===================== Product Identification =====================
MSDS NAME:ANILINE BLUE SOLUTION, HT15-4
NIIN:00N082777
MSDS Number: CGDPH
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:800-325-3010;314-771-5750
Emergency Phone Num:800-325-3010;314-771-5750
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:BENZENESULFONIC ACID, AMINOMETHYL((4-((SULFOPHENYL)
AMINO)PHENYL)(4-((SULFOPHENY)IMINO)-2,5-CYCLOHEXADIEN-1-YLIDENE)MET
HYL)-, DISODIUM SALT; (ANILINE BLUE WATER SOLUBLE CERTIFIED)
CAS:28631-66-5
RTECS #:DB4958000
Fraction by Wt: 2.40%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ACETIC ACID; (ACETIC ACID (CERCLA))
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 2.00%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAN BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION. PROLONGED OR
REPEATED EXPOSURE MAY CAUSE ALLERGIC REACTIONS IN CERTAIN SENSITIVE
INDIVIDUALS. TO THE BEST OF M FR'S KNOWLEDGE, THE CHEMICAL,
PHYSICAL,AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THROUGHLY
INVESTIGATED.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMED FLUSH W/COPIOUS AMTS OF WATER FOR @ LST 15
MINS WHILE REMOVING CONTAMD CLTHG & SHOES. INHAL: REMOVE TO FRESH
AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG.
INGEST: WA SH OUT MOUTH W/WATER PROVIDED PERSON ISCONSCIOUS. CALL
PHYS. WASH CONTAMINATED CLOTHING BEFORE REUSE.
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, WATER SPRAY.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPRVD RESP, CHEM SFTY GOGGS, RUBB
BOOTS & HEAVY RUBB GLOVES. ABSORB ON SAND/VERMICULITE & PLACE IN
CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH SPILL SITE
AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CAUTION: AVOID CONT & INHAL. DO NOT
BREATHE DUST. DO NOT GET IN EYES, ON SKIN, ON CLTHG. AVOID
PRLNGD/RPTD EXPOSURE. KEEP TIGHTLY CLOSED.
Other Precautions:STORE IN COOL DRY PLACE. IRRITANT. IRRITATING TO
EYES, RESP SYS & SKIN. WEAR SUITABLE PROT CLTHG.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROP NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:VERY DARK RED-BROWN POWDER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
NITROGEN OXIDES, SULFUR OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE/MIX MATL W/COMBUSTIBLE SOLV & BURN IN
CHEMICAL INCIN EQUIPPED W/AFTERBURNER & SCRUBBER. OBSERVE ALL
FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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