=====================  Product Identification  =====================

MSDS NAME:ROUNDUP ULTRA HERBICIDE, MON 65005
NIIN:00N085083
MSDS Number: CGZYB
=== Responsible Party ===
Company:MONSANTO CO
Address:800 NORTH LINDBERGH BLVD
City:ST LOUIS
State:MO
ZIP:63167
Country:US
Info Phone Num:800-332-3111
Emergency Phone Num:314-694-4000
CAGE:76541
=== Contractor Identification ===
Company:MONSANTO COMPANY
Address:800 N LINDBERGH BLVD
Box:City:SAINT LOUIS
State:MO
ZIP:63167
Country:US
Phone:314-694-6661 OR 800-332-3111
CAGE:76541

=============  Composition/Information on Ingredients  =============

Name:GLYCINE, N-(PHOSPHONOMETHYL)-, COMPD. WITH 2-PROPANAMINE
    (1:1); (N-(PHOSPHNOMETHYL)GLYCINE, MONOISOPROPYLAMINE SALT)
CAS:38641-94-0
RTECS #:MC1080000
Fraction by Wt: 41%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:INERT INGREDIENTS
Fraction by Wt: 59%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:SUP DAT: COULD FLASH OR EXPLODE, CAUSING SERIOUS PERSONAL
    INJURY. IF IGNITED BY OPEN FLAME, SPARK, WELDER'S (ING 4)
RTECS #:9999999ZZ

Name:ING 3: TORCH, LIGHTED CIGARETTE OR OTHER IGNITION SOURCE.
RTECS #:9999999ZZ

Name:EFTS OF OVEREXP: 0139 EXHIBITED SLIGHT BODY WT CHANGES.
    FOLLOWING RPTD SKIN EXPOS (3-WK) TO MON 0139, SKIN IRRIT (ING 6)
RTECS #:9999999ZZ

Name:ING 5: WAS PRIMARY EFT IN RABBITS. ADDNL TOX INFO IS AVAIL
    ON GLYPHOSATE, ACTIVE ING OF MON 0139. FOLLOWING RPTD (ING 7)
RTECS #:9999999ZZ

Name:ING 6: EXPOS (90-DAYS) TO GLYPHOSATE IN THEIR FEED, DECRD
    WT GAINS WERE NOTED AT HIGHEST TEST LEVEL IN MICE. (ING 8)
RTECS #:9999999ZZ

Name:ING 7: FOLLOWING RPTD SKIN EXPOS (3 WK) TO GLYPHOSATE,
    SLIGHT IRRIT WAS PRIMARY EFT OBSERVED IN RABBITS. REDUCED (ING 9)
RTECS #:9999999ZZ

Name:ING 8: BODY WT GAIN & EFTS ON LIVER TISS WERE OBSERVED
    W/LONG-TERM (2-YR) FEEDING OF GLYPHOSATE TO MICE AT HIGH (ING 10)
RTECS #:9999999ZZ

Name:ING 9: DOSE LEVEL IN 1 LONG-TERM (2-YR) FEEDING STUDY
    W/RATS. BASED ON RSLTS FROM CHRONIC STUDIES, EPA HAS (ING 11)
RTECS #:9999999ZZ

Name:ING 10: CLASSIFIED GLYPHOSATE IN CATEGORY E (EVIDENCE OF
    NON-CARCIN FOR HUMANS). GLYPHOSATE WAS FED CONTINUOUSLY(ING 12)
RTECS #:9999999ZZ

Name:ING 11: TO RATS AT VERY HIGH DOSE LEVELS FOR 2 SUCCESIVE
    GENERATIONS. TOX WAS REPORTED IN OFFSPRING FROM HIGH (ING 13)
RTECS #:9999999ZZ

Name:ING 12: DOSE, LEVEL WHICH ALSO PRDCED ADVERSE EFTS ON
    MOTHERS.
RTECS #:9999999ZZ

Name:SPILL PROC: OTHER IMPERVIOUS SURF SHOULD BE CONTAINED/DIKED
    & THEN ABSORBED W/ATTAPULGITE, BENTONITE/OTHER (ING 15)
RTECS #:9999999ZZ

Name:ING 14: ABSORB CLAYS. COLLECT CONTAM ABSORB, PLACE IN METAL
    DRUM & DISP OF I/A/W INSTRUCTIONS GIVEN IN DISP. (ING 16)
RTECS #:9999999ZZ

Name:ING 15: THORO SCRUB FLOOR/OTHER IMPERVIOUS SURF W/STRONG
    INDUS DETERGENT & RINSE W/WATER. LGE SPILLS THAT SOAK (ING 17)
RTECS #:9999999ZZ

Name:ING 16: INTO GROUND SHOULD BE DUG UP, PLACED IN METAL DRUMS
    & DISP OF I/A/W INSTRUCTIONS GIVEN UNDER DISP. (ING 18)
RTECS #:9999999ZZ

Name:ING 17: CONT APPROP STATE AGENCY WHEN CONSIDERING LAND
    SPREADING DISP OPTION. LEAKING CONTRS SHOULD BE SEPARATED(ING 19)
RTECS #:9999999ZZ

Name:ING 18: FROM NON-LEAKERS & EITHER CONTR/ITS CONTENTS
    TRANSFERRED TO DRUM/OTHER NON-LEAKING CONTR & DISP OF I/A/W(ING 20)
RTECS #:9999999ZZ

Name:ING 19: INSTRUCTIONS GIVEN UNDER DISP. ANY RECOVERED
    SPILLED LIQUID SHOULD BE SIMILARLY COLLECTED & DISPOSED OF.
RTECS #:9999999ZZ

Name:OTHER PREC: DO NOT APPLY DIRECTLY TO WATER, TO AREAS WHERE
    SURF WATER IR PRESENT/TO INTERTIDAL AREAS BELOW MEAN (ING 22)
RTECS #:9999999ZZ

Name:ING 21: HIGH WATER MARK. DO NOT CONTAMINATE WATER WHEN
    DISPOSING OF EQUIPMENT WASHWATERS.
RTECS #:9999999ZZ

Name:HYGIENE PRACT: GETS INSIDE. THEN WASH THORO & PUT ON CLEAN
    CLTHG. FOLLOW MFR'S INSTRUCTIONS FOR CLEANING/MAINT (ING 24)
RTECS #:9999999ZZ

Name:ING 23: PPE. IF NO SUCH INSTRUCTIONS, USE DETERGENT & HOT
    WATER. KEEP & WASH PPE SEPARATELY FROM OTHER LAUNDRY.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 (ORAL RAT): > 5000 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: MAY CAUSE PAIN, REDNESS &
    TEARING. SKIN: SLIGHTLY TOX & IRRIT. INGEST: SLIGHTLY TOX. NO
    SIGNIFICANT ADVERSE HLTH EFTS ARE EXPECTED TO DEVELOP IF ONLY SML
    AMTS (LESS THAN MOUTHFUL) ARE SWA LLOWED. INGEST OF SIMILAR
    FORMULATIONS HAS BEEN REPORTED TO PRDCE GI DISCOMFORT W/IRRIT OF
    MOUTH, NAUS,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: VOMIT & DIARR. ORAL INGEST OF LGE
    QTYS OF ONE SIMILAR PROD HAS BEEN REPORTED TO RSLT IN HYPOTENSION &
    LUNG EDEMA. INHAL: SLIGHTLY TOX. TOX INFO: DATA FROM STUDIES
    W/FORMULATION OF 62% ISOPRO PYLAMINE SALT OF GLYPHOSATE (MON 0139)
    INDICATE THE FOLLOWING: IN REPEAT DOSING STUDIES (6-MONTH), DOGS
    FED MON (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

Eyes: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
    MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: FLUSH W/COPIOUS
    AMOUNTS OF WATER. SEE MD . INHAL: REMOVE TO FRESH AIR. SUPPORT
    BREATHIN G (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . INGEST: CALL MD
    IMMED . NOTE: FOR ADDITIONAL HUMAN EMERGENCY FIRST AID/TREATMENT
    GUIDANCE, CALL COLLECT, ANYTIME, DAY/NIGHT (314) 694-4000.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:>200F,>93C
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE, OR
    ANY CLASS B EXTINGUISHING AGENT.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT . EQUIPMENT SHOULD BE THOROUGHLY CLEANED AFTER USE.
Unusual Fire/Explosion Hazard:NONE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:OBSERVE ALL PROT & SFTY PREC WHEN CLEANING UP
    SPILLS. SML SPILL: FOR <1 GAL ON FLOOR/OTHER IMPERVIOUS SURF, SOAK
    UP W/TOWELS/OTHER ABSORB MATL & DISCARD IN TRASH. CLEAN SPILL AREA
    W/SOAP & WATER & RIN SE AREA THORO. LGE LIQ SPILL ON FLOOR OR (ING
    14)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN.
    REFORMULATION PROHIBITED. SEE INDIVIDUAL CONTR LABEL FOR
    REPACKAGING LIMITATIONS. AVOID CONT W/EYES OR CLOTHING.
Other Precautions:AVOID BRTHG VAP/MIST. NOTE: PHYSICAL DATA GIVEN ARE
    TYPICAL VALUES BASED ON MATL TESTED BUT MAY VARY FROM SAMPLE TO
    SAMPLE. TYPICAL VALUES SHOULD NOT BE CONSTRUED AS A GUARANTEED
    ANALYSIS OF ANY SPECI FIC LOT/AS SPECIFICATION ITEMS. (ING 21)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IN EVENT OF ABNORM AIRBORNE EXPOS CNDTNS, USE
    NIOSH APPRVD EQUIP. IN WORK SITUATIONS WHERE AIR PURIFYING RESP IS
    APPROP TO BE USED, USE FULL FACE RESP EQUIPPED W/PURIFYING ELEMENTS
    FOR PROT. CONT NEHC  FOR MORE SPECIFIC INFO .
Ventilation:NO SPECIAL PRECAUTIONS ARE RECOMMENDED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
    WEAR LONG-SLEEVED SHIRT, LONG PANTS, SHOES PLUS SOCKS.
Work Hygienic Practices:WASH HANDS BEFORE EATING, DRINKING, CHEWING
    GUM, USING TOBACCO/USING TOILET. REMOVE CLTHG IMMED IF PESTICIDE
    (ING 23)
Supplemental Safety and Health
PH: 4.99 (1% SOLN). MATLS TO AVOID: PLASTIC-LINED CONTRS. DO NOT MIX,
    STORE/APPLY PROD/SPRAY SOLNS OF PROD IN GALVANIZED/UNLINED STEEL
    (EXCEPT STAINLESS STEEL) CONTRS/SPRAY TANKS. PROD/SPRAY SOLNS OF 
    PROD REACT W/SUCH CONTRS & TANKS TO PRDCE HYDROGEN GAS WHICH MAY
    FORM HIGHLY COMBUST GAS MIXT. THIS GAS MIXT (ING 3)

==================  Physical/Chemical Properties  ==================

Spec Gravity:1.17 (H*2O=1)
pH:SUPDAT
Appearance and Odor:CLEAR, VISCOUS AMBER-COLORED SOLN;PRACTICALLY
    ODORLESS TO SLIGHT AMINE-LIKE ODO

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
SPRAY SOLNS OF PROD SHOULD BE MIXED, STORED/APPLIED USING ONLY
    STAINLESS STEEL, ALUMINUM, FIBERGLASS, PLASTIC/ (SUP DAT)
Stability Condition to Avoid:NONE. STABLE FOR AT LEAST 5 YEARS UNDER
    NORMAL CONDITIONS OF WAREHOUSE STORAGE.
Hazardous Decomposition Products:NONE.
Conditions to Avoid Polymerization:CAN REACT W/CAUSTIC (BASIC) MATLS TO
    LIBERATE HEAT. THIS IS NOT POLYM BUT RATHER CHEM NEUTRALIZATION IN
    ACID BASE RXN.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTES THAT CANNOT BE USED/CHEM REPROCESSED
    SHOULD BE DISP OF IN LANDFILL APPRVD FOR PESTICIDE DISP OR I/A/W
    APPLIC FED, STATE/LOC PROC. EMPTIED CONTR RETAINS VAP & RESIDUE.
    OBSERVE ALL LABELED PREC U NTIL CONTR IS CLEANED,
    RECONDITIONED/DESTROYED.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***