===================== Product Identification =====================
MSDS NAME:1602 ULTRA FLT BLACK, K01602
NIIN:00-054-1950
MSDS Number: CGDSF
=== Responsible Party ===
Company:KRYLON PRODUCTS GROUP
Address:31500 SOLON RD
City:SOLON
State:OH
ZIP:44139
Country:US
Info Phone Num:800-832-2541
Emergency Phone Num:216-566-2917
CAGE:IO479
=== Contractor Identification ===
Company:KRYLON PRODUCTS
Address:180 EAST BROAD ST
Box:City:COLUMBUS
State:OH
ZIP:43215
Country:US
Phone:614-431-6600;800-848-9400
CAGE:IO479
Company:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.
Address:26300 FARGO AVENUE
Box:City:BEDFORD HEIGHTS
State:OH
ZIP:44146
Country:US
Phone:216-292-7400 OR 216-595-8634
CAGE:09800
============= Composition/Information on Ingredients =============
Name:PROPANE. VP: 760.00
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 14%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9495
Name:BUTANE. VP: 760.00
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 6%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM; 9495
Name:TOLUENE (SARA 313) (CERCLA). VP: 22.00
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 33%
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ACETONE (SARA 313) (CERCLA). VP: 180.00
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 32%
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL;9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AMORPHOUS SILICA GEL; (AMORPHOUS PRECIPITATED SILICA)
CAS:112926-00-8
Fraction by Wt: 2%
OSHA PEL:6 MG/M3 AS D (MFR)
ACGIH TLV:2 MG/M3 (MFR)
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 2%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9495
Name:SUPDAT:ASSOCIATED REPEATED & PROLONGED OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
RTECS #:9999999ZZ
Name:OTHER PREC:IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING &
GROUNDING PROC. CONTENTS UNDER PRESS. DO NOT PUNCTURE, (ING 9)
RTECS #:9999999ZZ
Name:ING 8:INCINERATE, OR EXPOSE TO TEMP ABOVE 120F. HEAT FROM
SUNLIGHT, RADIATORS, STOVES, HOT WATER, & OTHER HEAT (ING 10)
RTECS #:9999999ZZ
Name:ING 9:SOURCES COULD CAUSE CONTAINER TO BURST. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN. (ING 11)
RTECS #:9999999ZZ
Name:ING 10:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. (ING 12)
RTECS #:9999999ZZ
Name:ING 11:CALIFORNIA PROPOSITION 65:WARNING:THIS PRODUCT
CONTAINS CHEMICALS KNOWN TO THE STATE OF CA TO CAUSE (ING 13)
RTECS #:9999999ZZ
Name:ING 12:CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
RTECS #:9999999ZZ
Name:VENT:EXPOSURE LIMITS. REFER TO OSHA STANDARDS 1910.94,
1910.107, 1910.108.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TOLUENE APPEARS ON THE NAVY LISTING OF
OCCUP CHEM REPROD HAZ. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . ACUTE: IRRIT OF EYES, S KIN & RESP SYS. MAY CAUSE NERVOUS
SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCONSCIOUSNESS & (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS, VOL 65, PG
24-27, 1995: GROUP 2B.
Effects of Overexposure:HLTH HAZ:POSSIBLY DEATH. SIGNS & SYMPS OF
OVEREXP:HDCH, DIZZ, NAUS, & LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCHING/BURNING
SENSATION MAY INDICATE EYE/ EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG
OVEREXP TO SOLV INGRED IN INGRED SECTION MAY CAUSE ADVERSE EFFECTS
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:IF AFFECTED, REMOVE FROM EXPOS. RESTORE BRTHG. KEEP
WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER.
REMOVE CONTAMD CLTHG & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LRG AMTS
OF H*2O F OR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO
NOT INDUCE VOMIT. GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER.
SEEK MEDICAL ATTN.
===================== Fire Fighting Measures =====================
Flash Point:<0F,<-18C
Lower Limits:1.0%
Upper Limits:12.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF.
H*2O MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, &
OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFS REQS SPECIAL (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP
& SPRAY MIST. AVOID CNTCT W/SKIN & EYES. KEEP AWAY FROM HEAT,
SPARKS & OPEN FLAME.
Other Precautions:VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY.
DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENT-DO NOT
SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN OFF STOVES,
ELECTRIC TOOLS & APPLICAN CES, & ANY OTHER SOURCES OF (ING 8)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATERIALS IN INGR ED SECTION.
Ventilation:LOC EXHST PREF. GENL EXHST ACCEPTABLE IF THE EXPOS TO MATLS
IN INGRED SECTION IS MAINTAINED BELOW APPLIC (ING 14)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA. .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNITION/EXPLOSION
WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:PRECS. DURING EMER CNDTNS
OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMME
DIATELY APPARENT. OBTAIN MED ATTN. EFTSOF OVEREXP:TO LIVER,
URINARY, CARDIOVASCULAR & REPROD SYS. RPTS HAVE (ING 7)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE ING
Vapor Density:HVR/AIR
Spec Gravity:0.78
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:91
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
THE RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM THE APPPLIC EPA HAZ WASTE NUMBERS. DO NOT INCIN.
DEPRESSURIZE CNTNR. DISPOSE OF I/ A/W/FED, STATE, & LOCAL REGS
REGARDING POLLUTION.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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