===================== Product Identification =====================
MSDS NAME:SILVERTONE FINISH FOR PLASTICS 461-320
NIIN:00N015178
MSDS Number: BKNPG
=== Responsible Party ===
Company:E I DU PONT DE NEMOURS & CO
Address:FINISHES & FABRICATED PRODUCTS DEPT
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
CAGE:B0589
=== Contractor Identification ===
Company:E I DU PONT DE NEMOURS & CO
Address:RAKETSTRAAT, 100, RUE DE LA FUSEE
City:BRUSSEL
Country:BE
Phone:32-(0)15-401.505
CAGE:B0589
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
============= Composition/Information on Ingredients =============
Name:ING 14:LUNGS SHOWED LUNG CLEARANCE MECH WAS OVERWHELMED &
RESULTS AT MASSIVE 250 MG/M3 LEVEL ARE NOT (SEE ING 16)
RTECS #:9999999ZZ
Name:ING 15:RELEVANT TO WORKPLACE. EXPOS TO TEFLON DECOMP PRODS
CAN CREATE INFLUENZA-LIKE SYMPS, COMMONLY (SEE ING 17)
RTECS #:9999999ZZ
Name:ING 16:REFERRED TO AS POLYMER FUME FEVER. SYMPS DO NOT
ORDINARILY OCCUR UNTIL SEVERAL HRS AFTER EXPOS & (SEE ING 18)
RTECS #:9999999ZZ
Name:ING 17:PASS WITHIN 36-48 HRS. EFFECTS ARE NOT CUMULATIVE.
EXPOS USUALLY RESULTS FROM SMOKING TOBACCO OR (SEE ING 19)
RTECS #:9999999ZZ
Name:ING 18:CIGARETTES CONTAMD W/FLUOROCARBON DURING HNDLG/FROM
BRTHG VAPS EMITTED DURING BAKING. DO NOT EXCEED (SEE ING 20)
RTECS #:9999999ZZ
Name:ING 19:RECOMMENDED BAKING TEMPS. BAKING OVENS MUST BE
PROPERLY VENT. AT TEMPS ABOVE 750F SMALL AMTS OF (SEE ING 21)
RTECS #:9999999ZZ
Name:ING 20:HYDROGEN FLUORIDE CAN BE EVOLVED; AMTS INCR AS TEMP
INCR. HYDROGEN FLUORIDE IS TOXIC & CAN CAUSE (SEE ING 22)
RTECS #:9999999ZZ
Name:ING 21:SKIN/EYE IRRIT (3PPM-ACGIH). HIGH CONCS CAN CAUSE
LUNG DMG, PULMONARY EDEMA/BURNS. SOME VEGETATION (SEE ING 23)
RTECS #:9999999ZZ
Name:ING 22:IS PARTICULARLY SENSITIVE TO DMG BY HF & ATTENTION
MUST BE GIVEN TO EXHAUST LOCATIONS.
RTECS #:9999999ZZ
Name:METHYL ISOBUTYL KETONE (SARA III)
CAS:108-10-1
RTECS #:SA9275000
OSHA PEL:100 PPM/75 STEL
ACGIH TLV:50 PPM/75 STEL; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SILICONE RESIN
CAS:68037-81-0
Name:SILICA GEL (AMORPHOUS SILICA)
CAS:7631-86-9
OSHA PEL:6 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Name:MICA - SILICATES (< 1% CRYSTALLINE SILICA)
CAS:12001-26-2
RTECS #:VV8760000
OSHA PEL:20 MPPCF
ACGIH TLV:3 MG/M3 RDUST; 9293
Name:NON-HAZARDOUS POLYMER
Name:NAPHTHA, MEDIUM ALIPHATIC (MEDIUM MINERAL SPIRITS). VP:10
MM HG.
CAS:64742-88-7
Other REC Limits:100 PPM (MFR)
OSHA PEL:500 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Name:SUPP DATA:TO CHRONIC LUNG DISEASE. NON-HAZ POLYMER:NO KNOWN
HAZ W/NORMAL INDUS USE. MEDIUM MINERAL SPIRITS: (SEE ING 10)
RTECS #:9999999ZZ
Name:ING 9:PETROLEUM DISTILLATES-LAB STUDIES W/RATS HAVE SHOWN
THAT PETROLEUM DISTILLATES CAUSE KIDNEY DMG & (SEE ING 11)
RTECS #:9999999ZZ
Name:ING 10:KIDNEY/LIVER TUMORS. EFFECTS WERE NOT SEEN IN
SIMILAR STUDIES W/GUINEA PIGS, DOGS, MONKEYS. SEVERAL (SEE ING 12)
RTECS #:9999999ZZ
Name:ING 11:STUDIES EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN
SIGNIFICANT INCR OF KIDNEY DMG, KIDNEY/LIVER (SEE ING 13)
RTECS #:9999999ZZ
Name:ING 12:TUMORS. TITANIUM DIOXIDE:NO KNOWN HAZ W/NORMAL INDUS
USE. IN LIFETIME INHAL TEST, LUNG CANCERS WERE (SEE ING 14)
RTECS #:9999999ZZ
Name:ING 13:FOUND IN SOME RATS EXPOSED TO 250 MG/M3 RESP
TITANIUM DUST. ANALYSIS OF TITANIUM DIOXIDE CONCS IN (SEE ING 15)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:OVEREXPOS TO VAPS DURING SPRAY
APPLICATION MAY CAUSE NOSE/THROAT IRRIT. MAY CAUSE NERVOUS SYS
DEPRESS CHARACTERIZED BY FOLLOWING PROGRESSIVE STEPS:HDCH, DIZZ,
NAUSEA, STAGGERING GAIT, CONFUSION, UNCON. REPORTS HAVE ASSOC
RPTD/PRLNGD OVEREXPOS TO SOLVS W/PERM BRAIN DMG & NERVOUS SYSTEM
DMG. (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NONE.
Effects of Overexposure:HLTH HAZ:SKIN/EYE:MAY CAUSE IRRIT/BURNING OF
EYES. RPTD/PRLNGD LIQ CNTCT MAY CAUSE SKIN IRRIT W/DISCOMFORT/DERM.
OTHER POTNTL HAZ INCLUDE:METHYL ISOBUTYL KETONE:MAY CAUSE ABNORMAL
KIDNEY FUNCTION. XYL ENE:HIGH CONCS HAVE CAUSED EMBRYOTOXIC EFFECTS
IN LAB ANIMALS. RECURRENT OVEREXPOS MAY RESULT IN LIVER & (SEE SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP,
PREFERABLY MOUTH-TO-MOUTH. IF BRTHG DFCLTY PERSISTS/OCCURS LATER,
CALL MD. EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN,
CALL MD. SKIN :WASH W/SOAP & WATER. IF IRRIT OCCURS, CALL MD.
INGEST:GASTROINTESTINAL DISTRESS. CALL MD IMMEDIATELY & HAVE NAMES
OF INGREDIENTS AVAILABLE.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:20.0F,-6.7C
Lower Limits:1.10%
Upper Limits:18.00%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT. WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CNTNRS
TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASH POINT, EMITS
FLAMM VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLO. FINE
MISTS/SPRAYS MAY BE FLAMM AT TEMPS BELOW FLASH (SEE SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
AVOID SKIN CONTACT & BREATHING OF VAPOR. CONFINE & REMOVE W/INERT
ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS & FLAME. CLOSE CNTNR AFTER EACH USE. GROUND
CNTNRS WHEN POURING. DO NOT STORE ABOVE 120F.
Other Precautions:EXPLO REACTION MAY OCCUR ABOVE 796F W/FINELY DIVIDED
FLUOROCARBON/METAL POWDER (ALUMINUM/MAGNESIUM). OPERATIONS SUCH AS
GRINDING, BUFFING, GRIT BLASTING MAY GENERATE SUCH MIXTURES. KEEP
WET. USE ADEQU ATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DO NOT BREATHE VAPORS/MISTS. WEAR PROPERLY
FITTED NIOSH/MSHA APPRVD VAPOR/PARTICULATE RESPIRATOR FOR USE
W/PAINTS DURING APPLICATION & UNTIL ALL VAPORS/SPRAY MIST ARE
EXHAUSTED. FOLLOW RESPIRATOR MFR' S DIRECTIONS FOR RESPIRATOR USE.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME/PATTERN TO KEEP
CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING
& SMOKING.
Supplemental Safety and Health
% VOLAT:48-61(WT). EXPLO HAZ:POINT. HYDROGEN FLUORIDE IS RELEASED
DURING FIRE. EFTS OF OVEREXP:KIDNEY INJURY. CAN BE ABSORBED THRU
SKIN IN HARMFUL AMTS. SILICONE RESIN:MAY CAUSE EYE IRRIT
W/DISCOMFORT , TEARING/BLURRED VISION. AMORPHOUS SILICA:NO KNOWN
HAZ W/NORM INDUS USE. MICA:RPTD/PRLNGD OVEREXPOS MAY LEAD(SEE ING
9)
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:172F,78C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:SLIGHT.
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORSEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:OXIDES OF HEAVY METALS REPORTED IN
INGREDIENTS SECTION. HYDROGEN FLUORIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL I/A/W FEDERAL, STATE
AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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