=====================  Product Identification  =====================

MSDS NAME:RISTON-4700 SERIES PHOTOPOLYMER FILMS, (VAPORS)
NIIN:00N078802
MSDS Number: CGGPG
=== Responsible Party ===
Company:E I DUPONT DE NEMOURS & CO INC
Address:1007 MARKET ST
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
CAGE:0ERJ7
=== Contractor Identification ===
Company:E I DUPONT DE NEMOURS & CO, INC.
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515
CAGE:0ERJ7
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873

=============  Composition/Information on Ingredients  =============

Name:BENZOPHENONE
CAS:119-61-9
RTECS #:DI9950000
Fraction by Wt: 60-100%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:N,N-DIMETHYLBENZOCAINE; (ETHYL-4-DIMETHYL-AMINO BENZOATE)
CAS:10287-53-3
Fraction by Wt: 1-5%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:ETHYL ALCOHOL; (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 1-10%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM

Name:SUCCINONITRILE, TETRAMETHYL-; (TETRAMETHYL SUCCINONITRILE)
CAS:3333-52-6
RTECS #:WN4025000
Fraction by Wt: 1-10%
OSHA PEL:0.5 PPM, S
ACGIH TLV:0.5 PPM, S

Name:METHACRYLIC ACID, METHYL ESTER; (METHYL METHACRYLATE) 
    (SARA 313) (CERCLA)
CAS:80-62-6
RTECS #:OZ5075000
Fraction by Wt: 1-5%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 1-2%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:POLYOL ACRYLATE MONOMERS
Fraction by Wt: 1-5%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:SUPDAT:HDCH/WEAK. SKIN PERMEATION MAY OCCUR IN AMTS CAPABLE
    OF PRDCG EFTS OF SYSTEMIC TOX. ING 5:THIS CMPDS IS A (ING 9)
RTECS #:9999999ZZ

Name:ING 8:SKIN, EYE, NOSE & THROAT IRRIT & CAN CAUSE ALLERGIC
    SKIN RASHES. SKIN PERMEATION CAN OCCUR. ING 6:THIS (ING 10)
RTECS #:9999999ZZ

Name:ING 9:CMPD MAY IRRIT SKIN, EYES, NOSE & THROAT. INHAL MAY
    CAUSE NAUS, HDCH, WEAK, DIZZ, CONFUSN, INCOORD & LOSS (ING 11)
RTECS #:9999999ZZ

Name:ING 10:OF CONSCIOUSNESS. INGEST MAY CAUSE UPPER ABDOM PAIN,
    "HEART BURN", NAUS, VOMIT & DIARR. HIGH & PRLNG (ING 12)
RTECS #:9999999ZZ

Name:ING 11:EXPOS MAY CAUSE LIVER, KIDNEY/NEUROLOGICAL EFTS &
    HEART IRREGS. GROSS OVEREXP MAY CAUSE DEATH. ING 7:THIS(ING 13)
RTECS #:9999999ZZ

Name:ING 12:CLASS OF MATLS CAUSES SKIN & RESP IRRIT. SOME MAY BE
    SKIN SENSITIZERS. VAP CONDENSATE:CAUSES EYE, SKIN & (ING 14)
RTECS #:9999999ZZ

Name:ING 13:RESP IRRIT. CONDENSATE WILL CNTN HIGHER PERCENTAGES
    OF LESS VOLAT COMPONENTS INCL POLYOL ACRYLATE (ING 15)
RTECS #:9999999ZZ

Name:ING 14:MONOMERS WHICH MAY CAUSE DELAYED SKIN BURNS & MAY
    CAUSE SKIN SENSIT. TOLUENE IS KNOWN BY THE STATE OF (ING 16)
RTECS #:9999999ZZ

Name:ING 15:CALIFORNIA AS REPRO TOXIN. NOTE:TOLUENE APPEARS ON
    NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION (ING 17)
RTECS #:9999999ZZ

Name:ING 16:FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ
    LIST INFO & SAFE HNDLG & EXPOS INFO .
RTECS #:9999999ZZ

Name:OTHER PREC:LEVELS & CAPABLE OF PROVIDING SAFE ENVIRON FOR
    WORKERS. OTHER LAMINATORS & DESIGNS SHOULD BE TESTED (ING 19)
RTECS #:9999999ZZ

Name:ING 18:FOR ADEQUACY OF VENT. FOR FURTHER INFO REGARDING
    SAFE USE OF THIS MATL, PLEASE REFER TO DUPONT TECHNICAL (ING 20)
RTECS #:9999999ZZ

Name:ING 19:BULLETIN "HANDLING PROCEDURE FOR DUPONT PHOTOPOLYMER
    FILMS" (H-43328).
RTECS #:9999999ZZ

Name:VENT:MIN VAP GENERATION. LAMINATORS USED TO APPLY RISTON
    (A) FILMS SHOULD BE DESIGNED W/ADEQ VENT TO EXHST THESE(ING 22)
RTECS #:9999999ZZ

Name:ING 21:VAPORS FROM THE WORKPLACE.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:SKIN CONT W/VAPS OR VAP CONDENSATE MAY
    CAUSE IRRIT W/DISCOMFORT OR RASH; OR ALLERGIC RASHES. EYE CONT
    W/VAPS MAY CAUSE IRRIT W/DISCOMFORT, TEARING/BLURRING OF VISION.
    INHAL OF VAPS MAY CAUSE IRRIT OF  UPPER RESP PASSAGES, W/COUGH &
    DISCOMFORT. PRLNG INHAL OF VAPS MAY PRDCE NONSPECIFIC DISCOMFORT,
    SUCH (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:AS NAUS, HDCH/WEAK. ING 1:THIS CMPD
    MAY CAUSE SKIN, EYE, NOSE & THROAT IRRIT. SKIN CONT MAY CAUSE RASH.
    SKIN PERMEATION MAY OCCUR IN TOX AMTS. ING 2:THIS CMPD IS SKIN,
    EYE, NOSE & THROAT IRRI T. ING 3:THIS CMPD MAY CAUSE SKIN, EYE &
    THROAT IRRIT. PRLNG SKIN EXPOS CAN CAUSE DEFAT & ALLERGIC RASHES.
    (SUPP DATA)
Medical Cond Aggravated by Exposure:INCREASED SUSCEPTIBILITY TO THE
    EFFECTS OF THIS MATERIAL MAY BE OBSERVED IN PERSONS W/PRE-EXISTING
    DISEASES OF THE CENTRAL NERVOUS SYSTEM.

=======================  First Aid Measures  =======================

First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR
    IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
    BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. SKIN:FLUSH W/WATER
    AFTER CONTA CT. WASH CONTAMINATED CLOTHING BEFORE REUSE.
    EYES:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES.
    CALL MD.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:FOAM, DRY CHEMICAL, CO*2.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION CAN LEAD TO
    EVOLUTION OF IRRITATING VAPORS OR GASES.

==================  Accidental Release Measures  ==================

Spill Release Procedures:NOTE:REVIEW FIRE FIGHTING MEASURES & HNDLG
    (PERS) SECTIONS BEFORE PROCEEDING W/CLEAN-UP. USE APPROP PPE DURING
    CLEAN-UP. FOR CONDENSATE, SOAK UP W/INERT ABSORB MATL & PLACE IN
    WASTE CONTAINER FOR DISP OSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:VAPS MAY CONDENSE ON COLD SURFS NEAR
    AREA WHERE FILM IS HEATED/LAMINATOR EXHST DUCT. CHECK THESE SURFS
    FOR CONDENSATE BUILD-UP. CLEAN OFTEN W/(SUPDAT)
Other Precautions:AVOID BRTHG VAPS/MIST. AVOID CONT W/EYES, SKIN/CLTHG.
    CONTROL OF RESIST VAPS W/DUPONT LAMINATOR THAT IS INSTALLED,
    OPERATED & MAINTAINED I/A/W PUBLISHED INSTRUCTIONS ASSURES THAT
    AIRBORNE CONCS WILL B E MAINTAINED AT EXTREMELY LOW (ING 18)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH APPROVED SELF-CONTAINED BREATHING
    APPARATUS FOR FIRE FIGHTING & MIST OR SPRAY EXPOSURES, IF
    NECESSARY.
Ventilation:USE SUFFICIENT EXHST ON LAMINATORS TO KEEP EXPOS BELOW REC
    LIMS. LAMINATOR TEMP SHOULD BE MAINTAINED <125C TO (ING 21)
Protective Gloves:NEOPRENE GLOVES; BEFORE REMOVING(SUPDAT)
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
    ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY W/SOAP & WATER AFTER HANDLING
    CONDENSATE OR WIPES.
Supplemental Safety and Health
APPEAR/ODOR:EXHST VENT. VAPS MAY CONDENSE AS CLEAR YELLOW LIQ; MILD
    ACRYLIC ODOR. HNDLG/STOR PREC:CLOTH BARELY MOISTENED W/ISOPROPYL
    ALCOHOL. PROT GLOVES:GLOVES, DECONTAM BY WASHING W/SOAP & WATER. EF
    TS OF OVEREXP:ING 4:THIS CMPD MAY CAUSESKIN IRRIT W/DISCOMFORT OR
    RASH; NONSPECIFIC DISCOMFORT, SUCH AS NAUS, (ING 8)

==================  Physical/Chemical Properties  ==================

Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:VAPS ARE NORMALLY COLORLESS, BUT MAY APPEAR AS
    WHITE SMOKE IN ABSENCE OF(SUPDAT

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HAZ GASES/VAPS PRDCD ARE CARBON
    MONOXIDE, CARBON DIOXIDE & OXIDATION INTERMEDIATES FOR INCOMPLETE
    COMBUST/BURNING.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
    REGULATIONS . WHEN REQUIRED, VAPOR DISCHARGES TO ATMOSPHERE SHOULD
    BE PROPERLY PERMITTED.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***