===================== Product Identification =====================
MSDS NAME:R5038 BROMOCRESOL GREEN/METHYL RED INDICATOR (500 ML)
NIIN:00N070366
MSDS Number: CBLRD
=== Responsible Party ===
Company:CALGON CORP
Box:1346
City:PITTSBURGH
State:PA
ZIP:15230-1346
Country:US
Info Phone Num:412-777-8000
Emergency Phone Num:412-777-8000
Preparer's Name:P.J. MALONEY
CAGE:86035
=== Contractor Identification ===
Company:CALGON CORP
Address:RT 60 AND CAMPBELLS RUN RD
Box:1346
City:PITTSBURGH
State:PA
ZIP:15230-1346
Country:US
Phone:412-494-8000
CAGE:86035
============= Composition/Information on Ingredients =============
Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313) VP:33 @ 68F;
VAP DENS:2.07; LD50(ORAL,RAT):5045 MG/KG
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 80%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL
Name:SUPDAT:NOSE & THROAT. ISOPROPANOL HAS GOOD WARNING
PROPERTIES BECAUSE IT CAUSES MILD IRRIT OF EYES, NOSE AND (ING 3)
RTECS #:9999999ZZ
Name:ING 2:THROAT AT CONC LEVEL OF 400 PPM. HUMAN SYSTEMIC EFTS
BY INGEST/INHAL INCLUDE FLUSHING, PULSE RATE DECR, (ING 4)
RTECS #:9999999ZZ
Name:ING 3:BLOOD PRESS LOWERING, ANESTHSIA, NARCOS, HDCH, DIZZ,
MENTAL DEPRESS, HALLUCINATIONS, DISTORTED PERCEPTIONS,(ING 5)
RTECS #:9999999ZZ
Name:ING 4:SHORTNESS OF BRTH, RESP DEPRESS, NAUS/VOMIT, COMA.
CHRONIC:NO APPLIC INFO WAS FOUND CONCERNING ANY POTNTL (ING 6)
RTECS #:9999999ZZ
Name:ING 5:HLTH EFTS RSLTING FROM SUBCHRONIC/CHRONIC EXPOS TO
PROD. ISOPROPANOL HAS DEMONSTRATED TERATOGENIC & REPRO (ING 7)
RTECS #:9999999ZZ
Name:ING 6:EFTS IN LAB ANIMALS. IN 9-DAY RATE PROBE STUDY FOR
LONGER TERM INHAL RESEARCH W/ISOPROPANOL, RPT OF (ING 8)
RTECS #:9999999ZZ
Name:ING 7:PRELIMINARY FINDINGS INDICATES KIDNEY DISORDER WAS
OBSERVED IN MALE RATS. TARGET ORGANS:EYE, SKIN, CNS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT ONE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:PROD MAY BE EXPECTED TO CAUSE
IRRIT UPON CONT. SYMPS MAY INCLUDE REDNESS, TEARING, STINGING
SENSATION & BLURRED VISION. PROD VAPS MAY ALSO IRRIT. SKIN:PROD MAY
CAUSE DRYING & CRACKING UPON PRLNGD/ RPTD CONT. ISOPROPANOL IS
ABSORBED BUT IS EXPECTED TO BE PRACTICALLY NON-TOX BY THIS RTE OF
EXPOS. NO (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:DATA WERE AVAIL TO SUGGEST PROD MAY
PRDCE ALLERGIC RXN. INGEST:HAS BEEN KNOWN TO CAUSE STOM CRAMPS,
NAUS, VOMIT, DIARR, HDCH & CNS DEPRESS SIMILAR TO ETHANOL INTOX.
SINGLE LETHAL DOSE OF ISO PROPANOL FOR HUMAN ADULT IS ABOUT 250 ML
ALTHOUGH AS LITTLE AS 100 ML CAN BE FATAL. THERE ARE, HOWEVER, RPTS
(SUPDAT)
Medical Cond Aggravated by Exposure:UNKNOWN.
======================= First Aid Measures =======================
First Aid:SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD .
EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. SEEK MEDICAL AID. INGESTION:DO NOT INDUCE VOMITING. SEEK
MEDICAL AID IMMEDIA TELY. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. INHALATION:REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. SEEK MEDICAL AID.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:65.0F,18.3C
Lower Limits:2%
Upper Limits:12.7%
Extinguishing Media:USE ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL
FIRE.
Unusual Fire/Explosion Hazard:PROD EMITS TOX GASES UNDER FIRE CNDTNS.
PROD VAPS ARE HVR/AIR & MAY TRAVEL CONSIDERABLE DIST TO SOURCE OF
IGNIT & FLASH BACK. THIS PRODUCT IS FLAM LIQUID.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF SPILL. REMOVE ALL SOURCES OF
IGNITION.. WEARING APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT,
CONTAIN SPILL, COLLECT ON INERT ABSORBENT AND PLACE INTO SUITABLE
CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, PROLONGED OR
REPEATED CONTACT WITH SKIN AND BREATHING VAPOR. USE WITH ADEQUATE
VENT. KEEP AWAY FROM HEAT, SPKS & FLAME.
Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. INSIDE STORAGE
SHOULD BE IN A STANDARD FLAMMABLE LIQUIDS STORAGE WAREHOUSE, ROOM
OR CABINET.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF AIRBORNE CONCENTRATIONS EXCEED PUBLISHED
EXPOSURE LIMITS, USE A NIOSH/MSHA APPROVED RESPIRATOR IN ACCORDANCE
WITH OSHA RESPIRATORY PROTECTION REQUIREMENTS (29 CFR 1910.134).
Ventilation:USE LOCAL AND/OR GENERAL EXHAUST VENTILATION TO MAINTAIN
AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES RECOMMENDED.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH:3.3-3.7. % VOLAT:>99 (WT). MATLS TO AVOID:HYDROGEN PEROXIDE SHARPLY
REDUCES AUTOIGNIT TEMP. EFTS OF OVEREXP:OF SERIOUS ILLNESS FROM AS
LITTLE AS 10 ML OF ISOPROPANOL TAKEN INTERNALLY. VOMIT W/ASPIR IS
SERIOUS THREAT & DANGEROUS COMPLICATION IN CLINICAL ISOPROPANOL
POISONINGS. INHAL:VAPS CAN CAUSE IRRIT OF (ING 2)
================== Physical/Chemical Properties ==================
Vapor Pres:SEE ING 1
Vapor Density:SEE ING 1
Spec Gravity:0.84
pH:SUPDAT
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, DEEP RED LIQUID WITH AN ALCOHOL ODOR.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ISOPROPANOL CAN REACT VIGOROUSLY W/OXIDIZERS & REACT W/OXYG TO FORM
DANGEROUSLY UNSTABLE PEROXIDES. CONT WITH (SUPDAT)
Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS AND FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION
MAY PRODUCE CARBON DIOXIDE AND CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCARDED PRODUCT, AS SOLD, WOULD BE CONSIDERED
A RCRA HAZARDOUS WASTE BASED ON THE CHARACTERISTIC OF IGNITABILITY.
THE EPA HAZARDOUS WASTE NUMBER IS D001. DISPOSE OF IN ACCORDANCE
WITH LOCAL, STATE A ND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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