===================== Product Identification =====================
MSDS NAME:ORANGE, 5080U
NIIN:00N070369
MSDS Number: CBLRH
=== Responsible Party ===
Company:E I DU PONT DE NEMOURS & CO INC
Address:1007 MARKET ST
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
Preparer's Name:T R LOUER
CAGE:B0589
=== Contractor Identification ===
Company:DU PONT E I DE NEMOURS & CO FABRICATED PROD DEPT
Address:1007 MARKET ST BRANDYWINE BLDG 3332
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-3637
CAGE:90227
Company:E I DU PONT DE NEMOURS & CO
Address:RAKETSTRAAT, 100, RUE DE LA FUSEE
City:BRUSSEL
Country:BE
Phone:32-(0)15-401.505
CAGE:B0589
============= Composition/Information on Ingredients =============
Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Name:MOLYBDATE ORANGE; (LEAD CHROMATE MOLYBDATE)
CAS:12656-85-8
RTECS #:QA4660000
Fraction by Wt: 22%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:LEAD CHROMATE (VI) OXIDE; (LEAD CHROMATE)
CAS:18454-12-1
RTECS #:OF9800000
Fraction by Wt: 2%
OSHA PEL:1.0 MG/M3 (MFR)
ACGIH TLV:0.1 MG/M3 (MFR)
Name:ACRYLIC POLYMER
OSHA PEL:N/K
ACGIH TLV:N/K
Name:TOLUENE (SARA 313) (CERCLA) VP: 36.70
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 2%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ACETIC ACID, ETHYL ACETATE; (ETHYL ACETATE) (CERCLA) VP:
76.00
CAS:141-78-6
RTECS #:AH5425000
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE
GLYCOL MONOMETHYL ETHER ACETATE) VP: 3.70
CAS:108-65-6
RTECS #:AI8925000
OSHA PEL:10 PPM (MFR)
ACGIH TLV:10 PPM (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE NOSE & THROAT
IRRIT. RPTD & PRLNG OVEREXP TO SOLV MAY LEAD TO PERM BRAIN & NERV
SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ & LOSS OF COORD ARE SIGNS
THAT SOLV LEVELS ARE TOO HIGH. THIS PROD CANNOT BE APPLIED
SATISFACTORILY W/OUT ADDN OF ACTIVATOR WHICH CONTAINS ISOCYANATE.
(SEE APPROP MSDS FOR REC ACTIVATOR) EXPOS TO ISOCYANATES MAY CAUSE
RESP SENSIT. THIS EFT MAY BE PERM. SYM PS INCL ASTHMA-LIKE RXN
W/SHORTNESS OF BREATH, WHEEZING/COUGHING, WHICH MAY BE PERM. THIS
EFT MAY BE DELAYED FOR SEVERAL HRS AFTER EXPOS. RPTD OVEREXP TO
ISOCYANATES MAY CAUSE DECR IN LUNG FUNCTION WH ICH MAY BE PERM.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:MOLYBDATE ORANGE: IARC MONO ON
EVALUATION OF CARCIN RISK OF CHEMICALS TO MAN, VOL 49, PG 49, 1990:
GROUP 1. LEAD CHROMATE: IARC MONOGRAPHS ON THE EVALUATION OF
CARCINOGENIC RISK OF CHEMICALS, VOL 49, PG 49, 1990: GROUP 1. NTP
7TH ANNUAL REPORT ON CARCINOGENS, 1994: KNOWN TO BE CARCINOGENIC.
Effects of Overexposure:HLTH HAZ: INGEST: GI DISTRESS. EYES: MAY CAUSE
IRRIT/BURNING. SKIN: RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT
W/DISCOMFORT & DERM. CHRONIC: ING 1: IN LIFETIME INHAL TEST, LUNG
CANCERS WERE FOUND IN SOME RAT S EXPOSED TO 250 MG/M3 RESP TITANIUM
DUST. INGS 2/3: OVEREXP TO LEAD MAY CAUSE ADVERSE EFTS TO BLOOD
FORMING, NERV, URINARY, REPRO SYS INCL EMBRYOTOX EFTS. SYMPS MAY
INCL LOSS OF APPETITE, ANEMIA, DIS TURB OF SLEEP & FATG. SEE OSHA
LEAD STD 29CFR1910.1025. FOR EXPOS LONGER THAN 8 HRS, THE OSHA
EXPOS LIM IS REDUCED BY THIS FORMULA: LIM(IN MG/M3)=400/HRS WORKED
IN DAY. ING 5: RECURRENT OVEREXP MAY RS LT IN LIVER & KIDNEY
INJURY. (SUP DAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH LUNG OR BREATHING
PROBLEMS OR PRIOR REACTION TO ISOCYANATES MUST NOT BE EXPOSED TO
THE VAPORS OR SPRAY MIST OR THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP,
PREFERABLY MOUTH-TO-MOUTH. IF BRTHG DFCLT PERSISTS/OCCURS LATER,
CONSULT MD. EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15
MIN. CALL MD. SKIN: WASH W/SOAP & WATER. IF IRRIT OCCURS, CONT MD.
INGEST: GI DISTRESS. IN THE UNLIKELY EVENT OF INGEST, CALL MD IMMED
& HAVE NAMES OF INGS AVAILABLE.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>20F,>-7C
Lower Limits:1.3%
Upper Limits:13.1%
Extinguishing Media:USE FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO
PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASHPOINT, EMITS FLAMM
VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE. FINE
MIST/SPRAYS MAY BE FLAMMABLE AT TEMPS BELOW FLASHPOINT.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA. REMOVE SOURCES OF IGNIT. PVNT SKIN
CONT & BRTHG OF VAP. WEAR PROPERLY FITTED VAP/PARTICULATE RESP
(NIOSH/MSHA TC-23C). IF MATL HAS BEEN ACTIVATED W/ISOCYANATE, WEAR
POS-PRESS SUPP-AIR RESP (NIOSH/MSHA TC-19C). CONFINE & REMOVE
W/INERT ABSORB. DEACTIVATE ISOCYANATE CONTAINING SPILLS WITH: 20%
SURFACTANT (TERGITOL TMN-10), 80% WATER, OR 0-10% AMMONIA, 2-5%
DETERGENT, BALANCE WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING.
Other Precautions:DO NOT STORE > 120F. DO NOT SAND, FLAME CUT,
BRAZE/WELD DRY COATING W/OUT NIOSH/MSHA APPRVD RESP/APPROP VENT.
CONTAINS CHEMICALS KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH
DEFECTS/OTHER REPRODUCTIVE HARM (CALIFORNIA PROPOSITION 65).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WEAR POS-PRESS
SUPP-AIR RESP (NIOSH/MSHA TC-19C) WHILE MIXING ACTIVATOR W/ENAMEL,
DURING APPLICATION & UNTIL ALL VAPS & SPRAY MISTS ARE EXHAUSTED. DO
NOT PERMIT ANYONE W/OUT PROTECTION IN PAINTING AREA.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:COVERALLS. EMERGENCY EYEWASH & DELUGE SHOWER
MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING.
Supplemental Safety and Health
EFTS OF OVEREXP: HIGH AIRBORNE LEVELS HAVE PRODUCED IRREGULAR
HEARTBEATS IN ANIMALS & OCCAS PALPITATIONS IN HUMANS. RATS EXPOSED
TO VERY HIGH AIRBORNE LEVELS HAVE EXHIBITED HIGH FREQUENCY HEARING
DEFI CITS. SIGNIFICANCE OF THIS TO MAN IN UNKNOWN. ING 6: PRLNG &
RPTD HIGH EXPOS OF LAB ANIMALS RSLT IN (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>169F,>76C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.32
VOC Grams/Liter:4.9
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:62.6
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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