===================== Product Identification =====================
MSDS NAME:SILVERSTONE FOR PLASTICS 461-321
NIIN:00N015177
MSDS Number: BKNPF
=== Responsible Party ===
Company:E I DU PONT DE NEMOURS & CO
Address:FINISHES & FABRICATED PRODUCTS DEPT
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
CAGE:B0589
=== Contractor Identification ===
Company:E I DU PONT DE NEMOURS & CO
Address:RAKETSTRAAT, 100, RUE DE LA FUSEE
City:BRUSSEL
Country:BE
Phone:32-(0)15-401.505
CAGE:B0589
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
============= Composition/Information on Ingredients =============
Name:ING 20:EVOLVED; AMTS INCR AS TEMP INCR. HYDROGEN FLUORIDE
IS TOXIC & CAN CAUSE SKIN/EYE IRRIT (3PPM-ACGIH). (SEE ING 22)
RTECS #:9999999ZZ
Name:ING 21:HIGH CONCS CAN CAUSE LUNG DMG, PULMONARY
EDEMA/BURNS. SOME VEGETATION IS PARTICULARLY SENSITIVE TO (SEE ING
23)
RTECS #:9999999ZZ
Name:ING 22:DAMAGE BY HF & ATTENTION MUST BE GIVEN TO EXHAUST
LOCATIONS.
RTECS #:9999999ZZ
Name:NON-HAZARDOUS POLYMER
Name:NAPHTHA, MEDIUM ALIPHATIC (MEDIUM MINERAL SPIRITS). VP:10
MM HG. OSHA PEL:500PPM STEL(MFR). ACGIH TLV:500PPM STEL(MFR).
CAS:64742-88-7
OSHA PEL:100 PPM;(SEE INGRED)
ACGIH TLV:100 PPM;(SEE INGRED)
Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Name:SUPP DATA:LUNG DISEASE. NONHAZ POLYMER:NO KNOWN HAZ
W/NORMAL INDUS USE. MEDIUM MINERAL SPIRITS:PETROLEUM (SEE ING 10)
RTECS #:9999999ZZ
Name:ING 9:DISTILLATES-LAB STUDIES W/RATS HAVE SHOWN THAT
PETROLEUM DISTILLATES CAUSE KIDNEY DMG & KIDNEY/LIVER (SEE ING 11)
RTECS #:9999999ZZ
Name:ING 10:TUMORS. THESE EFFECTS WERE NOT SEEN IN SIMILAR
STUDIES W/GUINEA PIGS, DOGS/MONKEYS. SEVERAL STUDIES (SEE ING 12)
RTECS #:9999999ZZ
Name:ING 11:EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN
SIGNIFICANT INCR OF KIDNEY DMG/KIDNEY/LIVER TUMORS. (SEE ING 13)
RTECS #:9999999ZZ
Name:ING 12:TITANIUM DIOXIDE:NO KNOWN HAZ W/NORMAL INDUS USE. IN
LIFETIME INHAL TEST, LUNG CANCERS WERE FOUND IN (SEE ING 14)
RTECS #:9999999ZZ
Name:ING 13:SOME RATS EXPOSED TO 250 MG/M3 RESP TITANIUM DUST.
ANALYSIS OF TITANIUM DIOXIDE CONCS IN RATS LUNGS (SEE ING 15)
RTECS #:9999999ZZ
Name:ING 14:SHOWED LUNG CLEARANCE MECH WAS OVERWHELMED & RESULTS
AT MASSIVE 250 MG/M3 LEVEL ARE NOT RELEVANT (SEE ING 16)
RTECS #:9999999ZZ
Name:ING 15:TO THE WORKPLACE. EXPOS TO TEFLON DECOMP PRODS CAN
CREATE INFLUENZA-LIKE SYMPS, REFERRED TO AS (SEE ING 17)
RTECS #:9999999ZZ
Name:ING 16:POLYMER FUME FEVER. SYMPS DO NOT ORDINARILY OCCUR
UNTIL SEVERAL HRS AFTER EXPOS & PASS WITHIN 36-48 (SEE ING 18)
RTECS #:9999999ZZ
Name:ING 17:HRS. EFFECTS ARE NOT CUMULALTIVE. EXPOS USUALLY
RESULTS FROM SMOKING TOBACCO/CIGARETTES CONTAMD (SEE ING 19)
RTECS #:9999999ZZ
Name:ING 18:W/FLUOROCARBON DURING HNDLG/FROM BRTHG VAPS EMITTED
DURING BAKING. DO NOT EXCEED RECOMMENDED BAKING (SEE ING 20)
RTECS #:9999999ZZ
Name:ING 19:TEMPS. BAKING OVENS MUST BE PROPERLY VENT. AT TEMPS
ABOVE 750F SMALL AMTS OF HYDROGEN FLUORIDE CAN BE(SEE ING 21)
RTECS #:9999999ZZ
Name:METHYL ISOBUTYL KETONE (SARA III)
CAS:108-10-1
RTECS #:SA9275000
OSHA PEL:100 PPM/75 STEL
ACGIH TLV:50 PPM/75 STEL; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SILICONE RESIN
CAS:68037-81-0
Name:SILICA GEL (AMORPHOUS SILICA)
CAS:112945-52-5
RTECS #:VV7310000
OSHA PEL:6 MG/M3 (MFR)
ACGIH TLV:3 MG/M3 (MFR)
Name:MICA - SILICATES (< 1% CRYSTALLINE SILICA)
CAS:12001-26-2
RTECS #:VV8760000
OSHA PEL:20 MPPCF
ACGIH TLV:3 MG/M3 RDUST; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:OVEREXPOS TO VAPS DURING SPRAY
APPLICATION MAY CAUSE NOSE/THROAT IRRIT. MAY CAUSE NERVOUS SYS
DEPRESS CHARACTERIZED BY FOLLOWING PROGRESSIVE STEPS:HDCH, DIZZ,
NAUSEA, STAGGERING GAIT, CONFUSION, UNCON. REPORTS HAVE ASSOC
RPTD/PRLNGD OVEREXPOS TO SOLVS W/PERM BRAIN DMG & NERVOUS SYS DMG.
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHRYSTALLINE SILICA: IARC - 2A.
Effects of Overexposure:HLTH HAZ:SKIN/EYE:MAY CAUSE IRRIT/BURNING OF
EYES. RPTD/PRLNGD LIQ CNTCT MAY CAUSE SKIN IRRIT W/DISCOMFORT/DERM.
OTHER POTNTL HAZ INCLUDE:METHYL ISOBUTYL KETONE:MAY CAUSE ABNORMAL
KIDNEY FUNCTION. XYL ENE:HIGH CONCS HAVE CAUSED EMBRYOTOXIC EFFECTS
IN LAB ANIMALS. RECURRENT OVEREXPOS MAY RESULT IN LIVER & (SEE SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP,
PREFERABLY MOUTH-TO-MOUTH. IF BRTHG DFCLTY PERSISTS/OCCURS LATER,
CALL MD. SKIN:WASH W/SOAP & WATER. IF IRRIT OCCURS, CALL MD.
EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN,CALL MD.
INGEST:GASTRO-INTESTINAL DISTRESS. CALL MD IMMEDIATELY & HAVE NAMES
OF INGREDIENTS AVAILABLE.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:20.0F,-6.7C
Lower Limits:1.1%
Upper Limits:18%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT. WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASH POINT, EMITS
FLAMM VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLO. FINE
MISTS/SPRAYS MAY BE FLAMM AT TEMPS BELOW FLASH (SEE SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
AVOID SKIN CONTACT & BREATHING OF VAPOR. CONFINE & REMOVE W/INERT
ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS & FLAME. CLOSE CNTNR AFTER EACH USE. GROUND
CNTNRS WHEN POURING. DO NOT STORE ABOVE 120F.
Other Precautions:EXPLOSIVE REACTION MAY OCCUR ABOVE 796F W/FINELY
DIVIDED FLUOROCARBON & METAL POWDER (ALUMINUM/MAGNESIUM).
OPERATIONS SUCH AS GRINDING, BUFFING OR GRIT BLASTING MAY GENERATE
SUCH MIXTURES. KEEP WET. U SE ADEQUATE VENTILATION TO CONTROL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DO NOT BREATHE VAPORS/MISTS. WEAR PROPERLY
FITTED NIOSH/MSHA APPRVD VAPOR/PARTICULATE RESPIRATOR FOR USE
W/PAINTS DURING APPLICATION & UNTIL ALL VAPORS & SPRAY MIST ARE
EXHAUSTED. FOLLOW RESPIRATOR MF R'S DIRECTIONS FOR RESPIRATOR USE.
Ventilation:PROVIDE SUFFICIENT VENT IN VOLUME & PATTERN TO KEEP
CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NEOPRENE COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING
& SMOKING.
Supplemental Safety and Health
EXPLO HAZ:POINT. HYDROGEN FLUORIDE IS RELEASED DURING FIRE. EFTS OF
OVEREXP:KIDNEY INJURY. CAN BE ABSORBED THROUGH SKIN IN HARMFUL
AMTS. SILICONE RESIN:MAY CAUSE EYE IRRIT W/DISCOMFORT,
TEARING/BLURRE D VISION. AMORPHOUS SILICA:NO KNOWN HAZW/NORMAL
INDUS USE. MICA:RPTD/PRLNGD OVEREXPOS MAY LEAD TO CHRONIC(SEE
INGRED 9)
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:172F,78C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:SLIGHT.
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:48-61
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORSEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:OXIDES OF HEAVY METALS REPORTED IN
INGREDIENTS SECTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL I/A/W FEDERAL, STATE
AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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