LAROCHE CHEMICALS -- R-113 CFC-113 REFRIGERANT 113
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Material Safety Data Sheet
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MSDS Num: BSXYJ
MSDS NAME: R-113 CFC-113 REFRIGERANT 113
Responsible Party
Name: LAROCHE CHEMICALS
Box: 5500
City: GRAMERCY LA 70052
Info Phone: 800-528-4963
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
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Contractor Summary
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Name: LAROCHE CHEMICALS
Address: UNKNOWN
City: GRAMERCY LA 70052
Phone: 800-528-4963
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Ingredients
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Cas: 76-13-1
RTECS #: KJ4000000
Name: ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;
(1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE) (FREON 113) (SARA III)
% Wt: >99.9
OSHA PEL: 1000 PPM; 1250 STEL
ACGIH TLV: 1000 PPM; 1250 STEL
Ozone Depleting Chemical: 1
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CHLOROFLUOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM
TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUS
TAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CFC'S (FP N). EYE
CONT:VAP MAY ACT AS MILD (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:IRRITANT; LIQ WILL IRRITATE EYES
& CAUSE CONJUNCT. SKIN CONT:IRRITANT; EXCESSIVE CONT MAY CAUSE DEFATTING.
INHAL:MAY CAUSE DROW, LOSS OF CONC, "HEAVINESS" IN THE HEAD AT CONC <2500
PPM. AT HI GHER CONC, MAY CAUSE ARRHY. INGEST:MAY CAUSE DISCOMFORT. MAY ALSO
GIVE SIMILAR SYMPS & TOX AS NOTED UNDER INHAL.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES:IMMED FLUSH W/WATER FOR AT LEAST 15 MINS, LIFTING EYELIDS
OCCASIONALLY; IF SYMPTOMS PERSIST, CONSULT MD. SKIN: FLUSH W/WATER &
REMOVE CONTAMINATED CLOTHES. INHAL:REMOVE FROM CONTAMINATED AREA. AP PLY
OXYGEN IF BRTHG IS DFCLT. GIVE ARTFRESP IF BRTHG HAS STOPPED. GET MED ATTN.
INGEST:IF CONSCIOUS, INDUCE VOM IMMED BY GIVING TWO GLASSES OF WATER &
TOUCHING FINGERS TO THE BACK OF THROAT. CALL MD.
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Handling and Disposal
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Spill Release Procedures: STOP DISCHARGE IF POSSIBLE. KEEP PEOPLE AWAY. AVOID
CONTACT W/LIQUID. ISOLATE & REMOVE DISCHARGED MATERIAL. KEEP AWAY FROM
OPEN FLAME.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: PROD AS COMMERCIALLY PRDCED IS NOT A LISTED HAZ WASTE.
DISP OF THIS PROD MUST BE I/A/W APPROP FED, STATE & LOC ENVIRON LAWS
& REGS. DO NOT VENT TO ATM. DO NOT DISCHARGE TO GROUND OR WATER. IT IS
RECOM THAT PROD WASTE BE COLLECTED FOR POSS (SUPP DATA)
Handling And Storage Precautions: STORE IN WELL VENTILATED, DRY AREA
(<125F). CONTACT W/FLAME OR HIGH TEMPERATURE SHOULD BE AVOIDED.
Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY OF ARC
WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY CAUSE
FORMATION OF HCL &/OR PHOSGENE (FP N).
=======================================================
Fire and Explosion Hazard Information
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Flash Point Text: NONE
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: AS APPROPRIATE FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: THERMAL DECOMP PRODS MAY INCL CHLORIDES,
FLUORIDES & PHOSGENE (FP N). MAY DECOMPOSE TO FORM HALOGEN ACIDS &/OR
PHOSGENE AT TEMPERATURES ABOVE 600C.
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Control Measures
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Respiratory Protection: ATM LEVELS SHOULD BE MAINTAINED BELOW EXPOSURE
GUIDELINE. WHERE EXPOSURE GUIDELINES MAY BE GREATLY EXCEEDED, USE A NIOSH/
MSHA APPRVD POSITIVE PRESS SCBA. IN CONFINED OR POORLY VENTILATED AREAS, USE
A NIOSH/MSHA APPRVD POSITIVE SCBA.
Ventilation: CONTROL AIRBORNE CONC BELOW EXPOS GUIDELINE. USE ONLY W/ADEQ VENT.
LOCAL EXHST VENT MAY BE NEC FOR SOME OPERATIONS.
Protective Gloves: BUTYL RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKER GOGGLES (FP N).
Other Protective Equipment: BRIEF CONT, NO PRECS OTHER THAN CLEAN BODY-
COVERING CLTHG. WHEN PRLNGD/RPTD CONT COULD OCCUR, USE PROT CLTHG (SUPP DATA
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: WASTE DISP METH:RECYCLE/RECLAMATION ACTIVITIES.
IF SUCH OPTIONS ARE NOT AVAILABLE, THEN MATERIAL SHOULD BE SENT TO AN EPA
APPROVED INCINERATOR. OTHER PROT EQUIP:SUCH AS BUTYL RUBBER, IMPERVIOUS TO
THI S MATERIAL.
=======================================================
Physical/Chemical Properties
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HCC: T6
B.P. Text: 118F,48C
Vapor Pres: 285 @ 70F
Vapor Density: 6.5
Spec Gravity: 1.55 (H2O=1)
Evaporation Rate & Reference: 1.3 (CCL(4) = 1)
Solubility in Water: 0.017%
Appearance and Odor: COLORLESS LIQUID; FAINT ETHEREAL ODOR.
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID OPEN FLAMES & HIGH TEMPERATURES.
Materials To Avoid: ALUMINUM POWDER, FINELY DIVIDED BARIUM, LITHIUM SHAVINGS &
POWDERED TITANIUM.
Hazardous Decomposition Products: CHLORIDES, FLUORIDES & PHOSGENE (FP N). MAY
DECOMPOSE TO HALOGEN ACIDS OR PHOSGENE AT TEMPERATURES ABOVE 600C.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: R-113 CFC-113 REFRIGERANT 113
Company: LAROCHE CHEMICALS
Street: UNKNOWN
City: GRAMERCY LA
Zipcode: 70052
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 08/09/1993
Status Code: C
Label Date: 08/09/1993
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: MAY CAUSE HAZARDOUS DECOMPOSITION PRODUCTS. STORE IN
WELL-VENTILATED, DRY AREA (BELOW 125F). CONTACT WITH FLAME OR HIGH
TEMPERATURE SHOULD BE AVOIDED. NO SMOKING IN AREA OF USE. DO NOT USE IN
GENERAL VICINITY OF ARC WELDING, OPEN FLAMES ORHOT SURFACES. HEAT AND/OR UV
RADIATION MAY CAUSE FORMATION OF HCL AND/OR PHOSGENE. ACUTE: MILD IRRITANT.
MAY CAUSE DROWSINESS AND CARDIAC ARRHYTHMIA AT HIGH CONC ENTRATIONS.
CHLOROFLUOROCARBONS HAVE PRODUCED SENSITIZATION OF MYOCARDIUM TO EPINEPHRINE.
CHRONIC:NONE NOTED BY THE MFR.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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