2-propenenitrile, homopolymer (polymeric acrylonitrile) supp data: warning: this product contains approx 10ppm ing 02: to cause cancer. the amount of acrylonitrile ing 03: requirements for handling acrylonitrile.
MSDS NAME:POLYMERIC ACRYLONITRILE TYPE A
NIIN:00N015204
MSDS Number: BKNPX
=== Responsible Party ===
Company:E I DUPONT DE NEMOURS & CO INC
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
Preparer's Name:PETROCHEMICALS-ENV AFFAIR
CAGE:0ERJ7
=== Contractor Identification ===
Company:E I DUPONT DE NEMOURS & CO, INC.
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515
CAGE:0ERJ7
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
============= Composition/Information on Ingredients =============
Name:2-PROPENENITRILE, HOMOPOLYMER (POLYMERIC ACRYLONITRILE)
CAS:25014-41-9
Fraction by Wt: 100%
Name:SUPP DATA: WARNING: THIS PRODUCT CONTAINS APPROX 10PPM
ACRYLONITRILE WHICH IS KNOWN TO THE STATE OF CALIFORNIA (ING 03)
RTECS #:9999999ZZ
Name:ING 02: TO CAUSE CANCER. THE AMOUNT OF ACRYLONITRILE
PRESENT IN THIS PRODUCT DOES NOT TRIGGER ANY OF THE OSHA (ING 04)
RTECS #:9999999ZZ
Name:ING 03: REQUIREMENTS FOR HANDLING ACRYLONITRILE.
RTECS #:9999999ZZ
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:POLYMERIC ACRYLONITRILE CONTAINS A
SMALL AMT OF ACRYLONITRILE MONOMER (AVG 10PPM, MAX 26PPM). OSHA HAS
CLASSIFIED ACRYLONITRILE (AN) (CAS# 107-13-1) AS A CANCER HAZARD TO
HUMANS, & HAS ESTABLISHED A T WA EXPOS LIMIT OF 2PPM AN IN AIR. THE
ACTION LIMIT IS 1PPM (8 HR TWA). A CEILING OF 10PPM, (SEE EFTS OF
OVEREXP)
Explanation of Carcinogenicity:ACRYLONITRILE: NTP (GROUP 2), IARC
(GROUP 2A). LISTED BY OSHA AS A CANCER HAZARD TO HUMANS.
Effects of Overexposure:HLTH HAZ: AVERAGED OVER ANY 15 MIN PERIOD, IS
ALLOWED. DUPONT HAS ESTABLISHED AN AEL FOR ACRYLONITRILE OF 0.5 PPM
(8 HR TWA) (SKIN) & A 15 MIN TWA AEL OF 2PPM (SKIN). REGS FOR
MONITORING & CONTROLLING AN CONC ARE DESCRIBED IN SEC 1045, PART
1910 OF TITLE 29 OF THE CODE OF FED REGS. SOLID POLYMERS, SUCH (SEE
SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. SKIN:
FLUSH SKIN WITH WATER. EYE: IMMEDIATELY FLUSH EYES WITH PLENTY OF
WATE R FOR AT LEAST 15 MINUTES. CALL MD. INGEST: DO NOT INDUCE
VOMITING. GIVE LARGE QUANTITIES OF WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. CALL MD.
===================== Fire Fighting Measures =====================
Lower Limits:40 MG/L
Extinguishing Media:WATER.
Fire Fighting Procedures:KEEP PERSONNEL REMOVED AND UPWIND OF FIRE.
WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DUST FORMS EXPLOSIVE MIXTURE WITH AIR.
HAZARDOUS GASES/VAPORS PRODUCED IN FIRE ARE HYDROGEN CYANIDE, CO,
NO*X.
Spill Release Procedures:REVIEW FIRE & EXPLOSION HAZARDS & SAFETY
PRECAUTIONS BEFORE PROCEEDING WITH CLEAN UP. USE APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN UP. RECOVER UNDAMAGED &
MINIMALLY CONTAMINIATED MATERIA L FOR REUSE OR RECLAMATION. SHOVEL
OR SWEEP UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN WELL VENTILATED AREA. KEEP
CNTNR TIGHTLY CLOSED. DO NOT STORE OR CONSUME FOOD, DRINK OR
TOBACCO IN AREAS WHERE THEY MAY BECOME CONTAMINATED.
Other Precautions:AVOID BREATHING DUST.
Respiratory Protection:WEAR NIOSH/MSHA APPROVED FILTER RESPIRATOR/DUST
RESPIRATOR.
Ventilation:USE ONLY WITH ADEQUATE VENTILATION. AVOID DUST GENERATION.
Protective Gloves:NONE SPECIFIED BY MANUFACTURER.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP: AS POLYMERIC ACRYLONITRILE, ARE SPECIFICALLY EXEMPTED
FROM THESE REGS AS LONG AS THEY ARE NOT HEATED ABOVE 170F DURING
HANDLING, USE, OR PROCESSING. IF THIS TEMPERATURE IS EXCEEDED, E
XEMPTION WOULD REQUIRE OBJECTIVE DATA DEMONSTRATING THAT AN CONC
WILL NOT EXCEED THE ACTION LIMIT. (SEE INGRED 02)
HCC:T6
Spec Gravity:1.186
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE POWDER, ODORLESS
Percent Volatiles by Volume:1.5 WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMPOSES WITH HEAT. DEGRADES AT
TEMPERATURES > 150C.
Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL
MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL,
AND LOCAL REGULATIONS. REMOVE NONUSABLE SOLID MATERIAL AND/OR
CONTAMINATED SOIL, FOR DI SPOSAL IN AN APPROVED AND PERMITTED
LANDFILL.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.