===================== Product Identification =====================
MSDS NAME:PETROLEUM ETHER
NIIN:00-753-4990
MSDS Number: CGLDG
=== Responsible Party ===
Company:MALLINCKRODT/BAKER
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865-2219
Country:US
Info Phone Num:908-859-2151
Emergency Phone Num:908-859-2151 800-424-9300(CHEMTREC)
CAGE:LO895
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
Company:MALLINCKRODT/BAKER
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865-2219
Country:US
Phone:908-859-2151
CAGE:LO895
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:VM&P NAPHTHA (LIGROINE)
CAS:8032-32-4
RTECS #:OI6180000
Fraction by Wt: 90-100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS >25 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HIGH VAPOR LEVELS MAY CAUSE EYE
IRRITATION. THE LIQUID IS SLIGHTLY IRRITATING TO THE SKIN.
PROLONGED OR REPEATED CONTACT CAN RESULT IN DEFATTING AND DRYING
WHICH MAY RESULT IN SKIN IRRITATION AND DERM ATITIS. INHALATION OF
VAPORS MAY BE IRRITATING TO NOSE & LUNGS. MAY CAUSE CNS DEPRESSION.
INGESTION MAY CAUSE VOMITING
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE, SKIN & RESPIRATORY TRACT IRRITATION.
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION MAY BE EVIDENCED BY
GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA. IN EXTREME CASES,
UNCONSCIOUSNESS AND DEATH MAY OCCUR. ASPIRATION OF VOMITUS INTO
THE LUNGS MAY CAUSE COUGHING, LABORED BREATHING, CYANOSIS AND IN
SEVERE CASES, DEATH.
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT.
======================= First Aid Measures =======================
Eyes: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH
SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION. INHALA TION: REMOVE TO FRESH AIR. GIVE MOUTH-TO-MOUTH
RESUSCITATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION:
DO NOT INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS.
GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:-0F,-18C
Autoignition Temp:Autoignition Temp Text:550F
Lower Limits:1.1
Upper Limits:5.9
Extinguishing Media:CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.WATER MAY BE
AN INEFFECTIVE EXTINGUISHANT.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS.COOL
FIRE EXPOSED CONTAINERS WITH WATER FOG.AVOID CONTAMINATION OF
WATERWAYS BY FIRE CONTROL WATER RUNOFF.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.SEALED CONTAINERS MAY
RUPTURE.STATIC SENSITIVE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. WEAR
APPROPRIATE RESPIRATOR & PROTECTIVE CLOTHING. SHUT OFF SOURCE OF
LEAK IF SAFE TO DO SO. DIKE TO CONTAIN. REMOVE WITH VACUUM OR PUMP
TO STORAGE/SALVAGE VESSELS. ABSO RB RESIDUE WITH INERT MATERIAL.
WATER FLUSH AREA.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP LIQUID/VAPOR AWAY FROM HEAT,
SPARKS & FLAME. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE WITH
ADEQUATE VENTILATION. IGNITED VAPORS MAY EXPLODE.
Other Precautions:"EMPTY" CONTAINERS CAN CONTAIN EXPLOSIVE VAPORS. DO
NOT CUT, DRILL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS ON OR
NEAR CONTAINERS. STATIC ELECTRICITY MAY ACCUMULATE AND CREATE A
FIRE HAZARD. GROUND CONTAINERS, FIXED & TRANSFER EQUIPMENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS.
IF EXPOSURE EXCEEDS OCCUPATIONAL EXPOSURE LIMITS, USE A NIOSH/MSHA
APPROVED RESPIRATOR. EITHER AN AIR-SUPPLIED OR AIR-PURIFYING
RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES IS RECOMMENDED.
Ventilation:USE EXPLOSION-PROOF LOCAL AND/OR MECHANICAL VENTILATION.
AVOID OPEN ELECTRICAL SOURCES NEAR PRODUCT VAPOR AREAS.
Protective Gloves:NEOPRENE, NITRILE, OR POLYVINYL ALCOHOL
Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:INDUSTRIAL WORK CLOTHING TO MINIMIZE
CONTACT. RUBBER APRON AD BOOTS AS REQUIRED. EYE BATH AND SAFETY
SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USING PRODUCT AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
UNDER EPA-CWA, THIS PRODUCT IS CLASSIFIED AS AN OIL UNDER SECTION 311.
SPILLS INTO OR LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE
REPORTED TO THE NATIONAL RESPONSE CENTER, 800-424-8802. UNDER
EPA-CERCLA, RELEASES TO AIR, LAND OR WATER MAY BE REPORTABLE TO THE
NATIONAL RESPONSE CENTER, 800-424-8802.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:68-167F
Melt/Freeze Pt:M.P/F.P Text:<-99F,<-73C
Vapor Pres:40
Vapor Density:2.5
Spec Gravity:0.6-0.75
Evaporation Rate & Reference:10 (N-BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR COLORLESS LIQUID WITH ODOR OF GASOLINE OR
KEROSENE.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.PRODUCT WILL ATTACK RUBBER,PLASTICS AND
COATINGS.
Stability Condition to Avoid:HIGH HEAT, SUNLIGHT, STATIC DISCHARGE,
OPEN FLAMES AND OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:IF THIS PRODUCT BECOMES A WASTE MATERIAL, IT
WOULD BE AN IGNITABLE HAZARDOUS WASTE, NUMBER D001. REFER TO LATEST
EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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