LAROCHE CHEMICALS -- R-114 CFC-114 REFRIGERANT 114
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Material Safety Data Sheet
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MSDS Num: BSXYH
MSDS NAME: R-114 CFC-114 REFRIGERANT 114
Responsible Party
Name: LAROCHE CHEMICALS
Box: 5500
City: GRAMERCY LA 70052
Info Phone: 800-528-4963
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
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Contractor Summary
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Name: LAROCHE CHEMICALS
Address: UNKNOWN
City: GRAMERCY LA 70052
Phone: 800-528-4963
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Ingredients
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Cas: 76-14-2
RTECS #: KI1101000
Name: ETHANE, 1,2-DICHLORO-1,1,2,2-TETRAFLUORO-; (DICHLOROTETRAFLUOROETHANE)
(SARA III)
% Wt: >99.9
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM
Ozone Depleting Chemical: 1
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Health Hazards Data
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LD50 LC50 Mixture: LD50:(ORAL RAT) 61 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE CONTACT:NOT READILY ABSORBED THROUGH MUCOUS MEMBRANES
OR TISSUE OF EYE; HOWEVER, MAY CAUSE FROSTBITE AS INDICATED BY PALLOR OR
REDNESS, LOSS OF SENSATION & SWELLING OF AFFECTED TISSUE. SKIN CONTAC
T:IRRITANT; EXCESSIVE CONTACT MAY CAUSEDEFATTING. INHAL:VAPORS ARE RELATIVELY
NON-TOXIC BUT MAY ACT (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:AS NARCOTIC & CNS DEPRESSANT
AT HIGH CONC (WHEN OXYGEN LEVELS IN AIR ARE REDUCED TO 12-14%). SYMPTOMS OF
ASPHY MAY OCCUR, NAMELY:LOSS OF COORD, INCRD PULSE RATE, DEEPER RESPIRATION,
NAUSEA & DIZZINESS. INGEST:NOT PERTINENT, SINCE MATL IS GASEOUS AT
NORMAL TEMPERATURE & PRESSURE.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES/SKIN:IMMEDIATELY BATHE ANY FROSTBITE (DO NOT RUB) W/LUKEWARM
WATER FOR AT LEAST 15 MINS. IN ABSENCE OF WATER, COVER W/SOFT WOOL OR OTHER
SUITABLE MATL. CONTACT MD. DO NOT GIVE EPINEPHRINE. INHAL: REMOVE FROM
CONTAMD AREA; APPLY OXYGEN IF BRTHG IS DIFFICULT. GIVE ARTF RESP IF BRTHG HAS
STOPPED & GET MED ATTN. INGEST:CALL MD IMMEDIATELY (FP N).
=======================================================
Handling and Disposal
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Spill Release Procedures: STOP DISCHARGE IF POSSIBLE. KEEP PEOPLE AWAY. REMOVE
ANY FLAME. ISOLATE & REMOVE DISCHARGED MATERIAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: PROD AS COMMERCIALLY PRDCED IS NOT A LISTED HAZ WASTE.
DISP OF THIS PROD MUST BE I/A/W APPROP FED, STATE & LOC ENVIRON LAWS
& REGS. DO NOT VENT TO ATM. DO NOT DISCHARGE TO GROUND OR WATER. IT IS
RECOM THAT PROD WASTE BE COLLECTED FOR POSS (SUPP DATA)
Handling And Storage Precautions: STORE IN WELL-VENTILATED, DRY AREA
(<125F). CONTACT W/FLAMES OR HIGH TEMPERATURES SHOULD BE AVOIDED.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: AS APPROPRIATE FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: MAY DECOMPOSE TO FORM HALOGEN ACID &/OR
PHOSGENE AT TEMPERATURES ABOVE 600C.
=======================================================
Control Measures
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Respiratory Protection: ATM LEVELS SHOULD BE MAINTAINED BELOW EXPOSURE
GUIDELINE. WHERE EXPOSURE GUIDELINES MAY BE GREATLY EXCEEDED, USE A NIOSH/
MSHA APPRVD POSITIVE PRESS SCBA. IN CONFINED OR POORLY VENTILATED AREAS, USE
A NIOSH/MSHA APPRVD POSITIVE SCBA.
Ventilation: CONTROL AIRBORNE CONC BELOW EXPOS GUIDELINE. USE ONLY W/ADEQ VENT.
LOCAL EXHST VENT MAY BE NEC FOR SOME OPERATIONS.
Protective Gloves: BUTYL RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKER GOGGLES (FP N).
Other Protective Equipment: BRIEF CONT, NO PRECS OTHER THAN CLEAN BODY-
COVERING CLTHG. WHEN PRLNGD/RPTD CONT COULD OCCUR, USE PROT CLTHG (SUPP DATA
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: WASTE DISP METH:RECYCLE/RECLAMATION ACTIVITIES.
IF SUCH OPTIONS ARE NOT AVAILABLE, THEN MATERIAL SHOULD BE SENT TO AN EPA
APPROVED INCINERATOR. OTHER PROT EQUIP:SUCH AS BUTYL RUBBER, IMPERVIOUS TO
THI S MATERIAL.
=======================================================
Physical/Chemical Properties
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HCC: T4
B.P. Text: 38.4F,3.6C
Vapor Pres: 1427 @ 70F
Vapor Density: 5.9
Spec Gravity: 1.44 (H2O=1)
Evaporation Rate & Reference: 1.3 (CCL(4) = 1)
Solubility in Water: 0.013%
Appearance and Odor: COLORLESS LIQUID; WHICH RAPIDLY EVAPORATES; PRACTICALLY
ODORLESS.
Percent Volatiles by Volume: 100
=======================================================
Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID OPEN FLAMES & HIGH TEMPERATURES.
Materials To Avoid: CHEMICALLY ACTIVE METALS SUCH AS SODIUM, POTASSIUM,
CALCIUM, POWDERED ALUMINUM, ZINC & MAGNESIUM; ACIDS & ACID FUMES.
Hazardous Decomposition Products: MAY DECOMPOSE TO HALOGEN ACIDS OR PHOSGENE AT
TEMPERATURES ABOVE 600C.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: R-114 CFC-114 REFRIGERANT 114
Company: LAROCHE CHEMICALS
Street: UNKNOWN
City: GRAMERCY LA
Zipcode: 70052
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 08/09/1993
Status Code: C
Label Date: 08/09/1993
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: STORE IN A WELL-VENTILATED, DRY AREA (BELOW 125F).
CONTACT WITH FLAMES OR HIGH TEMPERATURES SHOULD BE AVOIDED. ACUTE: CONTACT
MAY CAUSE FROSTBITE. VAPORS MAY ACT AS NARCOTIC AND CENTRAL NERVOUS SYSTEM
DEPRESSANT AT HIGH CONCENTRATIONS, POSSIBLE LOSS OF COORDINATION, INCREASED
PULSE RATE, DEEPER RESPIRATION, NAUSEA AND DIZZINESS. CHRONIC: NONE LISTED BY
MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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