| MSDS | : | SULFURIC ACID 77 TO 100%, 60 DEGREES TECH | | CAS | : | 7664-93-9
7732-18-5 | | NAME | : | ing 12:patient lie down and remain quiet. apply artf resp
ing 13:call md. ingest:do not induce vomit. give lge qtys
ing 14:give anything by mouth to an uncon person. spill
ing 15:to waste water treatment system. prevent liquid from
ing 16:with federal, state, and local regulations on
hndlg/stor prec:relieve internal pressure when received and
ing 18:pressure to empty. be sure closure is securely
ing 19:use it for other purposes; replace closure after
eye prot:full-length faceshield to gog . other prot
ing 21:exposure, wear complete acid suit w/hood, boots, &
ing 22:limits may be exceeded, wear osha permissible
sulfuric acid (sara iii)
water
supp data:reducing/combustible organic matls. haz gases are
ing 3:sulfides, and carbides. efts of overexp:ulceration.
ing 4:membranes of mouth and esophagus. repeated or
ing 5:with discomfort, tearing, or blurring of vision; or
ing 6:of overexp by inhal may include irrit of upper resp
ing 7:expos by inhal may lead to temporary lung irrit
ing 8:shortness of breath; or poss modest initial symps,
first aid proc:water can be applied. avoid freezing tiss.
ing 10:cold or iced water will be helpful in removing last
ing 11:not be applied before or during the washing phase of
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===================== Product Identification =====================
MSDS NAME:SULFURIC ACID 77 TO 100%, 60 DEGREES TECH
NIIN:00N015746
MSDS Number: BKRMQ
=== Responsible Party ===
Company:DU PONT E I DE NEMOURS & CO INC
Address:1007 MARKET STREET
Box:1635
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515/MSDS 302-992-3511
Emergency Phone Num:800-441-3637/800-424-9300(CHEMTREC)
Preparer's Name:J C WATTS
CAGE:18873
=== Contractor Identification ===
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
============= Composition/Information on Ingredients =============
Name:ING 12:PATIENT LIE DOWN AND REMAIN QUIET. APPLY ARTF RESP
IF BRTHNG HAS STOPPED. GIVE O*2 IF BRTHNG DFCLT. (SEE ING 14)
RTECS #:9999999ZZ
Name:ING 13:CALL MD. INGEST:DO NOT INDUCE VOMIT. GIVE LGE QTYS
OF WATER. CALL MD. DO NOT GIVE CARBONATES. NEVER (SEE ING 15)
RTECS #:9999999ZZ
Name:ING 14:GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. SPILL
PROC:NEUTRALIZE WITH LIME OR SODA ASH, AND TRANSFER (SEE ING 16)
RTECS #:9999999ZZ
Name:ING 15:TO WASTE WATER TREATMENT SYSTEM. PREVENT LIQUID FROM
ENTERING SEWERS, WATERWAYS, OR LOW AREAS. COMPLY(SEE ING 17)
RTECS #:9999999ZZ
Name:ING 16:WITH FEDERAL, STATE, AND LOCAL REGULATIONS ON
REPORTING RELEASES. SUPERFUND REPORTABLE DISCAHRGE IS 1000 LBS.
RTECS #:9999999ZZ
Name:HNDLG/STOR PREC:RELIEVE INTERNAL PRESSURE WHEN RECEIVED AND
AT LEAST WEEKLY THEREAFTER. DO NOT USE (SEE ING 19)
RTECS #:9999999ZZ
Name:ING 18:PRESSURE TO EMPTY. BE SURE CLOSURE IS SECURELY
FASTENED BEFORE MOVING CNTNR. DO NOT WASH OUT CNTNR OR(SEE ING 20
RTECS #:9999999ZZ
Name:ING 19:USE IT FOR OTHER PURPOSES; REPLACE CLOSURE AFTER
EACH WITHDRAWAL AND RETURN IT WITH EMPTY CONTAINER.
RTECS #:9999999ZZ
Name:EYE PROT:FULL-LENGTH FACESHIELD TO GOG . OTHER PROT
EQUIP:WHERE THERE IS STRONG POSS OF CONSIDERABLE(SEE ING 22)
RTECS #:9999999ZZ
Name:ING 21:EXPOSURE, WEAR COMPLETE ACID SUIT W/HOOD, BOOTS, &
GLOVES. IF ACID VAP/MIST ARE PRESENT AND EXPOS (SEE ING 23)
RTECS #:9999999ZZ
Name:ING 22:LIMITS MAY BE EXCEEDED, WEAR OSHA PERMISSIBLE
RESPIRATORY PROTECTION.
RTECS #:9999999ZZ
Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: >77.6%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
Fraction by Wt: 0-22%
Name:SUPP DATA:REDUCING/COMBUSTIBLE ORGANIC MATLS. HAZ GASES ARE
EVOLVED ON CONTACT W/CHEMICALS SUCH AS CYANIDES(SEE ING 4)
RTECS #:9999999ZZ
Name:ING 3:SULFIDES, AND CARBIDES. EFTS OF OVEREXP:ULCERATION.
INGEST OF LIQUID MAY CAUSE SEVERE BURNS TO MUCOUS (SEE ING 5)
RTECS #:9999999ZZ
Name:ING 4:MEMBRANES OF MOUTH AND ESOPHAGUS. REPEATED OR
PROLONGED CONTACT WITH MISTS MAY CAUSE EYE IRRITATION(SEE ING 6)
RTECS #:9999999ZZ
Name:ING 5:WITH DISCOMFORT, TEARING, OR BLURRING OF VISION; OR
SKIN IRRIT W/DISCOMFORT OR RASH. HUMAN HLTH EFTS (SEE ING 7)
RTECS #:9999999ZZ
Name:ING 6:OF OVEREXP BY INHAL MAY INCLUDE IRRIT OF UPPER RESP
PASSAGES OR EROSION OF DENTAL SURFACES. HIGHER (SEE ING 8)
RTECS #:9999999ZZ
Name:ING 7:EXPOS BY INHAL MAY LEAD TO TEMPORARY LUNG IRRIT
EFFECTS WITH COUGH, DISCOMFORT, DIFFICULTY BRTHNG, OR (SEE ING 9)
RTECS #:9999999ZZ
Name:ING 8:SHORTNESS OF BREATH; OR POSS MODEST INITIAL SYMPS,
FOLLOWED IN HOURS BY SEVERE SHORTNESS OF BREATH, (SEE ING 10)
RTECS #:9999999ZZ
Name:FIRST AID PROC:WATER CAN BE APPLIED. AVOID FREEZING TISS.
NOTE TO MD:CONTINUED WASHING OF AFFECTED AREA W/ (SEE ING 11)
RTECS #:9999999ZZ
Name:ING 10:COLD OR ICED WATER WILL BE HELPFUL IN REMOVING LAST
TRACES OF SULFURIC ACID. CREAMS/OINTMENTS SHOULD(SEE ING 12)
RTECS #:9999999ZZ
Name:ING 11:NOT BE APPLIED BEFORE OR DURING THE WASHING PHASE OF
TREATMENT. INHAL:REMOVE TO FRESH AIR IMMED/HAVE (SEE ING 13
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL-RAT)2140 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES SEVERE BURNS TO EYE/SKIN/ALL
BODY TISSUES. INHAL OF MIST MAY CAUSE LUNG DMG. THE CONC COMPOUND
IS CORROSIVE TO SKIN AND EYE OF ANIMALS. BY INGESTION IT IS
MODERATELY TOXIC IN ANIMALS CAUSING CO RROSION OF MUCOSAL SURFACES.
TOXIC EFTSDESCRIBED IN ANIMALS FROM SINGLE EXPOSURES BY INHAL
INCLUDE(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:RESP IRRIT. HUMAN HEALTH EFTS OF
OVEREXP TO THE LIQUID BY SKIN/EYE CONTACT MAY CAUSE EYE CORROSION
W/CORNEAL OR CONJUNCTIVAL ULCERATION; OR SKIN BURNS OR (SEE INGRED
4)
Medical Cond Aggravated by Exposure:INDIVUDIALS WITH PRE EXISTING
DISEASES OF LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO TOXICITY OF
EXCESSIVE EXPOSURES.
======================= First Aid Measures =======================
First Aid:EYE/SKIN:IMMEDIATELY (WITHIN SECONDS) FLUSH W/PLENTY OF WATER
(PREFERABLY COLD) FOR AT LEAST 15 MINS WHILE REMOVING CONTAM
CLOTHING AND SHOES. CALL MD. WASH CLTHNG BEFORE REUSE. WHILE
PATIENT IS BEING TRANSPORTED TO MED FACILITY, APPLY COMPRESSES OF
ICED WATER. IF MED TREATMENT MUST BE DELAYED, IMMERSE THE AFFECTED
AREA IN ICED WATER. IF IMMERSION IS NOT PRACTICAL, COMPRESSES OF
ICED (SEE ING 10)
===================== Fire Fighting Measures =====================
Flash Point:WILL NOT BURN
Extinguishing Media:MEDIA AS APPROPRIATE FOR COMBUST IN AREA. USE WATER
SPRAY TO COOL CNTNRS EXPOSED TO FIRE; DO NOT GET WATER INSIDE
CNTNRS
Fire Fighting Procedures:EVACUATE PRESONNEL TO SAFE AREA. KEEP
PERSONNEL REMOVED AND UPWIND OF FIRE. GENERATES HEAT UPON ADDITION
OF WATER, WITH POSS SPLATTERING. WEAR (SEE SUPP DATA)
Unusual Fire/Explosion Hazard:REACTS WITH MOST METALS, ESPECIALLY WHEN
DILUTE, TO GIVE FLAMMABLE, POTENTIALLY EXPLOSIVE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP FLOW IF POSS. REVIEW "FIRE AND EXPLOSION
HAZARDS"/"SAFETY PRECAUTIONS" BEFORE PROCEEDING WITH CLEAN UP. USE
APPROPRIATE PROT EQUIP. SOAK UP SMALL SPILLS W/DRY SAND,
CLAY/DIATOMACEOUS EARTH. DIKE LARGE SPILLS AND CAUTIOUSLY
DILUTE,(SEEING 15)
Neutralizing Agent:LIME OR SODA ASH.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP OUT OF SUN & AWAY FROM
HEAT/SPARKS/FLAME. KEEP CNTNR TIGHTLY CLOSED (DRUM) CLOSURE UP TO
PREVENT LEAKAGE. LOOSE CLOSURE CAREFULLY.(SEE INGRED 18)
Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID
BREATHING VAPOR/MISTS. KEEP CONTAINERS CLOSED. DO NOT ADD WATER TO
CONTENTS WHILE IN CONTAINER BECAUSE OF VIOLENT REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ACID VAPOR OR MIST ARE PRESENT AND EXPOSURE
LIMITS MAY BE EXCEEDED, WEAR NIOSH/MSHA APPROVED RESPIRATORY
PROTECTION.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE PROVIDED TO KEEP VAPOR
AND MIST CONCENTRATIONS BELOW THE EXPOSURE LIMITS.
Protective Gloves:ACID-PROOF GAUNTLET GLOVES.
Eye Protection:CHEM WORKERS GOG, MAY ADD(SEE INGRED 21)
Other Protective Equipment:APRON/BOOTS; LONG SLEEVE WOOL/ACRYLIC OR
POLYESTER CLOTHING; ACID PROOF SUIT AND HOOD. IN CASE OF EMER
OR(SEE INGRED 21)
Work Hygienic Practices:WASH THOROUGLY AFTER HANDLING.
Supplemental Safety and Health
FIRE FIGHT PROC:NIOSH/MSHA SCBA AND FULL PROTECTIVE CLOTHING. RUNOFF
FROM FIRE CONTROL MAY CAUSE POLLUTION. NEUTRALIZE RUNOFF WITH LIME,
SODA ASH, ETC. TO PREVENT CORROSION OF METALS AND FORMATION OF
HYDROGEN GAS. MATLS TO AVOID:NITRATES; PICRATES; STRONG OXIDIZING,
(SEE INGRED 3)
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:380F,193C
Melt/Freeze Pt:M.P/F.P Text:-31F,-35C
Vapor Pres:<0.3 @ 77F
Vapor Density:3.4
Spec Gravity:1.706
pH:<1
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:100%
Appearance and Odor:LIQ, COLORLESS TO LIGHT GRAY, OILY; CLEAR-TURBID,
ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
VIGOROUS REACTIONS OCCUR W/WATER; ALKALINE SOLUTIONS; METALS; METAL
POWDERS; CARBIDES; CHLORATES; FULMINATES(SUPP DATA)
Stability Condition to Avoid:REACTS VIOLENTLY WITH WATER AND ORGANIC
MATERIALS WITH EVOLUTION OF HEAT.
Hazardous Decomposition Products:RELEASES SULFUR DIOXIDE AT EXTREMELY
HIGH TEMPERATURES.
==================== Disposal Considerations ====================
Waste Disposal Methods:CLEANED-UP MATERIAL IS RCRA HAZARDOUS WASTE. DO
NOT FLUSH TO SURFACE WATER OR SANITARY SEWER SYSTEM. COMPLY WITH
FEDERAL, STATE, AND LOCAL REGULATIONS. IF APPROVED, NEUTRALIZE AND
TRANSFER TO WASTE TR EATMENT SYSTEM.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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