===================== Product Identification =====================
MSDS NAME:LEAD/ACID STORAGE BATTERY, NW25811
NIIN:01-304-3215
MSDS Number: CGLGF
=== Responsible Party ===
Company:DOUGLAS BATTERY MFG CO
Address:500 BATTERY DR
Box:12159
City:WINSTON-SALEM
State:NC
ZIP:27117
Country:US
Info Phone Num:919-650-7000
Emergency Phone Num:800-424-9300(CHEMTREC) 800-368-4527
Preparer's Name:ALAN L. CSONTAS
CAGE:63432
=== Contractor Identification ===
Company:DOUGLAS BATTERY MFG CO
Address:500 BATTERY DR
Box:12159
City:WINSTON-SALEM
State:NC
ZIP:27107
Country:US
Phone:800-368-4527
CAGE:63432
Company:NORTHWESTERN MOTOR CO INC
Address:1125 STARR AVE
Box:265
City:EAU CLAIRE
State:WI
ZIP:54702
Country:US
Phone:715-835-3151
CAGE:44185
============= Composition/Information on Ingredients =============
Name:LEAD (SARA 313) (CERCLA)/LEAD OXIDE/LEAD SULFATE
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 60%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1025
ACGIH TLV:0.05MG/M3, A3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:ANTIMONY (SARA 313) (CERCLA)
CAS:7440-36-0
RTECS #:CC4025000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG (SB)/M3; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ARSENIC (SARA 313) (CERCLA)
CAS:7440-38-2
RTECS #:CG0525000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1018
ACGIH TLV:0.01 MG/M3, A1; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 10-38%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:CALCIUM, METAL
CAS:7440-70-2
RTECS #:EV8040000
Fraction by Wt: <0.15%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:REP CONTACT W/H2SO BATT ELECTROLYTE
FLUID MAY CAUSE SKIN DRYING WHICH MAY RESULT IN IRRIT/DERM.PROL
MIST OF H2SO4 INHAL CAN CAUSE INFLAMM OF UPPER RESP TRACT LEADING
TO CHRONIC BRONCHITIS.SHORT TERM L IQ/VAP CONTACT MAY RESULT IN EYE
IRRIT/ACID BURNS.PROL CONTACT TO STRONG ACID FUMES MAY RESULT IN
TEETH ENAMEL EROSION.
Explanation of Carcinogenicity:PER MSDS:CA PORP 65.EPA- YES.IARC-STRONG
INORG ACID MSIT W/H2SO4-CATELOG 1.DOESNT APPLY TO LIQ FORMS/SOLNS
IN BATT.
Effects of Overexposure:ACID CAN CAUSE IRRIT OF
EYES,NOSE,THROAT.BREATHING MIST PRODUCES RESPIRATORY
DIFFICULTY,CONTACGT W/SKIN/EYES CAUSES IRRIT & SKIN BURN.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SULFURIC ACID:INHAL:MOVE TO VENTILATED AREA.OBTAIN MED
ATTN.EYE:WASH W/COPIOUS QUANTITIES OF RUNNING WATER FOR
15MINS.OPBTAIN MED ATTN.SKIN:FLUSH AREA W/LG AMTS OF RUNNING
WATER.REMOVE COTNAM CLOTH & OBTAIN MED ATTN.INGEST:WASH OUT MOUTH
W/RUNNING WATER.DONT INDUCE VOMITING.CALL PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NA
Autoignition Temp:Autoignition Temp Text:SUPPL
Lower Limits:4.1 HYDROGEN
Upper Limits:74.2 H2
Extinguishing Media:HALON,DRY CHEMICAL.
Fire Fighting Procedures:BATT DONT BURN/BURN W/DIFFIC.EXT FIRE W/AGENT
SUITABLE FOR SURROUNDING COMBUST MATLS.COOL EXT OF BATT IF EXPO TO
FIRE TO PREVENT RUPTURE.ACID MIST/VAP(OTHR PRE)
Unusual Fire/Explosion Hazard:H2/H2SO4 VAP GENERATED UPON
OVERCHARGING.H2 FLAMM/EXPLO WHEN MIX W/AIR,OXY,CHLORINE.ENSURE
ADEQUATE VENTI OF CHARGING AREAS CONSISTENT W/29CFR1910,1926,(OTH
PR)
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROT CLOTHING.VENTI ENCLSD AREAS.DIKE TO
CONTAIN CONTAM MATLS & LIQS.LIMIT SITE ACCESS TO EMERG
RESPONDERS.NEUTRALIZE W/SODIUM BICARBONATE,SODA ASH,LIME,OTHER
NEUTALIZING AGENT.
Neutralizing Agent:SODA BICARBONATE,SODA ASH,SAND OR LIME.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FRM FLAMES DURING/IMMED AFT
CHARG.COMBUST/OVERCHAR MAY CREATE/LIBERATE TOXIC/HAZ GAS/LIQ
INCLUDE H2,H2SO4 MIST,SO2,SO3,STIBINE,ARSINE,H2SO4.
Other Precautions:STORE IN COOL DRY WELL VENTI AREA.DONT SHORT CIRCUIT
TERM/REMOFE VENT CAPS DUR STORAGE/RECAHARG. FIREFIGHT:GEN BY
HEAT/FIRE CORR.WEAR RESP PROT(SCBA)/PROT CLOTH.
FIRE/EXPLO:NFC,ACGIH,OTHER RELEVANT ST DS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SULFURIC ACID MIST-FULL FACE OR HALF MASK
RESPIRATOR W/ACID MIST FILTER OR SCBA.
Ventilation:CHANGE AIR EVERY 15MINS.LOC EXHAU:NO.MECHANICAL(GEN):NO
INFO FOUND.
Protective Gloves:ACID RESISTANT RUBB OR PLASTIC
Eye Protection:GOGGLES OR FACE SHIEL
Other Protective Equipment:ACID-RESISTANT RUBBER OR PLASTIC APRON,BOOTS
& PROTECTIVE CLOTHING.
Work Hygienic Practices:AVOID PROL OVERCHARGE.SODA BICARBONATE,SODA
ASH,SAND,LIME SHOULD BE KETP ON-SITE FOR SPILL REMEDIATION.
Supplemental Safety and Health
ELECTROLYTE:BOIL PT:275F;VAP PRESS 1MMHG@145.8F;SPEC GRAV
1.080-1.400.METL PT POLYPROPYLENE >320F.VAP PRESS
HYDROGEN=0.069,ELECTROLYTE=3.4. APPEARANCE:LIQUID,COLORLESS,OILY
FLUID;ACID ODOR WHEN HOT OR CHARGING BATT. AUTOIGN 675F
POLYPROPYLENE. DISPO:ENVIRO OFFICIALS FOR PROPER DISPO REQMTS.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:SUPPLEMENT
Melt/Freeze Pt:M.P/F.P Text:SUPPLEMENTA
Decomp Temp:Decomp Text:NP
Vapor Pres:SUPPLEMENT
Vapor Density:SUPPLEMENT
Spec Gravity:SUPPLEMENTAL
pH:<2
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:100% SOLUB ELECTROLY
Appearance and Odor:BATT-POLYPROPYLENE,HARD RUBB CASE,SOLID;PB-GRAY
METALLIC SOLID;ELECTOLYETE(SUPP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SPARKS,OPEN FLAMES.KEEP BATTERY CASE AWAY FROM STRONG OXIDIZERS.
Stability Condition to Avoid:AVOID OVERCHARGING & SMOKING, OR SPARKS
NEAR BATTERY SURFACE.
Hazardous Decomposition Products:AN EXPLO HYDROGEN/OXYGEN MIXTURE W/IN
BATTERY MAY OCCUR DURING CHARGING.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTAINS TOXIC CHEM SUBJ TO REPORTING REQMTS OF
SEC 313 TITLE II SARA/40CFR372.RETURN WHLE SCRAP BATT TO
DISTRIBUTOR/MFG/PB SMELTER FOR RECYCL.NEUTRA SPILLS PLACE RESIDUE
INTO CNTRNS W/SORBENT MATL,SA ND,EARTH FOR DISPO.CONTACT LOC &/OR
STATE(SUPPLE)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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