===================== Product Identification =====================
MSDS NAME:142-0009 RED-ORANGE FLUORESCENT, SHER-MARK (SUPDAT)
NIIN:00N062839
MSDS Number: CGZTR
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO
Address:101 PROSPECT AVE NW
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-566-2917
CAGE:54636
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Name:PROPANE; (PROPANE (PROPELLANT). VP: 760.
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 13%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Name:BUTANE; (BUTANE (PROPELLANT)). VP: 760.
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 7%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM
Name:HEXANE (CERCLA). VP: 127.
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: 13%
OSHA PEL:500 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:VM & P NAPHTHA. VP: 12.
CAS:64742-89-8
Fraction by Wt: 14%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:XYLENE (SARA 313) (CERCLA). VP: 5.9.
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 1%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM; 150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ACETONE (SARA 313) (CERCLA). VP: 180.
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 20%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM; 1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE)
CAS:471-34-1
RTECS #:FF9335000
Fraction by Wt: 3%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BARIUM SULFATE
CAS:7727-43-7
RTECS #:CR0600000
Fraction by Wt: 16%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Name:EFTS OF OVEREXP: CARDIOVASCULAR SYSTEMS. REPORTS HAVE ASSOC
RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN & (ING 11)
RTECS #:9999999ZZ
Name:ING 10: NERVOUS SYS DMG. WARNING: CONTAINS A CHEMICAL KNOWN
TO STATE OF CALIFORNIA TO CAUSE CANCER.
RTECS #:9999999ZZ
Name:HNDLG/STOR PRECS: ALL VAPS ARE GONE: KEEP AREA VENTD - DO
NOT SMOKE - EXTING ALL FLAMES, PILOT LIGHTS & (ING 13)
RTECS #:9999999ZZ
Name:ING 12: HEATERS - TURN OFF STOVES, ELEC TOOLS & APPLIANCES
& ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODE. USE (ING 14)
RTECS #:9999999ZZ
Name:ING 13: APPRVD BONDING & GROUNDING PROCS. CONTENTS UNDER
PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO TEMP ABOVE (ING 15)
RTECS #:9999999ZZ
Name:ING 14: 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT
WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. (ING 16)
RTECS #:9999999ZZ
Name:ING 15: DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF
CHILDREN.
RTECS #:9999999ZZ
Name:OTHER PRECS: PARTICULATES (LISTED "AS DUST" IN INGRED
SECTION) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING (ING 18)
RTECS #:9999999ZZ
Name:ING 17: SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC
DUSTS LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH (ING 19)
RTECS #:9999999ZZ
Name:ING 18: TLV 10 MG/M3 (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5
MG/M3 (RESPIRABLE FRACTION).
RTECS #:9999999ZZ
Name:RESP PROT: GENERATED FROM THIS PRODUCT, UNDERLYING PAINT OR
THE ABRASIVE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESS EXPOS TO VAPS/SPRAY MIS TS. REDNESS & ITCHING OR BURNING
SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS. CHRONIC: PRLNGD
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: & RPTD EXPOS TO HEXANE MAY CAUSE DMG
TO NERVE TISS OF ARMS & LEGS (PERIPHERAL NEUROPATHY), RLSTG IN MUSC
WEAK & LOSS OF SENSATION. THIS EFT MAY BE INCRD BY PRESENCE OF
METHYL ETHYL KETONE. P RLNGD OVEREXP TO SOLV INGREDS LISTED MAY
CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD FORMING, REPRO & (ING
10)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP &
WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:
FLUSH EYE S W/LARGE AMOUNTS OF WATER FOR AT LEAST15 MINUTES. GET
MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON.
DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MED
ATTN.
===================== Fire Fighting Measures =====================
Flash Point:<0F,<-18C
Lower Limits:1.0%
Upper Limits:12.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP. WATER
SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO
EXTREME HEAT. APPLICATION TO HOT SURFS REQS SPEC PRECS. DURING EMER
CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMMABLE. KEEP
AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY
IGNITE EXPLO. DURING USE & UNTIL (ING 12)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN
BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY
MIST. AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER USING. THESE
COATINGS MAY CNTN M ATLS CLASSIFIED AS NUISANCE (ING 17)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR PROPERLY FITTED, NIOSH APPRVD RESP ORG
VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR
DUST/MIST RESP APPRVD BY NIOS H FOR DUST WHICH MAY BE (ING 20)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
BELOW APPLIC LIMS. REFER TO OSHA STDS 1910.94, 107, 108.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: UPSIDE DOWN MARKING PAINT. FIRE FIGHT PROC:
TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLO WHEN EXPOSED TO
EXTREME HEAT. EXPLO HAZ: HAZ. SYMPTOMS MAY NOT BE IMMED APPARENT.
OBTAIN MED ATTN.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<325F,<163C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Volatile Org Content %:69
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>80
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM APPLIC EPA HAZ WASTE NUMBER. INCIN IN APPRVD FACILITY. DO
NOT INCIN CLSD CNTNR. DISP I/A/W FED, STATE & LOC REGS REGARDING
POLLUTION.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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