CONTACT: FLUSH WITH WATER.
SEE SUPPLEMENTAL PAGE FOR EMERGENCY PROCEDURES. SUPPLEMENT: INFORMATION
FOR FIRST AID AND CASUALTY ON TREATMENT FOR ADHESION OF HUMAN SKIN TO ITSELF
IF CAUSED BY CYANOACRYLATE ADHESIVES: CYANOACRYLATE ADHESIVE IS A VERY FAST
SETTING AND STRONG ADHESIVE. IT BONDS HUMAN TISSUE INCLUDING SKIN IN SECONDS.
EXPERIENCE HA S SHOWN THAT ACCIDENTS (ECOLOGICAL INFO)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE. SOAK UP WITH AN INERT
ABSORBENT.
Waste Disposal Methods: RECOMMENDED METHODS OF DISPOSAL: POLYMERIZE BY CONTACT
WITH WATER, ALCOHOLS, AMINES, ALKALIES. INCINERATE FOLLOWING EPA AND LOCAL
REGULATIONS. EPA HAZARDOUS NUMBER: NH - NOT A RCRA HAZARDOUS WASTE M
ATERIAL.
Handling And Storage Precautions: SAFE STORAGE: STORE BELOW 75 DEG. F. (CONTACT
LOCTITE CUSTOMER SERVICE 1-800-243-4874 FOR SHELF LIFE INFORMATION).
HANDLING: AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point: =65.6C, 150.F
Flash Point Text: 150 - 200F
Lower Limits: NOT AVAIL
Upper Limits: NOT AVAIL
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH-APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). HAZARDOUS PRODUCTS FORMED BY FIRE OR THERMAL
DECOMPOSITION: IRRITATING ORGANIC FRAGMENTS.
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: NITRILE OR POLYETHYLENE GLOVES. DO NOT USE COTTON.
Eye Protection: ANSI-APPROVED CHEMICAL SAFETY GOGGLES (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). SKIN: NITRILE OR POLYETHYLENE GLOVES AND APRONS. DO NOT
USE COTTON. SEE SUPPLEMENTAL PAGE FOR ADDITIONAL INFORMATION.
Supplemental Safety and Health: PRODUCT TYPE: CYANOACRYLATE ESTER. REVISION
NUMBER 0030. PHYSICAL AND CHEMICAL PROPERTIES (CONT): VOLATILE ORGANIC
COMPOUND (EPA METHOD 24): 68%, 714 GRAMS PER LITER. EST NFPA CODE: HEALTH
HAZ - 2 , FIRE HAZ - 2, REACTIVITY HAZ - 1, SPECIFIC HAZ - DOES NOT APPLY.
EST CODE: HEALTH HAZ - 2, FLAMMABILITY HAZ - 2.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >148.9C, 300.F
Vapor Pres: LESS THAN 0.2 MM
Vapor Density: APPROX. 3
Spec Gravity: 1.05
PH: DOES NOT APPLY
VOC Grams/Liter: 714
Evaporation Rate & Reference: NOT AVAILABLE.
Solubility in Water: POLYMERIZED BY WATER.
Appearance and Odor: WATER WHITE TO STRAW COLORED LIQUID; SHARP, IRRITATING
ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NOT AVAILABLE.
Materials To Avoid: POLYMERIZED BY CONTACT WITH WATER, ALCOHOLS, AMINES,
ALKALIES.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ESTIMATED DERMAL LD50: MORE THAN 2000 MG/KG.
INGREDIENT: ETHYL CYANOACRYLATE; LITERATURE REFERENCED TARGET ORGAN AND OTHER
HEALTH EFFECTS: ALLERGEN, IRRITANT, RESPIRATORY; CARCINOGEN: NTP - NO, IARC
- NO, OSHA - NO. INGREDIENT: POLY (METHYL METHACRYLATE); LITERATURE
REFERENCED TARGET ORGAN AND OTHER HEALTH EFFECTS: IRRITANT; CARCINOGEN: NTP -
NO, IARC - N/A, OSHA - NO. INGREDIENT: HYDROQUINONE; LITERATURE REFERENCED
TARGET ORGAN AND OTHER HEALTH EFFECTS: ACGIH ANIMAL CARCINOGEN, BLOOD, BONE
MARROW, CENTRAL NERVOUS SYSTEM, EYES, IMMUNE SYSTEM, IRRITANT, LIVER;
CARCINOGEN: NTP - NO, IARC - N/ A, OSHA - NO.
=======================================================
Ecological Information
=======================================================
Ecological: NO DATA AVAILABLE. FIRST AID (CONT): DUE TO CYANOACRYLATES ARE
HANDLED BEST BY PASSIVE, NONSURGICAL FIRST AID. TREATMENT OF SPECIFIC TYPES
OF ACCIDENTS ARE GIVEN BELOW. SKIN CONTACT: REMOVE EXCESS ADHESIVE. SOAK IN
WARM, SOAPY WATER. THE ADHESIVE WILL COME LOOSE FROM THE SKIN IN SEVERAL
HOURS. CURED ADHESIVE DOES NOT PRESENT HEALTH HAZARD EVEN WHEN BONDED TO
SKIN. AVOID CONTACT WITH CLOTHES, FABRICS, RAGS OR TISSUE. CONTACT WITH
THESE MATERIALS MAY CAUSE POLYMERIZATION. THE POLYMERIZATION OF LARGE AMOUNTS
OF ADHESIVE WILL GENERATE HEAT CAUSING SMOKE, SKIN BURNS AND STRONG,
IRRITATING VAPO RS. WEAR NITRILE OR (SARA III)
=======================================================
MSDS Transport Information
=======================================================
Transport Information: D.O.T. (49 CFR 172) DOMESTIC GROUND TRANSPORT. PROPER
SHIPPING NAME: UNRESTRICTED (NOT MORE THAN 450 LITERS); COMBUSTIBLE LIQUIDS,
N.O.S. (CYANOACRYLATE ESTER) (MORE THAN 450 LITERS). HAZARD CLASS OR
DIVISION: UNRESTRICTED (NOT MORE THAN450 LITERS) COMBUSTIBLE LIQUID (MORE
THAN 450 LITERS). IDENTIFICATION NUMBER: NONE (NOT MORE THAN 450 LITERS); NA
1993 (MORE THAN 450 LITERS). MARINE POLLUTANT: NONE. PROPER SHIPPING NAME:
UNRESTRICTED (NOT MORE THAN 1 PINT); AVIATION REGULATED LIQUID, N.O.S.,
(CYANOACRYLATE ESTER) (MORE THAN 1 PINT). CLASS OR DIVISION: UNRESTRICTED
(NOT MORE THAN 1 PINT); CLASS 9 MORE THAN (OTHER INFORMATION)
=======================================================
Regulatory Information
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Sara Title III Information: N/P. ECOLOGICAL INFO (CONT): POLYETHYLENE
GLOVES AND APRONWHEN HANDLING LARGE AMOUNTS OF ADHESIVE. SKIN ADHESION:
FIRST IMMERSE THE BONDED SURFACES IN WARM, SOAPY WATER. PEEL OR ROLL THE
SURFACE S APART WITH THE AID OF A BLUNT EDGE, E.G. A SPTULA OR A TEASPOON
HANDLE; THEN REMOVE ADHESIVE FROM THE SKIN WTH SOAP AND WATER. DO NOT TRY TO
PULL SURFACES APART WITH A DIRECT OPPOSING ACTION. EYELI D TO EYELID OR
EYEBALL ADHESION: IN THE EVENT THAT EYELIDS ARE STUCK TOGETHER OR BONDED TO
THE EYEBALL, WASH THOROUGHLY WITH WARM WATER AND APPLY A GAUZE PATCH. THE EYE
WILL OPEN WITHOUT FURTHER ACTIO N, TYPICALLY IN (FEDERAL REGULATORY)
Federal Regulatory Information: N/P. SARA III (CONT): 1 - 4 DAYS. THERE
WILL BE NO RESIDUAL DAMAGE. DO NOT TRY TO OPEN THE EYES BY MANIPULATION.
ADHESIVE ON THE EYEBALL: CYANOACRYLATE INTRODUCED INTO THE EYES WILL ATTACH
ITSEL F TO THE EYE PROTEIN AND WILL DISASSOCIATE FROM IT OVER INTERMITTENT
PERIODS, GENERALLY COVERING SEVERAL HOURS. THIS WILL CAUSE PERIODS OF WEEPING
UNTIL CLEARANCE IS ACHIEVED. DURING THE PERIOD OF CON TAMINATION, DOUBLE
VISION MAY BE EXPERIENCED TOGETHER WITH A LACHRYMATORY EFFECT, AND IT IS
IMPORTAN T TO UNDERSTAND THE CAUSE AND REALIZE THAT DISASSOCIATION WILL
NORMALLY OCCUR WITHIN A MATTER OF HOURS, EVEN WITH GROSS (STATE REGULATORY)
State Regulatory Information: NO CALIFORNIA PROPOSITION 65 CHEMICALS KNOWN TO
BE PRESENT. FEDERAL REGULATORY (CONT): CONTAMINATION. MOUTH: IF LIPS ARE
ACCIDENTALLY STUCK TOGETHER, APPLY LOTS OF WARM WATER TO THE LIPS AND ENCO
URAGE MAXIMUM WETTING AND PRESSURE FROM SALIVA INSIDE THE MOUTH. PEEL OR ROLL
LIPS APART. DO NOT TRY TO PULL THE LIPS WITH DIRECT OPPOSING ACTION. IT IS
ALMOST IMPOSSIBLE TO SWALLOW CYANOACRYLATE. TH E ADHESIVE SOLIDIFIES AND
ADHERES IN THE MOUTH. SALIVA WILL LIFT THE ADHESIVE IN ONE HALF TO TWO DAY S.
IN CASE A LUMP FORMS IN THE MOUTH, POSITION THE PATIENT TO PREVENT INGESTION
OF THE LUMP WHEN IT DETACHES.
=======================================================
Other Information
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Other Information: ABBREVIATIONS: N/A = NOT APPLICABLE. TRANSPORT INFO
(CONT): 1 PINT). UN OR ID NUMBER: NONE (NOT MORE THAN 1 PINT); UN 3334 (MORE
THAN 1 PINT). STATE REGULATORY (CONT): BURNS: CYANOACRYLATES GIVE OFF
HEAT ON SOLIDIFICATION. IN RARE CASES A LARGE DROP WILL INCREASE IN
TEMPERATURE ENOUGH TO CAUSE A BURN. BURNS SHOULD BE TREATED NORMALLY AFTER
THE LUMP OF CYANOACRYLATE IS RELEASED FROM THE T ISSUE AS DESCRIBED ABOVE.
SURGERY: IT SHOULD NEVER BE NECESSARY TO USE SUCH A DRASTIC METHOD TO
SEPARATE ACIDENTALLY BONDED SKIN.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PRISM 401 SURF-INSENSITIVE INST ADH, 40140
Company: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT
Zipcode: 06067-3910
Health Emergency Phone: 860-571-5100
Label Required IND: Y
Date Of Label Review: 12/06/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SKIN CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY
AND STRONGLY. SKIN AND EYE IRRITANT. VAPOR IS IRRITATING TO EYES AND MUCOUS
MEMBRANES. CHRONIC: PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS M AY
PRODUCE SYMPTOMS OF NON-ALLERGIC ASTHMA IN SENSITIVE INDIVIDUALS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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